期刊
CERAMICS INTERNATIONAL
卷 45, 期 17, 页码 22699-22706出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2019.07.307
关键词
CsPb1-xZnxBr3 NCs; Glass; Environment friendly; White LED
资金
- National Natural Science Foundation of China of China [51872207]
Inorganic perovskite nanocrystals (NCs) doped with metal ions have received much attention due to their superior optoelectronic properties and environment friendly. Here, we synthesized Zn-doped CsPbBr3 perovskite NCs in borosilicate glass by melt-quenching. When ZnBr2 and PbBr2 were in half, the fluorescence intensity was enhanced, and the PLQYs increased from 32 to 36%. Under the excitation of 460 nm blue chip, white LED (WLED) was fabricated by using Zn-doped CsPbBr3 NCs glass and red phosphor powder CaAlSiN3:Eu2+. The experimental results show that the photoelectric parameters of the constructed white LED are considerable, among which the luminous efficacy (LE) is 70.1 lm/W, and a high LE is 72.79. However, pure CsPbBr3 has a low LE value of 26.1 lm/W and a CRI value of 76.9 Zn2+ doped CsPbBr3 can reduce the toxicity of materials and can be used to prepare high-performance optical devices. The study showed a new doped chemical model system for various optoelectronic applications.
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