期刊
ENERGY TECHNOLOGY
卷 8, 期 2, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ente.201900175
关键词
calendering; carbon black; lithium-ion battery cathodes; porosities; roll temperatures
资金
- project ProKal [03XP0077A]
- Federal Ministry of Education and Research
Electrodes are usually calendered to enhance the energy density and improve the electrochemical cell performance. However, low porosities can compromise these two important features. To achieve the optimum porosity, a comprehensive process control is of major interest. This study further develops a Heckel-based compaction model considering the impact of the roll temperature and discusses the effect of the composition. Increasing the temperature of the roll linearly decreases the achievable coating porosity and the line load effort due to the rise of the elastic deformability of the thermoplastic binder PVDF. Reduced contents of simultaneously less-distributed additives increase the achievable coating porosity. Furthermore, the poor distribution is the main factor for lower line load efforts with lower additive contents. Moreover, the adhesion strength of the coating improves with increasing the temperature of the rolls due to the thermal rising of the elasticity of the binder.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据