4.7 Article

Synthesis and pyrolysis mechanism of a novel polymeric precursor for SiBN ternary ceramic fibers

期刊

CERAMICS INTERNATIONAL
卷 45, 期 16, 页码 20172-20177

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2019.06.286

关键词

Polymeric precursor; Pyrolysis mechanism; High-temperature behavior; SiBN ceramic fibers

资金

  1. National Natural Science Foundation of China [51703025]
  2. Fundamental Research Funds for the Central Universities [2232019D3-06, 2232019G-02]

向作者/读者索取更多资源

A novel polymeric precursor polyborosilazane (PBSZ) for SiBN ternary ceramic fibers was successfully synthesized from trichlorosilane (HSiCl3), boron trichloride (BCl3) and hexamethyldisilazane (HDMZ) by a simple one step reaction process. The chemical structures and ceramic yield of the PBSZ precursors were investigated by NMR spectroscopy, FT-IR and TGA. The preparation of PBSZ fibers was conducted in a lab-scale melt-spinning equipment at a spinning speed of 130 m/min. SiBN ternary ceramic fibers were obtained after the non-fusible treatment and pyrolysis of PBSZ fibers in an NH3 atmosphere. The pyrolysis mechanism, high-temperature behavior and morphologies of the SiBN ternary ceramic fibers were investigated by NMR, XRD, TEM and SEM. The obtained SiBN ternary ceramic fibers had good flexibility, and possessed a tensile strength of 0.84 GPa with a diameter of 18 pm. Furthermore, these SiBN ceramic fibers exhibited excellent thermal stability, and maintained the amorphous state up to 1600 degrees C.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据