期刊
ORGANIC LETTERS
卷 21, 期 13, 页码 5295-5300出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01911
关键词
-
资金
- Spanish Government [CTQ2015-64561-R, RTI2018-095038-B-I00]
- Comunidad de Madrid
- European Structural Funds [S2018/NMT-4367]
Aryl radical generation and manipulation constitutes a long-standing challenge in organic synthesis. Photocatalytic single-electron reduction of aryl halides has been established as a premier activation pathway to reach these intermediates. The current study integrates the conceptual simplicity of the classical intramolecular homolytic substitution with the practicality of the modern photocatalytic approach. Predicated on an efficient metal-free dehalogenation of aryl halides under mild organo-photoredox conditions, sulfur, phosphorus, and silicon heteroatoms capture the C(sp(2))-centered radical in an intramolecular fashion.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据