4.8 Article

Self-Healable Superomniphobic Surfaces for Corrosion Protection

期刊

ACS APPLIED MATERIALS & INTERFACES
卷 11, 期 33, 页码 30240-30246

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acsami.9b08855

关键词

superomniphobic surface; corrosion protection; chemical durability; self-healing; epoxidized soybean oil

资金

  1. University of Kansas
  2. Kansas Corn Commission [2234508-099-MESUPPRV, 1000350]
  3. Korea Institute of Industrial Technology [KITECH US-18-0001]

向作者/读者索取更多资源

Corrosion-protective surfaces are of the utmost relevance to ensure long-term stability and reliability of metals and alloys by limiting their interactions with corrosive species, such as water and ions. However, their practical applications are often limited either by the inability to repel low surface tension liquids such as oils and alcohols or by poor mechanical durability. Here, a superomniphobic surface is reported that can display very high contact angles for both high and low surface tension liquids as well as for concentrated acids and bases. Such extreme repellency allowed for approximately 20% of the corrosion rate compared to the conventional superhydrophobic corrosion protective coatings. Furthermore, the superomniphobic surface can autonomously repair mechanical damage at an elevated temperature (60 degrees C) within a short period of time (60 s), and the surface can restore its intrinsic corrosion protection performance. Such superomniphobic surfaces thus offer a wide range of potential applications, including pipelines, with sustainable corrosion protection and rust inhibitors for steel in reinforced concrete.

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