期刊
ORGANIC LETTERS
卷 21, 期 11, 页码 4359-4364出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01529
关键词
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资金
- NNSFC [21622201, 91856119, 21820102003, 21772053]
- Science and Technology Department of Hubei Province [2016CFA050, 2017AHB047]
- Program of Introducing Talents of Discipline to Universities of China (111 Program) [B17019]
A photoinduced, copper-catalyzed three-component radical cross-coupling of cycloketone oxime esters, alkenes, and terminal alkynes is described for the first time. Key to the success of this process was the integration of photoinduced iminyl radical-mediated C-C bond cleavage with the conceptual simplicity of copper-catalyzed radical cross-coupling. This protocol provides access to cyanoalkyl-containing propargylic compounds in good yields.
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