期刊
ORGANIC LETTERS
卷 21, 期 8, 页码 2593-2596出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00560
关键词
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资金
- Advanced Catalytic Transformation Program for Carbon Utilization (ACT-C) from Japan Science and Technology Agency (JST) [JPMJCR12YE]
- Ministry of Education, Culture, Sports, Science and Technology (Japan) [18H04253, 17KT0006, 15H03809]
- Grants-in-Aid for Scientific Research [15H03809] Funding Source: KAKEN
An efficient iron porphyrin Lewis acid-catalyzed cycloaddition of aziridines with aldehydes has been developed to provide oxazolidines with high regio- and diastereoselectivity. The cycloaddition proceeds in toluene with 1 mol % of the iron catalyst at 25 degrees C. A theoretical study and synchrotron-based X-rabsorption fine structure measurements provided fundamental insights into the aziridine iron porphyrin complex, which is the key intermediate for the generation of the 1,3-dipole synthon.
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