4.3 Article

A multi-reflection time-of-flight setup for the improvement and development of new methods and the study of atomic clusters

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出版社

ELSEVIER
DOI: 10.1016/j.ijms.2019.116189

关键词

Time of flight mass spectrometer; Mass separator; MR-ToF MS; Atomic clusters

资金

  1. German Ministry for Education and Research (BMBF) [05P15HGCIA]
  2. Collaborative Research Center of the DFG [SFB 652, TP A03]

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A multi-reflection time-of-flight (MR-ToF) device has been set up for the development and test of new MR-ToF techniques and for future applications in atomic cluster research. The instrument, consisting of a laser-ablation ion source, a quadrupole bender, the MR-ToF analyzer (with ion mirrors and in-trap lift), and a channeltron detector, is described in detail and characterized with respect to preliminary results of its performance parameters. In addition, cluster ions were mass selected in the MR-ToF device and photodissociated. The charged fragments were stored and mass analyzed in a proof-of-principle MS/MS experiment where both MS steps were performed in the MR-ToF operation mode. (C) 2019 Elsevier B.V. All rights reserved.

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