期刊
ORGANIC LETTERS
卷 21, 期 9, 页码 3028-3033出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00563
关键词
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资金
- National Natural Science Foundation of China [81573349, 81773633, 21772130]
- National Science and Technology Major Project [2018ZX09711002-014-002, 2018ZX09711002-011-019, 2018ZX09711003-003-006]
- 1.3.5 project for disciplines of excellence, West China Hospital, Sichuan University
A transition-metal-free aerobic oxidative selective C-C bond-cleavage reaction in primary and secondary heteroaryl alcohols is reported. This reaction was highly efficient and tolerated various heteroaryl alcohols, generating a carboxylic acid derivative and a neutral heteroaromatic compound. Experimental studies combined with density functional theory calculations revealed the mechanism underlying the selective C-C bond cleavage. This strategy also provides an alternative simple approach to carboxylation reaction.
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