期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 25, 期 58, 页码 13271-13274出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201902557
关键词
acceptorless dehydrogenation; dehydrogenation; homogenous catalysis; nitrile; ruthenium
资金
- Region Grand Est
A dehydrogenation of primary amine to give the corresponding nitrile under oxidant- and base-free conditions catalysed by simple [Ru(p-cym)Cl-2](2) with no extra ligand is reported. The system is highly selective for alkyl amines, whereas benzylamine derivatives gave the nitrile product together with the imine in a ratio ranging from 14:1 to 4:1 depending on the substrate. Preliminary mechanistic investigations have been performed to identify the key factors that govern the selectivity.
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