4.7 Article

Experimental investigation of two-phase gas-oil stratified flow wax deposition in pipeline

期刊

FUEL
卷 247, 期 -, 页码 113-125

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2019.03.032

关键词

Two-phase system; Stratified flow; Paraffin deposition; Heat and mass transfer

向作者/读者索取更多资源

Wax deposition in the onshore and offshore pipelines is a common occurrence and typically disturbs the transportation of oil and gas. Accurate prediction of wax deposition in multiphase flow is of great importance to develop economical prevention and remediation strategies. However, reliable experimental data is lacking to understand the deposition process and validate the existing prediction models. In this work, two-phase gas-oil stratified flow wax deposition data at various liquid and gas flow rates have been obtained using Garden Banks condensate and natural gas in a 52.5-mm I.D. multiphase flow loop under the pressure of 2.41 MPa. It is evident that both deposit mass and wax content increase as superficial gas and liquid velocities increase. In addition, the deposit mass per unit area and wax content have a strong correlation with the actual liquid velocity deduced from superficial velocities. The local deposits are observed to be thinner but harder at the sides compared to the bottom of the pipe. The local deposit composition is also analyzed using high temperature gas chromatography (HTGC), revealing that the effect of v(SG) and v(SL) on the side deposits is more predominant than the bottom. It can be seen that the fraction of the high carbon number components increases as the superficial velocities increases. However, the increase due to the increase of v(SG) is more distinct compared to the v(SL) effect. Moreover, it has been observed that the local wax mass flux increases along the circumferential direction, namely, from the bottom towards the gas-liquid interface. Local deposit analysis in the circumferential direction provided insights to enhance our understanding on the deposition behavior and aid to improve or develop appropriate models.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Energy & Fuels

Effect of Salts on TBAB Semi Clathrate Hydrate Formation: Application to Produced Water Desalination

Aziz Alhejaili, Ponnivalavan Babu, Nagu Daraboina

ENERGY & FUELS (2020)

Article Energy & Fuels

Wax deposition mechanisms: Is the current description sufficient?

Jinghao Yang, Yingda Lu, Nagu Daraboina, Cem Sarica

Article Engineering, Chemical

Effects of high oil viscosity on oil-gas downward flow in deviated pipes. Part 1: Experimental setup and flow pattern transitions

Gabriel Soto-Cortes, Eduardo Pereyra, Cem Sarica, Fabian Rivera-Trejo, Carlos Torres

Summary: This work provides new experimental data on high viscosity oil-gas flow, analyzing the effects of pipe inclination and liquid viscosity on flow pattern transitions and characterizing subclasses of annular flow pattern. Comparisons with existing models show disagreements, highlighting the need for further studies on the effects of viscosity and pipe inclination in liquid-gas downward flow mixtures.

CANADIAN JOURNAL OF CHEMICAL ENGINEERING (2021)

Article Engineering, Chemical

Effects of high oil viscosity on oil-gas downward flow in deviated pipes. Part 2: Holdup and pressure gradient

Gabriel Soto-Cortes, Eduardo Pereyra, Cem Sarica, Fabian Rivera-Trejo, Carlos Torres

Summary: This study investigates the holdup and pressure gradient behavior of high viscosity oil-gas flow in inclined downward flow, highlighting the transport mechanism through phase slippage and mechanical energy balance. Performance analysis of available mechanistic models reveals the need for a detailed study of the effects of viscosity and pipe inclination in liquid-gas mixtures.

CANADIAN JOURNAL OF CHEMICAL ENGINEERING (2021)

Article Energy & Fuels

Energy Analysis of Methane-Hydrate-Based Produced Water Desalination

Ponnivalavan Babu, Chandradeep Bollineni, Nagu Daraboina

Summary: Managing produced water is a significant environmental issue in the energy industry, with reverse osmosis and thermal distillation being commonly used techniques. Hydrate-based desalination shows promise as a low energy option, with external refrigeration identified as a major contributor to energy consumption.

ENERGY & FUELS (2021)

Review Energy & Fuels

Review of Asphaltene Deposition Modeling in Oil and Gas Production

Ahmed Al-Hosani, Sriram Ravichandran, Nagu Daraboina

Summary: The study provides a comprehensive review of asphaltene deposition modeling and discusses potential improvements for current models. It highlights the impact of asphaltene precipitation on pore blockage, particle size increase, and production decline, emphasizing the importance of understanding asphaltene structure and thermodynamic properties. By comparing models in the literature, it points out the need for further improvement in the universality of different models.

ENERGY & FUELS (2021)

Review Energy & Fuels

Thermal methods in flow assurance: A review

Elijah Bell, Yingda Lu, Nagu Daraboina, Cem Sarica

Summary: Solid deposition in flow-lines poses a significant challenge for offshore operations, leading to reduced production and increased costs when flow blockage occurs. Thermal management methods, including passive and active approaches, have been developed to ensure flow during production. Passive methods involve insulation and pipeline burial, while active methods require heating techniques to maintain or raise the temperature of the fluid.

JOURNAL OF NATURAL GAS SCIENCE AND ENGINEERING (2021)

Editorial Material Energy & Fuels

Response to Comments on Effect of Salts on TBAB Semi Clathrate Hydrate Formation: Application to Produced Water Desalination

Aziz Alhejaili, Nagu Daraboina

Summary: The original paper mainly focused on the thermodynamic equilibrium of semiclathrate hydrate formation in the presence of salts common in produced water, finding that TBAB hydrate formation is highly favorable. While there were criticisms of some inaccuracies and omissions in the paper, we believe they were based on a misunderstanding of our objectives and analysis, and acknowledge the need for more information in the original paper.

ENERGY & FUELS (2021)

Article Energy & Fuels

Experimental Investigation of active heating in removal of wax deposits

Elijah Bell, Yingda Lu, Nagu Daraboina, Cem Sarica

Summary: Active heating is found to be an effective method for controlling wax deposition in offshore flow-lines, with wax deposits being removed completely, partially, or not at all at different temperatures. The majority of wax can be swiftly removed within an hour, while higher removal temperatures are needed for deposits with higher wax content. In contrast to softer wax, the removal of harder wax seems to occur in two steps, with sudden removal followed by a period of no removal before sudden removal again.

JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING (2021)

Article Energy & Fuels

Dynamic Microscopic Study of Wax Deposition: Particulate Deposition

Gabriel Santos, Nagu Daraboina, Cem Sarica

Summary: This study aims to unravel the wax deposition mechanisms by investigating the effect of flow rate on the particulate deposition mechanism. It confirms the existence of the particulate deposition mechanism and observes a stronger mechanism under laminar and transition flow regimes. The study also shows that deposit thickness and growth rate are considerably greater under lower Reynolds numbers.

ENERGY & FUELS (2021)

Article Engineering, Mechanical

Signal processing for slug flow analysis via a voltage or instantaneous liquid holdup time-series

Gabriel Soto-Cortes, Eduardo Pereyra, Cem Sarica, Carlos Torres, Auzan Soedarmo

Summary: Slug flow is a common gas-liquid flow pattern in pipes, and its characteristics play a crucial role in engineering processes. This paper presents a new signal processing analysis method that utilizes statistical algorithms to accurately determine slug flow characteristics, with validation from experimental data showing good results. The proposed algorithm is recommended for slug flow characterization based on its performance against the experimental data.

FLOW MEASUREMENT AND INSTRUMENTATION (2021)

Article Engineering, Chemical

Particulate Deposition Modeling for Predicting Paraffin Thickness in Flowlines: Application of Data Analytics for Model Parameters

Nagu Daraboina, Ahmed Alhosani

Summary: This study developed a mechanistic model and conducted a sensitivity analysis to predict wax deposition in flowlines. Results showed that the deposition rate increased with increasing pipe diameter, decreasing particle size, and reducing flow rate.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2021)

Article Chemistry, Multidisciplinary

Experimental Study on Hydrate Structure Transition Using an In Situ High-Pressure Powder X-ray Diffractometer: Application in CO2 Capture

Asheesh Kumar, Nagu Daraboina, Praveen Linga, Rajnish Kumar, John A. Ripmeester

Summary: Gas hydrates, such as sH and sI hydrates, have potential for gas separation applications, with sH hydrates requiring large molecules and help-gas molecules to form stable structures. Testing different compositions showed that CO2 lean mixtures form sH hydrates, while CO2-rich mixtures form sI hydrates, indicating a structure transition pattern across gas mixtures. Furthermore, it was observed that the CO2 lean mixture initially forms sI hydrate and gradually converts to the thermodynamically stable sH hydrate, providing insights into a suitable gas separation mechanism for this gas mixture.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

Article Engineering, Chemical

Effect of Chloride Salts on TBAC Semiclathrate Hydrates: Application to Produced Water Desalination

Aziz Alhejaili, Ponnivalavan Babu, Nagu Daraboina

Summary: Clathrate hydrate applications have increased significantly, and one promising application is produced water purification. However, limitations such as high temperature and slow kinetics have persisted. This study investigates the effect of prevalent salts on the equilibrium of TBAC hydrates and finds that lower TBAC concentrations have better tolerance to higher contaminant concentrations. Additionally, operating at lower TBAC concentrations in high salinity water provides optimal water recovery.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2023)

Article Mechanics

Taylor bubble velocity in transition from pipe to annulus geometry

Vinicius Kramer Scariot, Eduardo Pereyra, Cem Sarica

Summary: The present study focuses on characterizing and modeling the Taylor bubble front and tail velocities in a pipe-to-annulus transition geometry. A new non-invasive method to measure liquid distribution using computer vision was developed. The results show that the Taylor bubble front velocity is dictated by drift, while the tail velocity is related to the liquid fallback rate and bubble coalescence. The choice of characteristic dimension has an important impact on the velocity measurement.

INTERNATIONAL JOURNAL OF MULTIPHASE FLOW (2023)

Article Energy & Fuels

Preparation of surface modified nano-hydrotalcite and its applicaiton as a flow improver for crude oil

Yingna Du, Chen Huang, Wei Jiang, Qiangwei Yan, Yongfei Li, Gang Chen

Summary: In this study, anionic surfactants modified hydrotalcite was used as a flow improver for crude oil under low-temperature conditions. The modified hydrotalcite showed a significant viscosity reduction effect on crude oil. The mechanism of the modified hydrotalcite on viscosity and pour point of crude oil was explored through characterization and analysis of the modified hydrotalcite and oil samples.
Article Energy & Fuels

Effect of incorporated hybrid MIL-53(Al) and MWCNT into PES membrane for CO2/CH4 and CO2/N2 separation

Mohammad Saeid Rostami, Mohammad Mehdi Khodaei

Summary: In this study, a hybrid structure, MIL-53(Al)@MWCNT, was synthesized by combining MIL-53(Al) particles and -COOH functionalized multi-walled carbon nanotube (MWCNT). The hybrid structure was then embedded in a polyethersulfone (PES) polymer matrix to prepare a mixed matrix membrane (MMM) for CO2/CH4 and CO2/N2 separation. The addition of MWCNTs prevented MIL-53(Al) aggregation, improved membrane mechanical properties, and enhanced gas separation efficiency.
Article Energy & Fuels

Phase behaviour and physical properties of dimethyl ether (DME)/flue gas/ water/heavy oil systems under reservoir conditions

Yunlong Li, Desheng Huang, Xiaomeng Dong, Daoyong Yang

Summary: This study develops theoretical and experimental techniques to determine the phase behavior and physical properties of DME/flue gas/water/heavy oil systems. Eight constant composition expansion (CCE) tests are conducted to obtain new experimental data. A thermodynamic model is used to accurately predict saturation pressure and swelling factors, as well as the phase boundaries of N2/heavy oil systems and DME/CO2/heavy oil systems, with high accuracy.
Article Energy & Fuels

Comparison of CO2 absorption in DETA solution and [bmim]-[PF6] using thermodynamic and process modelling

Morteza Afkhamipour, Ebad Seifi, Arash Esmaeili, Mohammad Shamsi, Tohid N. Borhani

Summary: Non-conventional amines are being researched worldwide to overcome the limitations of traditional amines like MEA and MDEA. Adequate process and thermodynamic models are crucial for understanding the applicability and performance of these amines in CO2 absorption, but studies on process modeling for these amines are limited. This study used rate-based modeling and Deshmukh-Mather method to model CO2 absorption by DETA solution in a packed column, validated the model with experimental data, and conducted a sensitivity analysis of mass transfer correlations. The study also compared the CO2 absorption efficiency of DETA solution with an ionic solvent [bmim]-[PF6] and highlighted the importance of finding optimum operational parameters for maximum absorption efficiency.
Article Energy & Fuels

Interfacial tension of smart water and various crude oils

Arastoo Abdi, Mohamad Awarke, M. Reza Malayeri, Masoud Riazi

Summary: The utilization of smart water in EOR operations has gained attention, but more research is needed to understand the complex mechanisms involved. This study investigated the interfacial tension between smart water and crude oil, considering factors such as salt, pH, asphaltene type, and aged smart water. The results revealed that the hydration of ions in smart water plays a key role in its efficacy, with acidic and basic asphaltene acting as intrinsic surfactants. The pH also influenced the interfacial tension, and the aged smart water's interaction with crude oil depended on asphaltene type, salt, and salinity.
Article Energy & Fuels

Co-based metal-organic frameworks confined N-hydroxyphthalimide for enhancing aerobic desulfurization of diesel fuels

Dongao Zhu, Kun Zhu, Lixian Xu, Haiyan Huang, Jing He, Wenshuai Zhu, Huaming Li, Wei Jiang

Summary: In this study, cobalt-based metal-organic frameworks (Co-based MOFs) were used as supports and co-catalysts to confine the NHPI catalyst, solving the leaching issue. The NHPI@Co-MOF with carboxyl groups exhibited stronger acidity and facilitated the generation of active oxygen radicals O2•, resulting in enhanced catalytic activity. This research provides valuable insights into the selection of suitable organic linkers and broadens the research horizon of MOF hybrids in efficient oxidative desulfurization (ODS) applications.
Article Energy & Fuels

Influence of carbon-coated zero-valent iron-based nanoparticle concentration on continuous photosynthetic biogas upgrading

Edwin G. Hoyos, Gloria Amo-Duodu, U. Gulsum Kiral, Laura Vargas-Estrada, Raquel Lebrero, Rail Munoz

Summary: This study investigated the impact of carbon-coated zero-valent nanoparticle concentration on photosynthetic biogas upgrading. The addition of nanoparticles significantly increased microalgae productivity and enhanced nitrogen and phosphorus assimilation. The presence of nanoparticles also improved the quality of biomethane produced.
Article Energy & Fuels

Effect of aqueous phase recycling on iron evolution and environmental assessment during hydrothermal carbonization of dyeing sludge

Yao Xiao, Asma Leghari, Linfeng Liu, Fangchao Yu, Ming Gao, Lu Ding, Yu Yang, Xueli Chen, Xiaoyu Yan, Fuchen Wang

Summary: Iron is added as a flocculant in wastewater treatment and the hydrothermal carbonization (HTC) of sludge produces wastewater containing Fe. This study investigates the effect of aqueous phase (AP) recycling on hydrochar properties, iron evolution and environmental assessment during HTC of sludge. The results show that AP recycling process improves the dewatering performance of hydrochar and facilitates the recovery of Fe from the liquid phase.
Article Energy & Fuels

Investigation on the lower flammability limit and critical inhibition concentration of hydrogen under the influence of inhibitors

He Liang, Tao Wang, Zhenmin Luo, Jianliang Yu, Weizhai Yi, Fangming Cheng, Jingyu Zhao, Xingqing Yan, Jun Deng, Jihao Shi

Summary: This study investigated the influence of inhibitors (carbon dioxide, nitrogen, and heptafluoropropane) on the lower flammability limit of hydrogen and determined the critical inhibitory concentration needed for complete suppression. The impact of inhibitors on explosive characteristics was evaluated, and the inhibitory mechanism was analyzed with chemical kinetics. The results showed that with the increase of inhibitor quantity, the lower flammability limit of hydrogen also increased. The research findings can contribute to the safe utilization of hydrogen energy.
Article Energy & Fuels

Phosphotungstic acid supported on Zr-SBA-15 as an efficient catalyst for one-pot conversion of furfural to ?-valerolactone

Zonghui Liu, Zhongze Zhang, Yali Zhou, Ziling Wang, Mingyang Du, Zhe Wen, Bing Yan, Qingxiang Ma, Na Liu, Bing Xue

Summary: In this study, high-performance solid catalysts based on phosphotungstic acid (HPW) supported on Zr-SBA-15 were synthesized and evaluated for the one-pot conversion of furfural (FUR) to γ-valerolactone (GVL). The catalysts were characterized using various techniques, and the ratio of HPW and Zr was found to significantly affect the selectivity of GVL. The HPW/Zr-SBA-15 (2-4-15) catalyst exhibited the highest GVL yield (83%) under optimized reaction conditions, and it was determined that a balance between Bronsted acid sites (BAS) and Lewis acid sites (LAS) was crucial for achieving higher catalytic performance. The reaction parameters and catalyst stability were also investigated.
Article Energy & Fuels

Experimental study of droplet vaporization for conventional and renewable transportation fuels: Effects of physical properties and chemical composition

Michael Stoehr, Stephan Ruoff, Bastian Rauch, Wolfgang Meier, Patrick Le Clercq

Summary: As part of the global energy transition, an experimental study was conducted to understand the effects of different fuel properties on droplet vaporization for various conventional and alternative fuels. The study utilized a flow channel to measure the evolution of droplet diameters over time and distance. The results revealed the temperature-dependent effects of physical properties, such as boiling point, liquid density, and enthalpy of vaporization, and showed the complex interactions of preferential vaporization and temperature-dependent influences of physical properties for multi-component fuels.
Article Energy & Fuels

An experimental and modeling study on the oxidation of ammonia-methanol mixtures in a jet stirred reactor

Yuan Zhuang, Ruikang Wu, Xinyan Wang, Rui Zhai, Changyong Gao

Summary: Through experimental validation and optimization of the chemical kinetic model, it was found that methanol can accelerate the oxidation reaction of ammonia, and methanol can be rapidly oxidized at high concentration. HO2 was found to generate a significant amount of OH radicals, facilitating the oxidation of methanol and ammonia. Rating: 7.5/10.
Article Energy & Fuels

Improving the biodiesel combustion and emission characteristics in the lean pre-vaporized premixed system using diethyl ether as a fuel additive

Radwan M. EL-Zohairy, Ahmed S. Attia, A. S. Huzayyin, Ahmed I. EL-Seesy

Summary: This paper presents a lab-scale experimental study on the impact of diethyl ether (DEE) as an additive to waste cooking oil biodiesel with Jet A-1 on combustion and emission features of a swirl-stabilized premixed flame. The addition of DEE to biodiesel significantly affects the flame temperature distribution and emissions. The W20D20 blend of DEE, biodiesel, and Jet A-1 shows similar flame temperature distribution to Jet A-1 and significantly reduces UHC, CO, and NOx emissions compared to Jet A-1.
Article Energy & Fuels

Condensation characteristics of ammonia vapor during supersonic separation: A novel approach to ammonia-hydrogen separation

Jiang Bian, Ziyuan Zhao, Yang Liu, Ran Cheng, Xuerui Zang, Xuewen Cao

Summary: This study presents a novel method for ammonia separation using supersonic flow and develops a mathematical model to investigate the condensation phenomenon. The results demonstrate that the L-P nucleation model accurately characterizes the nucleation process of ammonia at low temperatures. Numerical simulations also show that increasing pressure and concentration can enhance ammonia condensation efficiency.
Article Energy & Fuels

Multivariate time series prediction for CO2 concentration and flowrate of flue gas from biomass-fired power plants

Shiyuan Pan, Xiaodan Shi, Beibei Dong, Jan Skvaril, Haoran Zhang, Yongtu Liang, Hailong Li

Summary: Integrating CO2 capture with biomass-fired combined heat and power (bio-CHP) plants is a promising method for achieving negative emissions. This study develops a reliable data-driven model based on the Transformer architecture to predict the flowrate and CO2 concentration of flue gas in real time. The model validation shows high prediction accuracy, and the potential impact of meteorological parameters on model accuracy is assessed. The results demonstrate that the Transformer model outperforms other models and using near-infrared spectral data as input features improves the prediction accuracy.