期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 35, 页码 12286-12290出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201906692
关键词
alkenes; multicomponent reactions; nickel; photochemistry; reaction mechanisms
资金
- European Research Council (ERC) [307948]
- Swiss National Science Foundation [200020_146853]
- Swiss National Science Foundation (SNF) [200020_146853] Funding Source: Swiss National Science Foundation (SNF)
The potential of merging photoredox and nickel catalysis to perform multicomponent alkene difunctionalizations under visible-light irradiation is demonstrated here. Secondary and tertiary alkyl groups, as well as sulfonyl moieties can be added to the terminal position of the double bond with simultaneous arylation of the internal carbon atom in a single step under mild reaction conditions. The process, devoid of stoichiometric additives, benefits from the use of bench-stable and easy-to-handle reagents, is operationally simple, and tolerates a wide variety of functional groups.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据