期刊
ORGANIC LETTERS
卷 21, 期 15, 页码 5986-5989出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02129
关键词
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资金
- National Natural Science Foundation of China [21602182]
- Longshan academic talent research supporting program of SWUST [17LZX324, 18LZX305, 18LZXT02]
- Project of State Key Laboratory of Environment-Friendly Energy Materials, SWUST [17fksy0102, 18fksy0206]
An efficient and succinct protocol for synthesis of bis(o-carborane) connected by a B-B bond via palladium catalyzed oxidative dehydrogenative coupling of cage B-H/B-H bonds was developed for the first time. A series of bis(o-carborane)s connected by B(4)-B(4)' and B(4)-B(5)' bonds was synthesized with moderate to good yields. This work opens the door for miscellaneous applications of bis(o-carborane) in related disciplines and has important value in design and synthesis of different kinds of biscarboranes.
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