Investigations on the Properties and Performance of Mixed-Matrix Polyethersulfone Membranes Modified with Halloysite Nanotubes

Ultrafiltration (UF) polyethersulfone (PES) membranes were prepared by wet phase inversion method. Commercial halloysite nanotubes (HNTs) in the amount of 0.5-4 wt % vs PES (15 wt %) were introduced into the casting solution containing the polymer and N,N-dimethylformamide as a solvent. The morphology, physicochemical properties and performance of the membranes were characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM), zeta potential, porosity and contact angle analyses, as well as permeability measurements. Moreover, the antifouling properties of the membranes were evaluated during UF of a model solution of bovine serum albumin (BSA). The research revealed a positive influence of modification with HNTs on hydrophilicity, water permeability and antifouling properties of the PES membranes. The most significant improvement of permeability was obtained in case of the membrane containing 2 wt % of HNTs, whereas the highest fouling resistance was observed for 0.5 wt % HNTs content. It was found that a good dispersion of HNTs can be obtained only at loadings below 2 wt %. Based on the results a relation between severity of membrane fouling and surface roughness was proved. Moreover, an increase of the roughness of the modified membranes was found to be accompanied by an increase of isoelectric point values.