4.4 Article

Au Based Ni and Co Bimetallic Core Shell Nanocatalysts for Room Temperature Selective Decomposition of Hydrous Hydrazine to Hydrogen

期刊

CHEMISTRYSELECT
卷 4, 期 9, 页码 2734-2740

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201900483

关键词

Au@Co.; Au@Ni.; core; shell; nanoparticles.; bimetallic; catalyst.; hydrazine; decomposition; reaction; (HDR)

资金

  1. DST Nanomission [SR/NM/NS-1430/2014-G]
  2. UGC, Delhi

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Nickel and Cobalt bimetallic catalysts with Au as core metal has been synthesized and demonstrated for hydrazine decomposition reaction for producing hydrogen. Gold-cobalt and gold nickel bimetallic system belonging to the class of strained structures with high lattice mismatch of approximately 14% are demonstrated for synergistic effects atypical of monometallic counterparts for the selective decomposition of hydrous hydrazine to H-2 with N-2 as the other product at room temperature.

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