期刊
NANO ENERGY
卷 61, 期 -, 页码 228-235出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.nanoen.2019.04.048
关键词
Polymer solar cells; Random polymerization; Fill factor; Morphology optimization; Room-temperature processing
类别
资金
- National Natural Science Foundation of China (NSFC) [51673092, 21762029, 51833004]
- National Science Fund for Distinguished Young Scholars [51425304]
- Fundamental Research Funds for the Central Universities [2232019D3-04]
- Shanghai Sailing Program [19YF1401000]
- Initial Research Funds for Young Teachers of Donghua University
- Office of Naval Research [N00014-17-1-2201]
- Young 1000 Talents Global Recruitment Program of China
- Graduate Innovation Fund Projects of Nanchang University [cx2016060]
- DOE, Office of Science
- DOE, Office of Basic Energy Sciences
In this work, we successfully achieved a record fill factor (FF) of near 80% by using random copolymerization strategy to precisely control the morphology of active layer for polymer solar cells (PSCs). A series of random copolymers were synthesized by random copolymerization of a self-assembly third unit into the multithiophene-based polymer matrix. The random copolymers possess excellent room temperature processing performance due to their relatively weaker self-aggregation properties. More importantly, despite the non-irregular sequence of random copolymers, the planarity of the third unit favored by the S...O intramolecular interaction still induced a face-on orientation of the random copolymers and formed a homogeneously fibril-like interpenetrating network structure in the blend films. Ultimately, the random polymer-based device achieved a remarkably high fill factor (FF) near 80% without any treatment, even approaching to the values of the inorganic materials-based solar cells.
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