期刊
APPLIED ORGANOMETALLIC CHEMISTRY
卷 31, 期 4, 页码 -出版社
WILEY
DOI: 10.1002/aoc.3585
关键词
Antimicrobial; antioxidant; complexes; DNA binding; Schiff base
资金
- Science & Engineering Research Board (SERB), DST, New Delhi
Four novel copper(II) complexes of 2-aminobenzimidazole derivatives (obtained from the Knoevenagel condensation of acetylacetone (obtained from acetylacetone and halogen-substituted benzaldehydes) and 2-aminobenzimidazole) were synthesized. They were characterized using elemental analysis, molar conductance measurements, and fast atom bombardment mass, Fourier transform infrared, NMR, UV-visible and electron paramagnetic resonance spectroscopies. On the basis of the spectral studies, a distorted square planar geometry was assigned for all the complexes. The antibacterial screening of the ligands and their complexes revealed that all the complexes had higher activities than the free ligands. Superoxide dismutase and antioxidant activities of the copper complexes were also studied. The shifts in E-p, E-1/2, I-pc and I-pa values were explored for the interaction of the complexes with calf thymus DNA using the electrochemical technique.
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