期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 104, 期 -, 页码 150-154出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2019.04.013
关键词
Laser welding; Electrodeposition; Micro-supercapacitor; Nanocomposites
资金
- National Natural Science Foundation of China [21271116, 21476127, U1607119]
- Scientific and Technological Fund from Quzhou Science and Technology Bureau [2015010, 2016D003, 2017G05, 2017T04]
- Scientific Research Startup Project of Quzhou University [2014010]
Ag/Co(OH)(2) interdigital electrode with unique micro-flower structure was fabricated by welding Ag nanoparticles to polyproplene (PP) substrate via laser irradiation, followed by electrodeposition of Co(OH)(2). The Ag/Co(OH)(2) composite exhibited specific capacitance of 729 F.g(-1) at current density of 0.5 A.g(-1). Micro-supercapacitor was fabricated through coating KOH/polyvinyl alcohol hydrogel as electrolyte onto the interdigital electrode. Maximum energy density of 9.47 Wh.kg(-1) at power density of 300 W.kg(-1) had been obtained for the micro-supercapacitor with excellent bendability, demonstrating capacitance retention of approximately 97.67% after 1000 bending cycles. The enhanced bendability compared with the supercapacitors reported previously may be attributed to that the surface of thermoplastic PP melted under laser irradiation to form a melt, which soaked Ag nanoparticles and then solidified, thus realizing the good adhesion between PP and Ag. This technology opens up opportunities for facile and universal fabrication of high performance micro-supercapacitors.
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