Article
Chemistry, Multidisciplinary
Shaidatul Najihah Matussin, Fazlurrahman Khan, Mohammad Hilni Harunsani, Young-Mog Kim, Mohammad Mansoob Khan
Summary: In this study, irregular pentagonal CeO2 and cobalt-doped CeO2 nanoparticles were synthesized, and their structural, optical, and morphological properties were investigated. The results showed that cobalt doping enhanced the photocatalytic and photoantibacterial activities of CeO2.
Article
Materials Science, Multidisciplinary
Hui Yang, Lu Jia, Zhipeng Zhang, Bin Xu, Qitao Zhang, Saisai Yuan, Yonghao Xiao, Zhaodong Nan, Ming Zhang, Yongcai Zhang, Teruhisa Ohno
Summary: In this study, the photocatalytic abilities of Fe ions doped ceria with different morphologies for gaseous acetaldehyde degradation were compared. The results showed that Fe/CeO2-r nanorods exhibited 4.72 times higher photooxidation ability for acetaldehyde removal compared to pure CeO2-r nanorods. The analysis revealed that Fe/CeO2-r and CeO2-r mainly exposed {110} and {100} facets, while CeO2 and Fe/CeO2 with cube morphology mainly exposed {100} facets. The study also confirmed that Fe/CeO2 {110} is more conducive to acetaldehyde absorption and carbon dioxide desorption, and the doping of Fe ions improves the photocatalytic efficiency of ceria-based photocatalysts.
APPLIED MATERIALS TODAY
(2022)
Article
Thermodynamics
Martin Reli, Nela Ambrozova, Marta Valaskova, Miroslava Edelmannova, Libor Capek, Christian Schimpf, Mykhaylo Motylenko, David Rafaja, Kamila Koci
Summary: The study found that Fe8Ce2 is the most active photocatalyst, both in standalone powder form and attached on vermiculite, for hydrogen production via water splitting. The photocatalytic activity of Fe2O3/CeO2 photocatalysts is controlled by intrinsic photocatalytic properties of the oxides and the specific surface area of the composite. The formation of heterojunction Type I with bent bands effectively inhibits the recombination of photogenerated charge carriers.
ENERGY CONVERSION AND MANAGEMENT
(2021)
Article
Chemistry, Multidisciplinary
Jeong-Woo Nam, Vy Ngoc Pham, Jeong Min Ha, Minjeong Shin, Hangil Lee, Young-Sang Youn
Summary: Oxygen vacancies in CeO2 nanoparticles can enhance their photocatalytic activity under UV light. Doped CeO2 nanoparticles with increased oxygen vacancies were prepared by doping Cr and Fe ions into CeO2 nanoparticles, as confirmed by structural and electronic analysis. The doped CeO2 nanoparticles exhibited faster photocatalytic degradation rates for 5-hydroxymethylfurfural than pure CeO2 nanoparticles. In addition, the conversion of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid using the doped CeO2 nanoparticles occurred via selective oxidation to 5-hydroxymethyl-2-furancarboxylic acid, showing higher efficiency compared to CeO2 nanoparticles.
Article
Chemistry, Physical
Prince George, Pradip Chowdhury
Summary: This work systematically investigates the doping of sulfide ions (S2-) on photoactive MIL-53(Fe) and evaluates its performance. The study found that doping can influence the optical band-gap energy of materials, but this does not always lead to improved performance in photocatalytic reactions, especially for hybrid materials like Metal Organic Frameworks (MOFs). By varying the percentage of dopant in the reaction mixture, the study explored the effects of doping on the structural conformations and optical properties of MIL-53(Fe), demonstrating changes in band-gap energy and electron cloud expansion. The best performance in terms of MB degradation was observed for 1% S doped MIL-53(Fe) and the material showed stability even after multiple cycles, indicating potential for practical applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Physics, Applied
Ahmed A. Maarouf, D. Gogova, Mohamed M. Fadlallah
Summary: This study focuses on enhancing the photocatalytic behavior of potassium niobate (KNbO3) by doping with transition metals. Calculations reveal that Ag- and Mn-doped KNbO3 are the best candidates for water splitting and CO2 gas reduction, respectively. The results are expected to lead to more experimental investigations in the field of green energy production.
APPLIED PHYSICS LETTERS
(2021)
Article
Biochemistry & Molecular Biology
Zhao Lu, Wulin Song, Minghao Liu
Summary: Fe(SIC)-doped graphitic carbon nitride photocatalysts exhibited higher photocatalytic activities due to enhanced light absorption ability and rapid separation of photogenerated carriers.
Article
Chemistry, Physical
Xiaowei Jia, Xianchun Liu, Ruyu Zhang, Anqi Xie, Yueran Li, Xiaodan Yu, Min Yu, Yunfeng Li, Zhan Shi, Yan Xing
Summary: A series of Fe-doped KCuTa3O9 (FKCTO-x) oxides were synthesized via one-step high-temperature solid-state reaction. Fe atoms were successfully incorporated into the lattice of KCuTa3O9. The FKCTO-x samples showed enhanced photocatalytic hydrogen evolution activities, with FKCTO-2 exhibiting an optimal hydrogen production rate of 5.51 mu mol h-1 under visible light irradiation, far exceeding that of the pure KCTO. This work provides a simple and effective strategy to design and prepare highly efficient visible-light-driven PLMOs for photocatalytic water splitting.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Said M. El-Sheikh, Ahmed B. Azzam, Ramadan A. Geioushy, Farida M. El Dars, Bahaa Ahmed Salah
Summary: A facile one-pot homogenous precipitation method was used for the first time to fabricate the heterojunction of Bi2S3/BiOBr for enhanced photocatalytic reduction of Cr(VI) to Cr(III). The addition of tartaric acid as a hole scavenger further improved the reduction efficiency of Cr(VI) solution.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Multidisciplinary
W. Fang, Y. Mi, Y. Yang, Y. Jiang, Y. Liu, W. Shangguan
Summary: Bismuth-based Sillen-Aurivillius oxyhalide Bi4MO8Cl is a promising visible-light photocatalyst, and replacing the transition element M can enhance its photocatalytic hydrogen generation performance.
MATERIALS TODAY CHEMISTRY
(2022)
Article
Engineering, Environmental
Kailin Wang, Songyu Yang, Yan Wu
Summary: This paper presents the use of Fe-Co3O4 and Pt dual cocatalysts to enhance photocatalytic water splitting for hydrogen production. The dual cocatalysts not only improve the migration rate of photo-generated electrons and holes, but also enhance light absorption capacity. The interfacial electric field built from the p-n heterojunction of Fe-Co3O4 /g-C3N4 promotes the flow of photo-generated electrons to the holes, inhibiting carrier recombination.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Materials Science, Ceramics
Charitha Thambiliyagodage, Shanitha Mirihana
Summary: This study successfully synthesized Fe and Cu co-doped TiO2 nanoparticles and investigated their photocatalytic activity. Doping with Fe and Cu can enhance the visible light sensitivity of TiO2, but increasing dopant concentration leads to a decrease in photocatalytic activity.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Sapan K. Jain, Mohd Fazil, Nayeem Ahmad Pandit, Syed Asim Ali, Farha Naaz, Huma Khan, Amir Mehtab, Jahangeer Ahmed, Tokeer Ahmad
Summary: Cr-doped SnO2 nanostructures with a rutile tetragonal structure and rough morphology were successfully synthesized using low-temperature modified solvothermal method. Increasing dopant concentration resulted in a decrease in band gap and improved photocatalytic and electrochemical performance.
Article
Engineering, Environmental
Chun-Hui Shen, Yao Chen, Xin-Jie Xu, Xue-Yang Li, Xiao-Ju Wen, Zong-Tang Liu, Rong Xing, He Guo, Zheng-Hao Fei
Summary: The SnIn4S8/CeO2 (SISC) composites fabricated by a stirring and calcination method show promising photocatalytic activity under visible light, with good degradation effect on hexavalent chromium (Cr (VI)) and high hydrogen production efficiency.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Chemistry, Physical
Cui Lai, Fuhang Xu, Mingming Zhang, Bisheng Li, Shiyu Liu, Huan Yi, Ling Li, Lei Qin, Xigui Liu, Yukui Fu, Ning An, Hailan Yang, Xiuqin Huo, Xiaofeng Yang, Huchuan Yan
Summary: CeO2 nanoparticles were successfully loaded on carbonate doped Bi2O2CO3 (CBOC) nanosheets, forming a CeO2/CBOC heterojunction with significantly enhanced photocatalytic activity. The Z-scheme electron transfer mechanism and the Ce4+/Ce3+ redox pairs formed at the contact interface between CeO2 and CBOC were found to play critical roles in enhancing photocatalytic activity.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Chemistry, Physical
Haotian Li, Liang Xu, Xin Huang, Jie Ou-Yang, Min Chen, Ying Zhang, Shuaihao Tang, Kejun Dong, Ling-Ling Wang
Summary: This paper focuses on finding a new two-dimensional van der Waals heterojunction for hydrogen production through water splitting. A direct Z C3N/WS2 heterojunction was successfully designed, combining highly active two-dimensional transition metal dichalcogenides with C3N similar to graphene. The staggered band structure and high carrier mobility facilitate efficient separation of electron and hole pairs. Moreover, the C3N/WS2 heterojunction allows for total water splitting from pH = 0 to pH = 7, demonstrating excellent hydrogen and oxygen evolution capabilities. Overall, these studies provide new insights for designing high-performance photoelectric catalysts for visible-light water splitting.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Physics, Condensed Matter
Wen-Xia Yu, Bin Liu, Wei-Qing Huang, Hong Zhou, Sheng-Yi Xie
Summary: This study reveals the phase transformations and electrochemical properties changes during the oxidation process of bismuth selenide. The intermediate phase Bi2OSe2 may have potential applications in photovoltaics.
JOURNAL OF PHYSICS-CONDENSED MATTER
(2023)
Article
Chemistry, Physical
Liang Xu, Ji Tao, Bin Xiao, Feilong Xiong, Zongle Ma, Jian Zeng, Xin Huang, Shuaihao Tang, Ling-Ling Wang
Summary: Based on density functional theory, this study unexpectedly found that monolayers of AlN and C2N, g-C3N4, and C6N8 all formed type-II heterojunctions, which showed promising potential in photocatalytic applications. The AlN/C2N heterojunction demonstrated an appropriate band gap value for visible light water splitting and higher carrier mobility compared to other heterojunctions.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Bo Li, Zhi Tian, Lei Li, Yu-Han Wang, Yuan Si, Hui Wan, Jinghui Shi, Gui-Fang Huang, Wangyu Hu, Anlian Pan, Wei-Qing Huang
Summary: In this study, directional charge transfer channels were constructed using carbon dots/carbon nitride (CCN) nanotubes and FeOOH/FeCo layered double hydroxide (FFC) nanosheets, which significantly improved the photo-assisted overall water splitting performance. Experimental investigations and DFT calculations demonstrated that the interfacial C-O-Fe bonds between CCN and FFC served as charge transfer channels, facilitating the migration of photoexcited carriers between their surfaces. The in situ oxidized Fe/Co species triggered lattice oxygen activation, leading to the construction of the Fe-Co dual-site as the catalytic center and effectively lowering the energy barrier for water oxidation. As a result, the CCN@FFC electrode exhibited multiple functionalities in photoelectrocatalysis, achieving low overpotentials for photo-assisted hydrogen evolution, oxygen evolution, and overall water splitting.
Article
Chemistry, Physical
Jinghui Shi, Yi-Fei Yang, Yao Li, Hui Wan, Bo Li, Jianhang Nie, Meng -Yuan Xie, Gui-Fang Huang, Wei-Qing Huang
Summary: This study proposes a self-arrested strategy to rapidly grow nanowires in a cavity, constructing a hollow core-shell nanostructure nanoreactor. The structure fully utilizes the cavity, increases specific surface area and active sites, and improves electrical conductivity. Moreover, the nanomaterials exhibit enhanced oxygen evolution reaction activity and excellent durability. This work provides a novel strategy for the synergistic utilization of materials and topological structure in various applications.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Jinghui Shi, Wei Peng, Yi-Fei Yang, Bo Li, Jianhang Nie, Hui Wan, Yao Li, Gui-Fang Huang, Wangyu Hu, Wei-Qing Huang
Summary: A universal synthesis strategy is proposed for the fabrication of binary transition metal phosphides (TMPs) hollow sandwich heterostructures. Through density functional theory (DFT) calculation, the growth process and mechanism of layered double hydroxide (LDH) on Prussian blue analog (PBA) surface are revealed. This unique structure combines the advantages of sandwich, hollow, and vertical heterostructures, achieving a synergistic effect.
Article
Materials Science, Multidisciplinary
Yanwen Wang, Yunxin Zheng, Jianrong Xiao, Liang Xu, Xueqiong Dai, Zhiyong Wang
Summary: In this paper, the authors investigated the adsorption behavior of toxic nitrogenous gas molecules on arsenene with adsorbed transition metal atoms using first-principles methods. It was found that the adsorption of transition metal atoms enhances the interaction between the gas molecules and the substrate. The systems with Ti or Zr adsorbed showed the best adsorption energy and charge transfer. Most of the systems retained their semiconductor properties, except for the Zr-Arsenene with nitric oxide adsorbed, which exhibited metallic properties. The adsorption of NO and NO2 induced magnetism in the system. Additionally, uniaxial strain could change the adsorption strength and adjust the NO2 sensing characteristics of arsenene. The authors suggest that arsenene with transition metal adsorbed is a potential candidate for detecting nitrogen-containing toxic gas molecules.
Article
Physics, Applied
Xue-Ying Liu, Haohao Bi, Lei Li, Bo Li, Yu-Han Wang, Jinghui Shi, Jianhang Nie, Gui-Fang Huang, Wangyu Hu, Wei-Qing Huang
Summary: In this study, single-crystalline cobalt carbonate hydroxide hydrate (CCOH) nanowires with high oxygen evolution reaction (OER) activity were prepared using a doping-induced facet transformation strategy. The Cu-doped (020)-faceted CCOH nanowire arrays exhibited outstanding OER performances with a low overpotential of 210mV at 10mA cm(-2) and a Tafel slope of 67mV dec(-1) in alkaline medium, as well as extremely long-term durability over 36 h. The findings demonstrate that doping-induced facet engineering is an effective strategy to design and develop highly active catalysts.
APPLIED PHYSICS LETTERS
(2023)
Article
Chemistry, Physical
Haotian Li, Min Chen, Kai-Wu Luo, Xin Huang, Shuaihao Tang, Ling-Ling Wang, Liang Xu
Summary: The design and analysis of SiC/RGO and GaN/RGO heterojunctions using first-principles hybrid density functional theory reveals that the GaN/RGO heterojunction has better band gap reduction and light absorption capacity compared to the SiC/RGO heterojunction. It also meets the requirements for photocatalytic water splitting, leading to enhanced photocatalytic performance.
Article
Materials Science, Multidisciplinary
Luzhen Xie, Tong Chen, Xiansheng Dong, Haipeng Wang, Liang Xu, Guanghui Zhou
Summary: In this study, the spin-dependent transport properties of nanodevices based on zigzag graphene nanoribbons bridged by oblique, horizontal, and vertical connecting biphenyl molecules were investigated. The superb transport results showed almost 100% spin polarization for oblique and horizontal connecting devices in the parallel state, and excellent dual spin filtering efficiency and rectification effect in the antiparallel state. Furthermore, a pronounced negative differential resistance effect and thermal spin transport properties were observed. The study provides new insights into the design of multifunctional spin carbon-based and low-power consumption devices.
Article
Chemistry, Multidisciplinary
Yu-Han Wang, Lei Li, Jinghui Shi, Meng-Yuan Xie, Jianhang Nie, Gui-Fang Huang, Bo Li, Wangyu Hu, Anlian Pan, Wei-Qing Huang
Summary: This study proposes a method to enhance the OER activity of NiFe-based hydroxides by modulating oxygen defects. The results show that proper oxygen defects can promote the synergy between adsorbate evolution mechanism and single lattice oxygen mechanism, maximizing the use of surface metal and oxygen atoms as active sites and improving electrocatalytic activity.
Article
Materials Science, Multidisciplinary
Yu-Han Wu, Jia-Cheng Luo, Jing Zhang, Zi-Cheng He, Yu Lan, Gui-Fang Huang, Wangyu Hu, Wei-Qing Huang
Summary: This article proposes a novel strategy of functionalization and external electric fields to tune the metal-semiconductor contact nature in MXene-based vdW heterostructures. It reveals the potential of MXenes in future nanoelectronics and optoelectronics.
RESULTS IN PHYSICS
(2023)
Article
Materials Science, Multidisciplinary
Hang Liu, Liang Xu, Zongle Ma, Zhengquan Li, Haotian Li, Ying Zhang, Bo Zhang, Ling -Ling Wang
Summary: The bandgap of semiconductor materials can be accurately predicted using machine learning methods, with an average absolute error of 0.142 eV and a coefficient of determination of 0.977 achieved through feature processing using density functional theory. The federal learning framework is employed to forecast bandgap under different experimental conditions for small-sample datasets, with bandgap errors of compound semiconductor materials at 2-10% and 2D heterojunction semiconductor materials at 5-30%.
MATERIALS TODAY COMMUNICATIONS
(2023)