Article
Chemistry, Physical
Daichi Takami, Junya Tsubakimoto, Wirya Sarwana, Akira Yamamoto, Hisao Yoshida
Summary: The design of optimized photothermal catalysts is essential for the efficient conversion of CO2 into syngas using solar energy. This study demonstrated that silica-supported nickel catalysts prepared via Ni phyllosilicate exhibited superior catalytic performance and resistance to sintering and carbon deposition under visible and near-infrared light. The loading of nickel had positive and negative effects on the surface temperature and light absorption capacity, which influenced the photothermal catalytic activity for methane dry reforming.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Euiseob Yang, Eonu Nam, Yoonjeong Jo, Kwangjin An
Summary: Core@shell Ni@Co and bimetallic alloyed Ni-Co nanoparticles with controlled Co/Ni compositions were supported on CeO2 for catalytic dry reforming of methane (DRM). Increasing the Co/Ni ratio reduced coke deposition while maintaining catalytic activity. However, a Co/Ni ratio > 1 caused a rapid decrease in activity.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Chemistry, Physical
Sonali Das, Ashok Jangam, Shanmukapriya Jayaprakash, Shibo Xi, Kus Hidajat, Keiichi Tomishige, Sibudjing Kawi
Summary: Sandwich structured core-shell Ni-Phyllosilicate@Ce1-xZrxO2 catalysts with optimal Zr loading in the Ce1-xZrxO2 shell are found to greatly enhance the intrinsic activity for DRM due to increased lattice oxygen mobility of the ceria-zirconia shell and stronger metal-support interaction with Ni. Involvement of lattice oxygen in methane activation and dissociation contributes to the higher DRM activity of the Zr-doped catalyst with maximum oxygen storage capacity, as inferred from rigorous kinetic and mechanism studies.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Chemistry, Physical
Marcin Cichy, Monika Panczyk, Grzegorz Slowik, Witold Zawadzki, Tadeusz Borowiecki
Summary: Methane reforming with CO2 is a hot research topic due to the increasing demand for new hydrogen sources. In this study, a series of commercial nickel catalysts supported on a-Al2O3 and modified with different amounts of rhenium were investigated. The addition of rhenium positively influenced the stability and activity of the catalyst, and the formation of Ni-Re alloy played a significant role in enhancing its properties.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Mohammadreza Kosari, Saeed Askari, Abdul Majeed Seayad, Shibo Xi, Sibudjing Kawi, Armando Borgna, Hua Chun Zeng
Summary: Hollow nanocatalysts with optimal shell thickness play a crucial role in enhancing reactant conversion and preventing coking hindrance during methane dry reforming reaction.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Chemistry, Multidisciplinary
Ekaterina Smal, Yulia Bespalko, Marina Arapova, Valeria Fedorova, Konstantin Valeev, Nikita Eremeev, Ekaterina Sadovskaya, Tamara Krieger, Tatiana Glazneva, Vladislav Sadykov, Mikhail Simonov
Summary: Two series of Ni/Ce(Ti/Nb)ZrO2 catalysts were prepared using different synthesis methods and studied in dry reforming of methane. The composition of the support and the preparation method were found to influence the morphology and surface features of the catalysts. The addition of Ti increased the amount of carbon, while the use of supercritical supports resulted in a higher amount of coke. All compositions of catalysts showed similar carbon deposits in DRM.
Article
Chemistry, Multidisciplinary
Sungjoon Kweon, Hyejin An, Chae-Ho Shin, Min Bum Park, Hyung-Ki Min
Summary: N-ZSM-5 and N-beta zeolites with enhanced basic properties were prepared by substituting the framework oxygen with nitrogen using high temperature nitridation with ammonia. These basic zeolites, impregnated with Ni, showed superior DRM activity, especially at high temperature, due to enhanced basic property and dispersion of Ni active species.
JOURNAL OF CO2 UTILIZATION
(2021)
Article
Chemistry, Physical
Morgana Rosset, Liliana Amaral Feris, Oscar W. Perez-Lopez
Summary: Incorporating Mg or Zn into NiAl-LDH for reconstruction using a memory effect improved the catalytic activity and stability in the dry reforming of Biogas. The washing step significantly affected LDH reconstruction, with different metals influencing the properties of the materials. Ni-Zn alloy formation in Zn-reconstructed catalysts led to the best performance in methane and carbon dioxide conversion with a H-2/CO ratio of approximately 2.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Zhoufeng Bian, Wenqi Zhong, Yang Yu, Zhigang Wang, Bo Jiang, Sibudjing Kawi
Summary: Catalysts of Ni supported on home-made mesoporous alumina exhibited high activity and stability in DRM, with NiAl2O4 spinel structure contributing to improved performance. Control of calcination temperature is crucial for catalyst properties.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Energy & Fuels
Junjie Wen, Yu Xie, Yanping Ma, Haiyang Sun, Huimin Wang, Mo Liu, Qiulin Zhang, Jianjun Chen
Summary: Ni-CeZrAl catalyst prepared by co-precipitation method demonstrated high performance in dry reforming of methane, with the highest methane conversion reaching 38.1%. The superior catalytic behavior was attributed to the high dispersion of surface Ni-0 active phase, abundant oxygen vacancies, and basic sites. In contrast, Ni-CeAl and Ni-CeZr showed inferior catalytic performance due to weak interaction and fewer active sites.
Article
Environmental Sciences
Longzhi Li, Jian Chen, Yue Zhang, Jifu Sun, Guifu Zou
Summary: The bimetallic catalysts supported on coconut shell activated carbon show enhanced catalytic stability with an explicit Ni:Co ratio of 2:1, synergistic effects for CH4 and CO2 conversions with ratios of 1:2 and 1:1, and significantly improved conversions of methane and carbon dioxide at 900 degrees C.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Chemistry, Applied
Yao Lu, Dan Guo, Yifan Zhao, Perseverence S. Moyo, Yujun Zhao, Shengping Wang, Xinbin Ma
Summary: The novel structured catalyst Ni@S2-T, designed and synthesized through a unique two-step method, exhibited optimal catalytic activity and stability for dry reforming of methane (DRM). It showed remarkable anti-coking ability during prolonged testing, making it a promising candidate for DRM reactions.
MICROPOROUS AND MESOPOROUS MATERIALS
(2021)
Article
Chemistry, Applied
Min Li, Ziwei Li, Qian Lin, Jianxin Cao, Fei Liu, Ming Hui Wai, Sibudjing Kawi
Summary: In this study, the authors synthesized a cubic CeO2 yolk Ni phyllosilicate shell catalyst with excellent catalytic performance for methane dry reforming reaction. The unique structure of the catalyst mitigates agglomeration of Ni nanoparticles and provides intimate interaction between reactant gases and the catalyst, resulting in superior catalytic performance compared to other catalysts.
Article
Chemistry, Applied
Yanli Huang, Xiaodong Li, Qian Zhang, Vladimir A. Vinokurov, Wei Huang
Summary: Pressurized dry reforming of methane (DRM) is highly desirable for its economic and efficient benefits, but the risk of catalyst carbon deposition is a concern. This study explored the use of hydrotalcite-derived Ni-Ir/MgAl(O) catalysts with different Ir/Ni molar fractions to enhance stability and carbon tolerance in pressurized DRM reactions. The addition of Ir was found to improve catalyst performance and inhibit carbon deposition, leading to improved durability and resistance to coke formation in high pressure DRM processes.
FUEL PROCESSING TECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Qi Song, Rui Ran, Xiaodong Wu, Zhichun Si, Duan Weng
Summary: Dry reforming of methane is an efficient way to utilize carbon dioxide. This study utilized mesoporous silica support SBA-15 and microporous silica support beta as catalyst supports, and obtained highly dispersed Ni nanoparticles on Ni-SBA-15 and Ni-beta catalysts prepared by ammonia evaporation method. The Ni-SBA-15 and Ni-beta catalysts showed excellent catalytic activity, with a CO2 conversion of ca. 89 % and a CH4 conversion of ca. 84 % at 700 degrees C and nearly 100 % conversions at 800 degrees C. The mesopores of SBA-15 provided confinement for Ni nanoparticles, preventing Ni sintering and carbon deposition. However, the smaller pore size of beta hindered the introduction of Ni into its micropores, leading to more intensive Ni sintering and carbon deposition.
JOURNAL OF CO2 UTILIZATION
(2023)
Article
Chemistry, Applied
Zhoufeng Bian, Sibudjing Kawi
Article
Engineering, Environmental
Tianjia Chen, Zhigang Wang, Lina Liu, Subhasis Pati, Ming Hui Wai, Sibudjing Kawi
CHEMICAL ENGINEERING JOURNAL
(2020)
Article
Engineering, Environmental
Chenchen Geng, Yingjuan Shao, Zhoufeng Bian, Wenqi Zhong
CHEMICAL ENGINEERING JOURNAL
(2020)
Article
Engineering, Chemical
Yingjuan Shao, Zhaozhi Li, Wenqi Zhong, Zhoufeng Bian, Aibing Yu
CHEMICAL ENGINEERING SCIENCE
(2020)
Article
Chemistry, Physical
Zhoufeng Bian, Wenqi Zhong, Yang Yu, Bo Jiang, Sibudjing Kawi
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2020)
Article
Chemistry, Physical
Plaifa Hongmanorom, Jangam Ashok, Guanghui Zhang, Zhoufeng Bian, Ming Hui Wai, Yiqing Zeng, Shibo Xi, Armando Borgna, Sibudjing Kawi
Summary: Ni and Ni-Mg phyllosilicate mesoporous SBA-15 catalysts prepared via ammonia evaporation (AE) method exhibit superior catalytic performance in CO2 methanation compared to catalysts prepared via wetness impregnation (WI) method, due to enhanced metal-support interaction and weakly basic sites provided by surface hydroxyl groups. Incorporation of Mg into phyllosilicate structure increases medium basic sites, promoting monodentate formate formation and improving CO2 methanation activity. Additionally, the turnover frequency of CO2 conversion is correlated with the concentration of basic sites, and the strong metal-support interaction and confinement effect of SBA-15 can suppress metal sintering, ensuring good stability.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Chemistry, Multidisciplinary
Zhewei Liu, Zhoufeng Bian, Zhigang Wang, Bo Jiang
Summary: The study focuses on the interplay of water permeation and methanation within a membrane reactor, aiming to recommend suitable membrane properties and optimal operation conditions. Results indicate the importance of matching the methanation reaction rate with the H2O permeation rate for CO2 conversion, as well as the necessity of maintaining H2 and CO2 permeation selectivity lower than 0.1 to avoid negative effects.
REACTION CHEMISTRY & ENGINEERING
(2022)
Article
Chemistry, Applied
Xingyuan Gao, Ping Cai, Ziyi Wang, Xiaomei Lv, Sibudjing Kawi
Summary: CO2 utilizations and conversions play a significant role in reducing greenhouse gas emissions and regenerating industrial exhausts. Metal oxides, as catalysts, have been proven effective in adsorbing and activating CO2 based on surface acidity/basicity and oxygen defects. This review comprehensively summarizes the impacts of these physicochemical properties of metal oxides on CO2 adsorption and activation, with a focus on CO2 conversion activity, product yield selectivity, and catalyst stability in reforming and hydrogenation reactions. Additionally, the review explores the structure-performance relationships, reaction/deactivation mechanisms, and origins of surface acidity/basicity and oxygen defects.
TOPICS IN CATALYSIS
(2023)
Article
Engineering, Environmental
Guoqiang Song, Claudia Li, Wenjun Zhou, Libo Wu, Kang Hui Lim, Feiyang Hu, Tianchang Wang, Shaomin Liu, Zhifeng Ren, Sibudjing Kawi
Summary: This study reports a structure-reconstruction strategy based on a micropore-confined process to prepare yolk-shell catalysts with highly dispersed metallic nickel. The size of the nickel particles has a significant impact on the rates of methane decomposition, penetration of dissolved carbon, and growth of carbon nanotubes (CNTs), which provides an important route for the design of functionalized CDM catalysts.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Polymer Science
Yingjie Guo, Zan Chen, Xue Hu, Yawei Du, Cuijia Duan, Claudia Li, Sibudjing Kawi, Yinhui Li
Summary: Imino hypercrosslinked polymers (NH-HCPs), amino hypercrosslinked polymers (NH2-HCPs), and carboxyl hypercrosslinked polymers (COOH-HCPs) were synthesized as highly efficient adsorbents for doxycycline hydrochloride (DOX) in water. The NH-HCPs exhibited the highest specific surface area and adsorption capacity, while the COOH-HCPs showed the strongest adsorption capability. Structural adjustments played a more significant role in improving adsorption performance compared to functional adjustments. The primary DOX adsorption mechanism involved hydrogen bonding and other mechanisms.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Chemistry, Physical
Xiaoyu Han, Tiantian Xiao, Maoshuai Li, Ziwen Hao, Jiyi Chen, Yutong Pan, Xiaohui Zi, Heng Zhang, Shibo Xi, Hui Ming Wai, Sibudjing Kawi, Xinbin Ma
Summary: CuGaZrOx solid solution catalysts show promise for the selective hydrogenation of CO2 to methanol. The structural complexity of the catalyst presents a challenge to understanding the nature of active sites. This study reveals that synergistic interactions between copper and gallium species enhance the capacity for CO2 adsorption/activation and promote the hydrogenation of CO2 to form methanol via a formate pathway.
Review
Chemistry, Physical
Zhikun Zhang, Ziyan Yang, Lina Liu, Yaru Wang, Sibudjing Kawi
Summary: This review provides a comprehensive overview of the catalytic performance and mechanism of single-atom catalysts (SACs) in the thermocatalytic conversion of CO2 to C1 chemicals. SACs offer advantages in performance tuning through the regulation of coordination environment. However, there are still limitations in current studies that need to be addressed in order to drive decarbonization and greenhouse gas cycling in industries.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Inorganic & Nuclear
Yuepeng Hei, Zuojun Lu, Claudia Li, Jian Song, Bo Meng, Naitao Yang, Sibudjing Kawi, Jaka Sunarso, Xiaoyao Tan, Shaomin Liu
Summary: In this study, Ce0.8Y0.2O2-delta-BaCe0.8Y0.2O3-delta (YDC-BCY) hollow fiber (HF) membranes were developed and characterized for their hydrogen (H-2) permeation fluxes. By synthesizing YDC and BCY ceramic powders using the sol-gel method and fabricating YDC-BCY dual-phase ceramic HF membranes, it was found that the YDC/BCY molar ratio of 4:1 exhibited the highest hydrogen flux under certain conditions.
Article
Chemistry, Physical
Bo Jiang, Lin Li, Qian Zhang, Jing Ma, Haotian Zhang, Kewei Yu, Zhoufeng Bian, Xiaoliang Zhang, Xuehu Ma, Dawei Tang
Summary: In this study, it was demonstrated through experiments and theoretical calculations that the A-site lanthanide in perovskite-type oxygen carriers plays a crucial role in controlling the Fe-O covalency and hence the syngas yield. A smaller A-site cation radius was found to induce severe geometric tilting of the FeO6 octahedra, weakening the Fe-O orbital hybridization and reducing the oxygen mobility and surface oxygen activity. The charge-transfer energy was identified as a useful tool for designing oxygen carriers rationally and enhancing the understanding of oxygen modulation in chemical looping technologies.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Physical
Bolun Yu, Denan Li, Qianqian Zhu, Shufan Yao, Lifeng Zhang, Yanshuo Li, Zhenxin Zhang
Summary: This study successfully improved the catalytic activity of a zeolitic octahedral metal oxide by incorporating a single zinc species into its micropore. The zinc incorporation achieved a high ethane conversion rate and ethylene selectivity. Mechanism study showed that the isolated zinc site played a crucial role in activating oxygen and ethane, as well as stabilizing intermediates and transition states.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Ruoqi Liu, Hao Fei, Jian Wang, Ting Guo, Fangyang Liu, Zhuangzhi Wu, Dezhi Wang
Summary: This work successfully synthesized a high-performing S-enriched MoS2 catalyst for electrocatalytic nitrogen reduction reaction (NRR), demonstrating high activity and selectivity. The synergistic effect of the 1T phase and bridging S22- species was shown to play a positive role in NRR performances, and DFT calculations revealed the mechanism behind the improved performance.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Pan Xia, Lele Zhao, Xi Chen, Zhihong Ye, Zhihong Zheng, Qiang He, Ignasi Sires
Summary: This study presents a modified gas-diffusion electrode (GDE) for highly efficient and stable H2O2 electrosynthesis by using trace polymethylhydrosiloxane (PMHS). DFT calculations provide an in-depth understanding of the roles of PMHS functional groups.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Kwangchol Ri, Songsik Pak, Dunyu Sun, Qiang Zhong, Shaogui Yang, Songil Sin, Leliang Wu, Yue Sun, Hui Cao, Chunxiao Han, Chenmin Xu, Yazi Liu, Huan He, Shiyin Li, Cheng Sun
Summary: Different B-doped rGO catalysts were synthesized and their 2e- oxygen reduction reaction (ORR) performance was investigated. It was found that the 2e- ORR selectivity of B-doped rGO was influenced by the B content and oxygen mass transfer conditions. The synthesized catalyst exhibited high 2e- ORR selectivity and was capable of degrading organic pollutants continuously.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Li Lv, Lin Lei, Qi-Wen Chen, Cheng-Li Yin, Huiqing Fan, Jian-Ping Zhou
Summary: Monoclinic phase La2Ti2O7 and orthorhombic phase Bi4Ti3O12 are widely used in photocatalysis due to their layered crystal structure. The electronic structures of these phases play a crucial role in their photocatalytic activity. Heat treatment in a nitrogen atmosphere introduces more oxygen vacancies into the S-scheme heterojunction, leading to enhanced NO removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Choe Earn Choong, Minhee Kim, Jun Sup Lim, Young June Hong, Geon Joon Lee, Keun Hwa Chae, In Wook Nah, Yeomin Yoon, Eun Ha Choi, Min Jang
Summary: In this study, the synergistic effect between argon-plasma-system (AP) and catalysts in promoting the production of reactive species for water remediation was investigated. By altering the oxygen vacancies concentration of CeO2/Bi2O3 catalyst, the production of hydrated electrons was stimulated for PFOA removal. The results showed that the built-in electric field in the Bi/Ce0.43 interface enhanced electron migration and eaq- generation, leading to improved PFOA removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yushan Wu, Di Xu, Yanfei Xu, Xin Tian, Mingyue Ding
Summary: Efficient synthesis of primary amines from carbonyl compounds was achieved via reductive amination using Ru@NC-Al2O3 as a catalyst, exhibiting high activity and selectivity under mild conditions.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yilan Jiang, Peifang Wang, Tingyue Chen, Keyi Gao, Yiran Xiong, Yin Lu, Dionysios D. Dionysiou, Dawei Wang
Summary: By controlling the content of Co and Ni in Co1-xNixFe2O4, the production of O-1(2) from H2O2 can be regulated. NiFe2O4, with the lowest lattice distortion degree, can efficiently produce O-1(2) as the dominant reactive oxygen species. The system also exhibits significant resistance to water matrix interference.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Shuai Feng, Donglian Li, Hao Dong, Song Xie, Yaping Miao, Xuming Zhang, Biao Gao, Paul K. Chu, Xiang Peng
Summary: In this study, MoO2/Mo2N heterostructures were prepared by regulating the coordination of Mo atoms. The electrocatalyst exhibits high current density and excellent stability for hydrogen evolution reaction.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Jia-Cheng E. Yang, Min -Ping Zhu, Daqin Guan, Baoling Yuan, Darren Delai Sun, Chenghua Sun, Ming-Lai Fu
Summary: This study successfully modulated the electron configuration and spin state of millimetric metal catalysts by adjusting the support curvature radius. The electronic structure-oriented spin catalysis was found to affect the degradation of pollutants, providing new insights for the design and production of highly active, reusable, and stable catalysts.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Tao Zhong, Su Tang, Wenbin Huang, Wei Liu, Huinan Zhao, Lingling Hu, Shuanghong Tian, Chun He
Summary: In this study, a highly efficient photocatalyst for the elimination of CH3SH was developed by engineering different crystal facets and coupling them with PHI. Cu (111)/PHI exhibited the highest elimination efficiency and showed good stability and reusability. The enhanced surface electron pump effect and effective adsorption mechanisms were revealed through comprehensive characterizations and DFT calculations.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Feifei Yang, Tianyu Zhang, Jiankang Zhao, Wei Zhou, Nicole J. Libretto, Jeffrey T. Miller
Summary: A Ni3Sn intermetallic nano particle was found to have geometrically isolated Ni sites that could selectively cleave C-O bonds in biomass derivatives. This nano particle showed high activity and selectivity towards 2-methylfuran, unlike Ni nanoparticles that produced other unwanted products derived from the aromatic rings.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Lulu Qiao, Di Liu, Anquan Zhu, Jinxian Feng, Pengfei Zhou, Chunfa Liu, Kar Wei Ng, Hui Pan
Summary: This study reveals that surface evolution plays a crucial role in enhancing the electrocatalytic performance of transition metal oxides for electrochemical nitrate reduction reaction (e-NO3RR). Incorporating nickel into Co3O4 can promote surface reconstruction and improve the adsorption of intermediates and reduce energy barriers, leading to enhanced catalytic performance. The reconstructed cobalt-nickel hydroxides (CoyNi1_y(OH)2) on the catalyst's surface serve as the active phase.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Xinyu Song, Yang Shi, Zelin Wu, Bingkun Huang, Xinhao Wang, Heng Zhang, Peng Zhou, Wen Liu, Zhicheng Pan, Zhaokun Xiong, Bo Lai
Summary: This study explores the discriminative activities and mechanisms for activation of O-O bond in peroxy compounds via single-atom catalysts (SACs) with higher coordination numbers (M-N5). The atomic catalyst (Fe-SAC) with Fe-N5 as the active center was constructed, effectively activating peroxymonosulfate (PMS), peroxydisulfate (PDS), and hydrogen peroxide (H2O2). The study demonstrates the degradation efficiencies of acyclovir are related to the O-O bond length in different peroxy compounds, and reveals the discriminative mechanisms for activation of O-O bond in different Fenton-like systems.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Yangzhuo He, Hong Qin, Ziwei Wang, Han Wang, Yuan Zhu, Chengyun Zhou, Ying Zeng, Yicheng Li, Piao Xu, Guangming Zeng
Summary: A dual-metal-organic framework (MOF) assisted strategy was proposed to construct a magnetic Fe-Mn oxycarbide anchored on N-doped carbon for peroxymonosulfate (PMS) activation. The FeMn@NC-800 catalyst exhibited superior activity with almost 100% degradation of sulfamethazine (SMZ) in 30 minutes. The study provided insights for the rational design of high-performance heterogeneous catalysts and proposed a novel nonradical-based catalytic oxidation for environmental cleaning.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
