Article
Environmental Sciences
Zannatul Mumtarin Moushumy, Mohammad Jobaer Hassan, Mohebul Ahsan, Md Mahmudul Hasan, Md Nizam Uddin, Yuki Nagao, Mohammad A. Hasnat
Summary: A series of Ce, Bi, and N co-doped TiO2 photocatalysts were prepared to remove Chlorazol yellow (CY) dye molecules from water. The 5 wt% (Ce-Bi-N) co-doped TiO2 composite catalyst showed the best catalytic activity under sunlight irradiation. The catalyst achieved 97% degradation of CY molecules within 30 minutes and followed second-order kinetics. The developed catalyst can destruct CY molecules with a maximum rate of 23.1 mu g CY g(-1) min(-1) and the photodegradation kinetics depends on the concentration of CY.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Environmental Sciences
Sobia Maqbool, Adeel Ahmed, Arif Mukhtar, Muhammad Jamshaid, Aziz Ur Rehman, Saima Anjum
Summary: This work aims to develop a highly efficient solar light-induced photocatalyst based on La-Mn co-doped Fe2O3 nanoparticles. The synthesized nanoparticles were analyzed for their morphological, structural, and magnetic characteristics. The photocatalytic performance of the different catalysts was evaluated, and it was found that La0.2Mn0.2Fe1.6O3 catalyst showed exceptional degradation performance.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Environmental Sciences
Lianxin Yuan, Weixuan Liu, Wanting Zhang
Summary: Element doping is an effective method for enhancing the photocatalytic performance of photocatalysts. This study utilized potassium sorbate as a new precursor to dope potassium ions into g-C3N4 during the calcination process, resulting in the formation of potassium-doped g-C3N4 (KCN). Through various characterization techniques and electrochemical measurements, it was found that potassium doping efficiently modified the band structure of g-C3N4, enhancing light absorption and conductivity, which accelerated charge transfer and photogenerated carrier separation. These findings demonstrate the potential of potassium incorporation in g-C3N4 for fabricating high-performance photocatalysts for organic pollutant removal.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Chemistry, Physical
Saranya Sasi, Benazeera Beegum, Christeena Thomas, Linu Mary Joseph, V. K. Shinoj, R. Reshmi
Summary: Pure and manganese (Mn) doped molybdenum disulphide (MoS2) was synthesized by hydrothermal approach. The XRD spectrum confirmed the Mn2+ ion incorporation without affecting the crystal structure of MoS2. FESEM images revealed flower-like hierarchical nanostructures with increased surface area for 3% Mn doping. Photocatalytic degradation of methylene blue achieved 97% efficiency in 55 minutes using 3% Mn doped MoS2, attributed to the edge terminated active sites and increased surface area. This is the first report of Mn doped MoS2 as an efficient photocatalyst for methylene blue degradation.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Inorganic & Nuclear
Lin Liu, Qiang Chen, Zheng-Bo Han
Summary: A Co(II)-based porous metal-organic framework with semiconductor properties has been synthesized and characterized. The framework exhibits photocatalytic activity for the degradation of methylene blue dyes.
INORGANIC CHEMISTRY COMMUNICATIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Shubhangi N. Kotkar, Subedar Prasad, Gunwant P. Gadekar, Suresh B. Rewatkar
Summary: Natural sunlight active zinc oxide nanoparticles were synthesized using a simple solution auto combustion method. The structural and optical characteristics of the nanoparticles were studied, and it was found that they exhibited excellent photodegradation activity and antimicrobial properties.
INORGANIC CHEMISTRY COMMUNICATIONS
(2022)
Article
Engineering, Chemical
Van Nhuong Vu, Thi Ha Thanh Pham, Quoc Dung Nguyen, Thi Hau Vu, Thi Tu Anh Duong, Thi Hue Tran, Thi Kim Ngan Tran
Summary: Cu2+ modified ZnAlCO3 hydrotalcite materials were synthesized by co-precipitation method and characterized. The modified materials exhibited layered double hydroxide structure, with a slight increase in specific surface area and decrease in bandgap energy with increasing Cu2+ molar ratios. The material samples showed high adsorption capacity for phenol red and high degradation efficiency with the presence of light and H2O2. The CuH-3.5 sample demonstrated good catalytic stability after repeated use.
Article
Environmental Sciences
Neetu Talreja, Shagufta Afreen, Mohammad Ashfaq, Divya Chauhan, Adriana C. Mera, C. A. Rodriguez, R. Mangalaraja
Summary: The synthesized Fe/Zn-BiOI based photocatalyst materials showed promising results in degrading TC antibiotics and inhibiting bacteria, especially under high TC antibiotic concentrations and alkaline conditions.
Article
Energy & Fuels
Mehala Kunnamareddy, Karmegam Natchimuthu, Kavitha Tangavelu, Senthilkumar Palanisamy, Barathi Diravidamani, Priyadharsan Arumugam, Ranjith Rajendran
Summary: In this study, Mg-S co-doped TiO2 nanoparticles were synthesized using the sol-gel method and their photocatalytic activity under simulated visible light was examined. The Mg-S co-doped TiO2 nanoparticles exhibited a pure anatase structure with a decreased band gap energy compared to pristine TiO2. They showed excellent photocatalytic activity and achieved a maximum degradation efficiency of 94.8% for methylene blue dye. Additionally, the antimicrobial activity of Mg-S co-doped TiO2 nanoparticles against Escherichia coli and Staphylococcus aureus was investigated, and the maximum antibacterial activity was achieved by doping and co-doping with Mg/S.
BIOMASS CONVERSION AND BIOREFINERY
(2023)
Article
Chemistry, Physical
Manifa Noor, Fahmida Sharmin, M. A. Al Mamun, Sajjad Hasan, M. A. Hakim, M. A. Basith
Summary: The development of metal oxide photocatalysts with improved dye degradation efficiency under natural sunlight is in increasing demand. In this study, Gd and Y co-doped BiVO4 materials were synthesized using a surfactant-free hydrothermal technique. Structural and optical characterizations confirmed the superior performance of the co-doped materials.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Engineering, Environmental
Prerna Attri, Preeti Garg, Moondeep Chauhan, Rajender Singh, Ramesh K. Sharma, Sandeep Kumar, Dong-Kwon Lim, Ganga Ram Chaudhary
Summary: Here, we presented the fabrication of well-crystalline metal-doped BiOCl nanoscale photocatalytic materials through solvothermal synthetic route. Ni doping significantly improved the photocatalytic and antibacterial behavior of BiOCl. The morphological study showed that different metal dopings led to the formation of nanosheet (Ni, Cd), nanoflower (Mo), and nanodisc (Co) morphologies, while Ni doping resulted in large size nanosheets with increased surface area and improved porous structure. The inclusion of Ni into BiOCl nanostructure shifted the band gap and reduced electron-hole recombination, contributing to its excellent photocatalytic performance. Additionally, Ni-BiOCl exhibited excellent photocatalytic antibacterial activity against S. aureus bacteria under visible light.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Chemistry, Physical
Pardhasaradhi Nandigana, Sanchayan Mahato, Manjubashini Dhandapani, Basudev Pradhan, B. Subramanian, Subhendu K. Panda
Summary: In this study, pristine MoS2 and Sn-doped MoS2 were successfully synthesized for photocatalytic degradation of dye. It was found that lyophilized Sn-doped MoS2 showed excellent photocatalytic activity with efficient and rapid degradation ability for RhB dye.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Engineering, Chemical
Yinuo Gao, Weijin Yang, Fei Wang, Yafei Li, Shihai Cui, Xuewei Liao, Jing Yang
Summary: This study prepared three-dimensional flower-like MoS2/UiO-66 heterojunctions by in-situ hydrothermal method, and the composite exhibited excellent photocatalytic activity with an oxytetracycline degradation efficiency of 86.6% and broad-spectrum response. Additionally, the composite material showed good repeatability and potential applications.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2023)
Article
Chemistry, Multidisciplinary
Yuankun Liu, Xinxia Zhang, Hongrun Liu
Summary: In this study, iron-nitrogen co-doped modified corncob was synthesized and showed excellent oxidation performance and environmental friendliness. Under specific conditions, the material effectively eliminated ciprofloxacin in water, and the effects of reaction parameters on its catalytic activity were thoroughly assessed. The study proposed the degradation mechanism, possible pathways, and toxicity of ciprofloxacin, providing theoretical and technical support for its removal in water treatment.
Article
Chemistry, Inorganic & Nuclear
Chananchida Khaokhajorn, Pongsaton Amornpitoksuk, Chamnan Randorn, Tanattha Rattana, Sumetha Suwanboon
Summary: An In2O3/ZnO nanocomposite was synthesized and applied in the photocatalytic degradation of dyes. The nanocomposite showed two phases, In2O3 and ZnO, and had an increased specific surface area with higher content of In2O3. The nanocomposite exhibited good photocatalytic activity in degrading cationic and anionic dyes under different pH conditions.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Article
Green & Sustainable Science & Technology
Manjakuppam Malika, Shriram S. Sonawane
Summary: A hybrid nanofluid consisting of aqueous Aluminium Hydroxide and Graphitic Carbon Nitride was fabricated, exhibiting enhanced photocatalytic performance compared to a hybrid photocatalyst. The nanofluid produced about 6 times higher H-2 than the hybrid photocatalyst, with only a 1% decrease in performance after 4 cycles. This study provides a sustainable approach for harvesting H-2 from photocatalytic degradation of industrial pollutants under visible light.
SUSTAINABLE ENERGY TECHNOLOGIES AND ASSESSMENTS
(2021)
Article
Thermodynamics
Manjakuppam Malika, Shriram S. Sonawane
Summary: A novel water-based hybrid nanofluid was synthesized and the thermal conductivity ratio was predicted using artificial neural network (ANN) and response surface methodology (RSM) with optimized nanoparticle mixing ratio, demonstrating the effectiveness of both methods in predicting the thermal conductivity ratio of the nanofluid.
INTERNATIONAL COMMUNICATIONS IN HEAT AND MASS TRANSFER
(2021)
Article
Engineering, Chemical
Manjakuppam Malika, Shriram S. Sonawane
Summary: This study investigates the efficiency of a novel 3D artificially illuminated sono-photocatalytic reactor in removing toxic fragments from industrial wastewater, achieving 99% dye degradation within 40 minutes. Response surface methodology and artificial neural network methods were used to optimize the process, revealing significant impact of input parameters on the response variable. With a high R-2 value of 0.999, the engineered multilayer perceptron ANN successfully validated the experimental findings, showing promising potential as a pre-treatment step for producing low toxic intermediates in industrial wastewater treatment.
INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING
(2021)
Article
Chemistry, Analytical
Smruti Ranjan Dash, Subhendu Sekhar Bag, Animes Kumar Golder
Summary: Carbon dots modified glassy carbon electrode was successfully used for electrochemical sensing of Chlorpyrifos. The reduction of CHL involved an irreversible two-electron process with good repeatability and sensitivity. The electrochemical sensing of CHL showed comparable results with HPLC (around 5% variation).
Article
Chemistry, Multidisciplinary
Manjakuppam Malika, Rahul Bhad, Shriram S. Sonawane
Summary: This study investigates the heat transfer performance and optimization of CuO-ZnO (80:20)/water hybrid nanofluid in a shell and tube heat exchanger, showing improved heat transfer efficiency at different Reynolds numbers. The hybrid nanofluid demonstrates significant enhancements in convective heat transfer coefficient and pressure drop, with minimal changes in thermal conductivity after multiple trials. The ANSYS Fluent simulation results align well with experimental values, highlighting the potential of hybrid nanofluids in enhancing heat transfer processes.
JOURNAL OF THE INDIAN CHEMICAL SOCIETY
(2021)
Article
Engineering, Environmental
Paulomi Bose, Chandan Mukherjee, Animes Kumar Golder
Summary: Electrochemical reduction of CO2 using Pb(II)-salen complexes as catalysts deposited on graphite electrodes was explored. The presence of different functional groups facilitated the formation of different carbon products, depending on the ligand framework. The study provides insights into the role of ligands in modifying the substrate and proton concentrations for CO2 reduction.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Manjakuppam Malika, Shriram S. Sonawane
Summary: The calcination temperature affects the crystallinity and morphology of Fe2O3- TiO2 nanosheets, and using hybrid nanofluids can improve the photocatalytic degradation.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Engineering, Mechanical
Manjakuppam Malika, Shriram S. Sonawane
Summary: This study estimates the environmental impact and cost model for the early-stage design of a shell and tube heat exchanger (STHE), and compares the effectiveness of using nanofluid in the chemical processing industry. The results show that nanofluids improve heat transfer and have higher economic value compared to typical coolant systems. The suggested novel method is cost-effective and environmentally feasible.
PROCEEDINGS OF THE INSTITUTION OF MECHANICAL ENGINEERS PART E-JOURNAL OF PROCESS MECHANICAL ENGINEERING
(2022)
Article
Chemistry, Multidisciplinary
Manjakuppam Malika, Prakash G. Jhadav, Vishal R. Parate, Shriram S. Sonawane
Summary: Nanoscale magnetite is widely used in various applications, but its potential environmental consequences need to be considered. This study investigates the environmental impact of adding magnetite nanoparticles in commercially available coolants and proposes methods to improve the performance of nanofluids. By employing green chemistry principles, the environmental impact of magnetite production can be minimized. In addition, addressing the viscosity and method of preparation of nanofluids is crucial in reducing environmental effects.
Article
Chemistry, Physical
Manjakuppam Malika, Shriram S. Sonawane
Summary: Seasonings have become popular for enhancing food flavor recently. However, many users are unaware of the ingredients in these seasonings and are only concerned about tasty food rather than their health effects. This study focused on extracting monosodium glutamate (MSG) from a simulated polluted solution using an emulsion liquid membrane (ELM), which is an effective extraction and stripping process. The stability of the emulsion limits the industrial application of ELM, so the study replaced the membrane phase with a silicon carbide based nanofluid to form an emulsion nanofluid membrane (ENM). The enhanced dispersion stability of the nanofluid ensured the effectiveness of the extraction process. Additionally, a three level RSM-CCD model was used to optimize parameters such as nanofluid concentration, ultrasonication time, surfactant concentration, and carrier concentration. The ENM proved to be the most efficient and recyclable method for MSG extraction.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Chemistry, Multidisciplinary
Anirban Chowdhury, Chandra Bhan, Nageswara Rao Peela, Animes Kumar Golder
Summary: This study focuses on the bioinspired synthesis of SnO2 nanoparticles using S. edule fruit. A mechanistic route for the synthesis of SnO2 nanoparticles has been proposed. The study shows that these nanoparticles can efficiently catalyze the electrochemical reduction of CO2 to formate under specific conditions.
JOURNAL OF CO2 UTILIZATION
(2022)
Article
Chemistry, Multidisciplinary
Manjakuppam Malika, Aaditi Pargaonkar, Shriram S. Sonawane
Summary: In this study, a highly stable Emulsion Nanofluid Membrane (ENM) was developed using Al2O3 nanofluid and surfactant (Span 80) as the membrane phase. At optimal conditions, the ENM achieved a total extraction of 99% of Methylene blue (MB) within the first 15 minutes.
Article
Chemistry, Multidisciplinary
Manjakuppam Malika, Aaditi Pargaonkar, Shriram S. Sonawane
Summary: The study developed a novel MWCNT-Fe2O3/water-based drilling fluid, which utilized hybrid nanofluids by dispersing multiple nanoparticles in a base fluid. The addition of nanofluids significantly increased the thermal conductivity of the drilling fluid, with a thermal conductivity enhancement of approximately 414% observed for 0.5 vol% hybrid nanofluid-based drilling fluid. RSM studies optimized the input parameters to enhance the drilling fluid's thermal conductivity. The significant improvement in thermal conductivity demonstrates the effectiveness of nanofluid addition in the drilling fluid's performance.
Article
Engineering, Environmental
Subhendu Sekhar Bag, Sayantan Sinha, Aniket Banerjee, Animes Golder
Summary: Careless discharge of textile/industry effluents containing carcinogenic organic dyes into local water bodies has become a major source of wastewater pollution in India. To address this issue, the researchers developed I5+/TiO2 as a smart catalyst with dual functions: colorimetric visual sensing and degradation of the dyes. The catalyst showed excellent ability in both colorimetric sensing and degradation of methyl orange and methylene blue dyes. The treated water was found to be safe for plants and human health, making it suitable for agricultural and household activities.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Green & Sustainable Science & Technology
Manjakuppam Malika, Shriram S. Sonawane
Summary: A novel aqueous based copper-nickel doped titania supported montmorillonite clay hybrid nanofluid was prepared using a hydrothermal process in this study. The photocatalyst activity was analyzed by degrading Rhodamine B under visible light, showing a 19% reduction in the TiO2 band gap energy at a metal ratio of 75:25. The addition of clay improved the adsorption surface area and porosity of the photocatalyst. By adjusting input parameters using response surface methodology, a 97% photocatalytic degradation of effluent within 60 minutes was achieved. An analysis of variance study was also conducted to understand the significant effects of input parameters on the response variable, proposing a new quadratic correlation and possible photocatalytic degradation mechanism.
SUSTAINABLE ENERGY TECHNOLOGIES AND ASSESSMENTS
(2021)
Article
Chemistry, Physical
Qi-Wen Chen, Ze-Qing Guo, Jian-Ping Zhou
Summary: Multifunctional continuous solid solutions NFMTO-x were successfully synthesized via a one-step hydrothermal method by controlling the ratio of Mg and Fe. The NFMTO-x materials exhibited enhanced visible light response, effective adsorption and photocatalytic degradation of organic pollutants, CO2 methanation capability, and easy recyclability due to their magnetic properties. This research provides a significant multifunctional material for water purification.
APPLIED SURFACE SCIENCE
(2024)
Review
Chemistry, Physical
George E. Stan, Maziar Montazerian, Adam Shearer, Bryan W. Stuart, Francesco Baino, John C. Mauro, Jose M. F. Ferreira
Summary: Bioactive glasses have the ability to form strong bonds with tissues and release therapeutic ions. However, their biomechanical compatibility limits their use in load-bearing applications. The use of magnetron sputtering technology to fabricate BG coatings shows promise in improving their efficacy and potential for application.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zhaoxuan Wang, Zhicheng Yan, Zhigang Qi, Yu Feng, Qi Chen, Ziqi Song, Meng Huang, Peng Jia, Ki Buem Kim, Weimin Wang
Summary: The corrosion behavior of Fe-60 and Fe-83 ribbons in 0.6 M NaCl was studied. Fe-60 exhibited a local corrosion mode and formed a stable passivation film with higher corrosion resistance, while Fe-83 showed a combination of local and global corrosion modes and had lower corrosion resistance. Controlling the precipitation of nanocrystalline phases and increasing the POx content in the passivation film significantly improved the corrosion resistance of Fe-based glassy alloys.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hao-Kai Peng, Sheng-Yen Zheng, Wei-Ning Kao, Ting-Chieh Lai, Kai-Sheun Lee, Yung- Hsien Wu
Summary: This study investigates the effects of high energy/fluence proton radiation on the performance of HfZrOx-based FeFETs memory with different Zr content. The results show that the characteristics of FeFETs are influenced by proton radiation, and the extent of the influence depends on the Zr content. FeFETs with 50% Zr content exhibit minimal changes in memory window and demonstrate good endurance and retention performance.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zongyi Yue, Guangyi Wang, Zengguang Huang, Sihua Zhong
Summary: In this study, AZO and ITO films were successfully tuned as excellent passivation layers for c-Si surfaces, achieving effective minority carrier lifetime and outstanding optical properties through the optimization of annealing temperature and interfacial silicon oxide.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Martin Hruska, Jan Kejzlar, Jaroslav Otta, Premysl Fitl, Michal Novotny, Jakub Cizek, Oksana Melikhova, Matej Micusik, Peter Machata, Martin Vrnata
Summary: This paper presents a detailed study on the hydrogen sensing capabilities of highly nanoporous black gold films. The films exhibit fast response and recovery times at low temperatures. Different levels of nanoporosity were prepared and tested to investigate the sensing properties, and it was found that nanoporous black gold is suitable for hydrogen sensing. The sensitivity of the film depends on its nanoporosity.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yupu Wang, Gaofeng Teng, Chun To Yiu, Junyi Zhu
Summary: In the study of BM-SCO and HSCO thin films, it was found that H vacancies tend to prefer sites near the external surface or oxygen vacancy channels (OVCs), while H interstitials prefer sites of oxygen on a layer that contains six-fold coordinated Co. These findings not only enrich the understanding of complex surface phenomena of defect formation but also provide an explanation for the reversibility during phase transformation.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jiafeng Lu, Linping Teng, Qinxiao Zhai, Chunhua Wang, Matthieu Lancry, Ye Dai, Xianglong Zeng
Summary: In this study, we achieved full control of fiber nanograting orientation by manipulating laser polarization, and tailored space variant fiber nanogratings, which expanded the diversity in fiber nanograting engineering.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yibo Liu, Yujie Tao, Yue Liu, Qi Sun, Qinrong Lin, Kexin Kang, Qinghua Zhang, Qingjie Sun
Summary: This study investigates the wettability of the Ti-Cu-Fe multi-metal system, specifically the wetting behaviors of CuSi3 droplets on TC4 and 304SS plates. The results show that the CO2 + Ar gas atmosphere significantly affects interfacial mass transfer, thus influencing the wettability of the systems.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jimei Liu, Fei Wang, Rong Guo, Yuqi Liu, Mengyu Zhang, Jaka Sunarso, Dong Liu
Summary: This study developed Co/MXene composites with anti-corrosion properties by varying the cobalt content. These composites exhibited remarkable electromagnetic absorption performance and high resistance to corrosion under various corrosive conditions. The study also revealed the mechanism of electron transfer from cobalt to MXene and the electromagnetic dissipation behavior originated from polarization loss alone.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Moujie Huang, Yongsong Ma, Jingbo Yang, Lingyun Xu, Hangqi Yang, Miao Wang, Xin Ma, Xin Xia, Junhao Yang, Deli Wang, Chuang Peng
Summary: Strong metal-support interactions (SMSIs) are important for enhancing catalytic activities and stability in thermal catalysis. This study demonstrates a method to create SMSIs in electrocatalysis using carbon nanotubes and Ru nanoparticles, resulting in excellent catalytic activity and stability.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Ravi Trivedi, Brinti Mondal, Nandini Garg, Brahmananda Chakraborty
Summary: This study explores the potential of biphenylene as a nanocarrier for the delivery of the anticancer drug cisplatin. It is found that biphenylene offers physical stability, rapid release rate, solubility, and bio-compatibilities compared to other nanocarriers. The adsorption of cisplatin on the surface of biphenylene involves charge transfer from cisplatin to biphenylene. The drug is shown to be released at body temperature in an acidic environment. Biphenylene also exhibits excellent cytotoxicity activity and cellular uptake of the drug. Overall, biphenylene shows promise as a potential nanocarrier for cisplatin delivery.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hyun Jeong, Hyeong Chan Suh, Ga Hyun Cho, Rafael Salas-Montiel, Hayoung Ko, Ki Kang Kim, Mun Seok Jeong
Summary: In this study, a potential platform to enhance Raman scattering and increase the number of observable Raman modes in monolayer transition metal dichalcogenides (TMDs) was proposed. The platform consisted of large-scale arrays of gold micropillars (MPs), which were able to enhance the Raman intensity of TMDs and make difficult-to-detect Raman modes observable. The platform showed great industrial advantages and wide applicability due to its low cost, simple process, large controllable area, and short process time.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yasir Abbas, Shafqat Ali, Sajjad Ali, Waqar Azeem, Zareen Zuhra, Haoliang Wang, Mohamed Bououdina, Zhenzhong Sun
Summary: In this study, FeOx@SPNO-C core-shell nanospheres as a catalyst for degradation of sulfamethoxazole (SMX) were successfully synthesized. The synergistic interaction between FeOx and SPNO-C, high carbon charge density, and the presence of C = O groups and N/Fe-Nx sites were found to be key factors for the enhanced degradation of SMX.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Qiaoting Yang, Yuxiao Gong, Yan Qian, Zhou-Qing Xiao, Serge Cosnier, Xue-Ji Zhang, Robert S. Marks, Dan Shan
Summary: This study proposes a hierarchical confinement strategy to design Prussian blue nanoparticles (PB NPs) with satisfactory electrocatalytic ability and stability. The catalytic synthesis of PB NPs is achieved through a hydrothermal process, and the as-prepared PB@NH2MIL exhibits efficient electronic transmission and enhanced electrocatalytic properties.
APPLIED SURFACE SCIENCE
(2024)