Article
Chemistry, Multidisciplinary
Jiacheng He, Wangping Sheng, Jia Yang, Yang Zhong, Yang Su, Licheng Tan, Yiwang Chen
Summary: A porous PbI2 layer with ordered array structure is successfully fabricated by integrating a succinamide (SA) additive with nanoimprinting technology, leading to omnidirectional diffusion and sufficient conversion to perovskites. The unencapsulated device achieves an efficiency of 23.56% and excellent long-term humidity stability. The perovskite solar cell and module achieve impressive efficiencies of 21.57% and 16.42%, respectively. This work paves the way for large-scale fabrication of high-performance perovskite photovoltaic devices.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Yuhao Peng, Junli Huang, Lue Zhou, Yuncheng Mu, Shuyao Han, Shu Zhou, Pingqi Gao
Summary: In this study, all-inorganic cesium lead bromide polycrystalline films with grain size exceeding 1 μm were successfully created through a two-step sintering process. Compared to the one-step sintering process, the two-step process resulted in films with larger grain size, higher density, and lower trap density. Photovoltaic devices based on the two-step sintering process demonstrated enhanced efficiency and reduced hysteresis.
Article
Chemistry, Physical
Vanira Trifiletti, Sally Luong, Giorgio Tseberlidis, Stefania Riva, Eugenio S. S. Galindez, William P. Gillin, Simona Binetti, Oliver Fenwick
Summary: Lead halide perovskites and bismuth-based materials have played significant roles in the optoelectronic field, with the former considered a good alternative to the latter. The engineering of a two-step synthesis process can address challenges in synthesizing compact layers in thin-film technology.
Article
Engineering, Electrical & Electronic
Shilpi Singh, Saurabh Kumar, Manish Deo, R. K. Chauhan
Summary: In this paper, we enhance the performance of optoelectronic devices using organometal halide perovskite material. By optimizing the multiple layers of the device through numerical simulation techniques, we achieved the best performance. The results of this study pave the way for future research in photodetectors.
OPTICAL AND QUANTUM ELECTRONICS
(2023)
Article
Materials Science, Multidisciplinary
Ilenia Viola, Fabio Matteocci, Luisa De Marco, Leonardo Lo Presti, Silvia Rizzato, Simona Sennato, Alessandra Zizzari, Valentina Arima, Antonio De Santis, Chiara Rovelli, Silvio Morganti, Matthias Auf Der Maur, Marianna Testa
Summary: Organometal halide perovskites (OMHP) are promising materials for fast, sensitive, and large area photodetectors. In this study, a controlled growth of OMHP single crystals in the form of microwires directly on conductive patterned substrates was achieved using a microfluidics-assisted technique. The resulting vertical devices with a pixelated sensor layer exhibit gain, a responsivity up to 200 AW(-1), and a fast rise time down to 35 µs. This is the first demonstration of an OMHP vertical device on a patterned substrate using microfluidics-assisted techniques.
ADVANCED MATERIALS TECHNOLOGIES
(2023)
Article
Materials Science, Multidisciplinary
Zhang Lei, Li Shugang, Zhang Tianjun, Song Shuang, Pan Hongyu
Summary: A novel solvent-induced fabrication method was reported to synthesize a high-quality perovskite thin film, which was applied to prepare a stable flexible photodetector. The flexible PD exhibited excellent performance and long-term stability.
FRONTIERS IN MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Yi Liu, Wuqian Guo, Lina Hua, Xi Zeng, Tian Yang, Qingshun Fan, Yu Ma, Changhao Gao, Zhihua Sun, Junhua Luo
Summary: In this study, a strong anomalous photovoltaic (APV) effect was demonstrated in a 2D hybrid perovskite ferroelectric material, achieved by alloying mixed organic cations. The material exhibited a high level of polarization sensitivity, with a giant current ratio and an above-bandgap photovoltage exceeding its bandgap. This research sheds light on the exploration of APV-active ferroelectrics and inspires their future optoelectronic device applications.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Physical
Zhonghai Yu, Xiucheng Wei, Yixiong Zheng, Haolei Hui, Mengying Bian, Samyak Dhole, Jung-Hun Seo, Yi-Yang Sun, Quanxi Jia, Shengbai Zhang, Sen Yang, Hao Zeng
Summary: The research reports a method to synthesize BaZrS3 thin films at lower temperatures (500 degrees Celsius) by changing the chemical reaction pathway, eliminating defects and contaminants associated with high temperature processing. The study also confirms that the resulting single-phase BaZrS3 thin film has smaller grain size and surface roughness.
Article
Materials Science, Multidisciplinary
Liansong Liu, Fengren Cao, Liukang Bian, Meng Wang, Haoxuan Sun, Liang Li
Summary: Inorganic tin-lead mixed halide perovskite-based self-powered photodetectors have shown promising performance with high responsivity, large specific detectivity, and fast response speed, which is comparable to other Sn-Pb mixed or pure Sn perovskite-based photodetectors. The improved performance can be mainly attributed to the gradient distribution-induced band bending, which enhances carrier separation and transport.
SCIENCE CHINA-MATERIALS
(2023)
Article
Chemistry, Physical
Mengfei Zhu, Lina Qin, Yuren Xia, Yi Hu, Xinmei Song, Daocheng Hong, Yuxi Tian, Zuoxiu Tie, Zhong Jin
Summary: In recent years, all-inorganic perovskite solar cells have gained attention due to their stability compared to hybrid cells. However, fabrication process defects limit their efficiency. To address this, erbium doping was proposed to improve the performance of CsPbI2.5Br0.5 perovskite films. The chloride ions assist in formation, enhance crystallinity, and prolong carrier lifetime. Erbium doping also leads to a contracted lattice volume and enhanced thermal stability. The fabricated cells achieved a high PCE of 9.22% and demonstrated superior heat resistance. This study provides a solution to excessive crystal defects and improves the thermal stability of all-inorganic perovskite solar cells.
SUSTAINABLE ENERGY & FUELS
(2023)
Article
Chemistry, Multidisciplinary
Haian Qiu, Jeffrey M. Mativetsky
Summary: The study reveals localized nonlinear lattice deformation and nanoscale structural rearrangement in methylammonium lead triiodide films caused by the combined action of light and voltage. These effects are connected with organic cation motion, suggesting that localized cation migration plays a significant role in the instability of perovskite optoelectronic devices under operating conditions.
Article
Materials Science, Multidisciplinary
Ga In Choi, Chung Wung Bark, Hyung Wook Choi
Summary: The study focuses on the development of a mixed-cation halide perovskite-based photodetector for deep-UV sensing. By mixing different ions, the prepared perovskite exhibits high stability, excellent light absorption, and increased bandgaps. The FAPbCl3-MAPbCl3 perovskite shows high responsivity, detectivity, and external quantum efficiency, making it a promising material for sensitive photodetection.
Article
Chemistry, Multidisciplinary
Geemin Kim, Sol An, Seok-Ki Hyeong, Seoung-Ki Lee, Myungwoong Kim, Naechul Shin
Summary: In this study, the combination of halide exchange process and patterning of metal halide perovskite thin films through vapor transport method was demonstrated, resulting in high-quality MAPbBr(3) pattern arrays with exceptional stability and detectivity in photodetectors. These results highlight the potential of chemical vapor deposition patterning of MHP materials in multicomponent optoelectronic device systems.
Article
Chemistry, Multidisciplinary
Edgar Rueda, Juan Serna, Jose Ignacio Uribe, Daniel Ramirez, Franklin Jaramillo, Jaime Osorio, Hernando Garcia
Summary: An F-scan nonlinear spectrometer was used to measure the two-photon absorption coefficient of CH3NH3PbBr3 perovskite films. The experimental data was fitted using a two-band model and irradiance saturation correction, revealing a nonlinear absorption magnitude of cm/MW.
Article
Chemistry, Multidisciplinary
Javier Castillo-Seoane, Lidia Contreras-Bernal, Jose Manuel Obrero-Perez, Xabier Garcia-Casas, Francisco Lorenzo-Lazaro, Francisco Javier Aparicio, Carmen Lopez-Santos, Teresa Cristina Rojas, Juan Antonio Anta, Ana Borras, Angel Barranco, Juan Ramon Sanchez-Valencia
Summary: Polarizers are commonly used components in optoelectronic devices, but controlling light polarization is still a challenge. Organometal halide perovskites (OMHP) have become the preferred material in photovoltaics and optoelectronics due to their tunable optical properties and excellent light emission. Nanowires and nanorods are key players in controlling light polarization. Highly aligned and anisotropic methylammonium lead iodide perovskite nanowalls fabricated by glancing-angle deposition exhibit anisotropic optical properties and can be used in photovoltaic devices with polarization-sensitive response.
ADVANCED MATERIALS
(2022)
Correction
Energy & Fuels
D. Mateus Torres-Herrera, Paola M. Moreno-Romero, Dagoberto Cabrera-German, Hugo J. Cortina-Marrero, Merida Sotelo-Lerma, Hailin Hu
Article
Materials Science, Ceramics
Obed Yamin Ramirez-Esquivel, Dalia Alejandra Mazon-Montijo, Dagoberto Cabrera-German, Eduardo Martinez-Guerra, Zeuz Montiel-Gonzalez
Summary: Current research on transparent conductive oxides focuses on developing environmentally friendly materials with competitive electrical and optical properties, while also ensuring compatibility with advanced microelectronics and miniaturization. This study improved the efficiency of Al doping in ZnO through the ALD supercycle approach, demonstrating typical electrical and optical properties and indicating potential for further exploration of additional Al incorporation into the ZnO structure.
CERAMICS INTERNATIONAL
(2021)
Article
Engineering, Electrical & Electronic
F. J. Ochoa-Estrella, A. Vera-Marquina, A. L. Leal-Cruz, I. Mejia, M. I. Pintor-Monroy, M. Martinez-Gil, M. Quevedo-Lopez
Summary: Heterojunctions made of n-type cadmium sulfide (CdS) and p-type zinc telluride (ZnTe) thin films with rectifying behavior were successfully developed using an in situ approach based on pulsed laser deposition (PLD). The structure and properties of the CdS and ZnTe thin films were characterized through X-ray diffraction and electrical measurements, showcasing potential applications in photodetector development by modifying carrier concentration differences between the two materials.
JOURNAL OF ELECTRONIC MATERIALS
(2021)
Article
Engineering, Electrical & Electronic
M. Fuentes-Perez, M. Sotelo-Lerma, J. L. Fuentes-Rios, Eric G. Morales-Espinoza, Manuel Serrano, M. E. Nicho
Summary: In this study, Fe3O4@ZnFe2O4 core/shell nanoparticles were prepared by depositing ZnO on Fe3O4 nanoparticles seeds obtained by the chemical bath deposition method. Characterization techniques showed that Fe3O4@ZnFe2O4 had higher crystallinity and specific crystal structures.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Chemistry, Multidisciplinary
Marcos Cota-Leal, Jorge A. Garcia-Valenzuela
Summary: In this study, a simple and low-cost method for obtaining transparent Al(OH)(3)-AlOOH thin films via chemical solution deposition at 60 degrees C was presented. The adhesion of these thin films to various substrates was tested, and it was demonstrated that they can act as a sensitizing layer for subsequent deposition of CdS thin films without the need for modifying reaction conditions. Additionally, a general formulation for depositing metal hydroxides/oxyhydroxides/oxides films was proposed, along with realistic assessments of X-ray photoelectron spectroscopy and thermogravimetric analysis on Al(OH)(3), AlOOH, and Al2O3 compounds.
Article
Chemistry, Multidisciplinary
Jorge A. Garcia-Valenzuela, Martha R. Baez-Gaxiola, Marcos Cota-Leal
Summary: By adding a small amount of Al-2(SO4)(3) solution into the reaction solution, the adhesion problem between CdS thin films and tin-free glass and silicon wafers can be solved, without the need for additional toxic cadmium salt or complex processing steps.
Article
Engineering, Electrical & Electronic
J. L. Fuentes-Rios, D. Cabrera-German, G. Suarez-Campos, M. Pintor-Monroy, H. Hu, M. A. Quevedo-Lopez, M. Sotelo-Lerma
Summary: The study developed a formulation for synthesizing Pb1-xSnxS thin films by chemical bath deposition, utilizing the high miscibility between PbS and SnS. The addition of different concentrations of Pb2+ ions solution to an Sn2+ S2- formulation resulted in films with varying Pb/Sn ratios. Structural changes, morphological variations, and a decrease in energy band gap were observed with increasing Pb2+ concentration in the films, leading to broader absorption spectra.
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
(2021)
Article
Materials Science, Multidisciplinary
A. Olivas, J. R. Rodriguez, F. Cardenas-Lizana, M. Cota-Leal, M. A. Keane
Summary: Nanostructured nickel and nickel sulfide-based catalysts were synthesized and studied for the selective hydrogenation of p-chloronitrobenzene. The addition of sulfur promoted the selectivity towards p-chloroaniline.
CHALCOGENIDE LETTERS
(2022)
Article
Energy & Fuels
M. A. Armenta, V. M. Maytorena, D. A. Buentello-Montoya, E. Arroyo, M. Cota-Leal, D. Yong, A. Olivas
Summary: In this study, microagglomerates of PdO and Mn2O3 supported over gamma-chi-Al2O3 were synthesized via the impregnation method for the methanol dehydration to dimethyl ether. The presence of 3% PdO (Pd2+) over gamma-chi-Al2O3 resulted in high conversions and selectivity at a lower temperature, attributed to a higher density of moderate acid sites. The size of PdO agglomerates also affected the mass transfer rates in the reaction. The stability of the PdO/gamma-chi-Al2O3 catalyst was correlated with its low apparent activation energy and the inactive phase change of PdO after the reaction.
Article
Materials Science, Multidisciplinary
Zeuz Montiel-Gonzalez, Obed Yamin Ramirez-Esquivel, Dagoberto Cabrera-German, Jorge Alejandro Torres-Ochoa, Axel Agustin Ortiz-Atondo, Dalia Alejandra Mazon-Montijo
Summary: This study explores the relationship between the structural and chemical properties of SILAR-deposited CuS-cov films, and assesses their impact on the Mid Infrared (MIR) response. The results demonstrate that the thickness, crystallinity, and composition of the CuS-cov films have an effect on their optical behavior in the MIR, with reflectivity reaching 80%. Furthermore, these films have low emissivity, making them suitable for low-emissivity coatings.
Article
Materials Science, Ceramics
M. Martinez-Gil, D. Cabrera-German, M. Rodriguez-Curiel, N. Abundiz-Cisneros, E. Vargas-Viveros, L. Cota, W. De la Cruz
Summary: Thermally processed nickel oxide (NiO) thin films were synthesized from nickel hydroxide films obtained by chemical solution deposition. The potential applications of the films were studied through controlled annealing atmospheres. The NiO films exhibited high optical transmittance, amorphous structure, and suitable electrical properties for transparent electronic devices.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2023)
Article
Optics
ChJ. Salas-Juarez, S. E. Burruel-Ibarra, M. I. Gil-Tolano, A. Perez Rodriguez, F. Romo-Garcia, A. R. Garcia-Haro, F. Brown, M. Yacaman-Valdez, J. L. Iriqui-Razcon, M. Martinez-Gil, R. Melendrez
Summary: In this study, we synthesized ZrO2:Tb3+ samples via a conventional solid-state reaction and investigated their Persistent Luminescence (PLUM) and performance in radiation dosimetry. X-ray diffraction confirmed the formation of monoclinic phase ZrO2 and the presence of Tb3+ ions and Tb2O3 in the samples. The PLUM response of the ZrO2:Tb3+ 1% sample was measured for 600 s after exposure to beta particle irradiation in the dose range of 0.5 to 256 Gy. The integrated area of the PLUM decay curves showed a sublinear dependence within the dose range of 0.5 to 64 Gy. The TL glow curve of the ZrO2: Tb3+ 1% sample exhibited two maxima at 79 and 150 degrees C, indicating that trapping states associated with the 79 degrees C maximum are responsible for the PLUM emission at room temperature. Computational deconvolution analysis revealed that the 79 degrees C maximum consisted of two traps with first-order kinetics. These results suggest that the ZrO2:Tb3+ 1% sample holds potential as a dosimeter for beta particle irradiation.
JOURNAL OF LUMINESCENCE
(2023)
Article
Materials Science, Multidisciplinary
Jeisson Javier Solis-Mosquera, Dagoberto Cabrera-German, Hisila Santacruz-Ortega, Monica Alessandra Acosta-Elias, Merida Sotelo-Lerma
Summary: A method for synthesizing lead iodide through chemical bath deposition without the use of organic solvents is presented in this study. The process involves three stages: producing tin hydroxide films as a seed layer, synthesizing lead iodide films, and annealing to induce polytypic transitions and investigate their effects on material properties. Various characterization techniques reveal the influence of annealing on the induction of polytypes. The resulting PbI2 films show wide-area coverage, wide-bandgap, and a structure belonging to the 2H and 4H polytypes, making them promising candidates for large-scale optoelectronic applications.
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE
(2023)
Article
Green & Sustainable Science & Technology
Luis Medina-Zazueta, F. C. Miranda-Castro, F. Romo-Garcia, M. Martinez-Gil, H. E. Esparza-Ponce, D. Encinas-Basurto, Jaime Ibarra
Summary: Vallesia glabra (Vg) leaf extract can be used to synthesize magnetic adsorbents for the removal of cationic dyes from aqueous solutions.
Article
Materials Science, Multidisciplinary
Jinfei Dai, Chenjing Zhao, Jie Xu, Hossein Roshan, Hua Dong, Francesco Di Stasio, Fang Yuan, Bo Jiao, Zhaoxin Wu
Summary: In this study, the performance of perovskite nanocrystal light emitting diodes (PNC-LEDs) was enhanced through rational device structure design and the application of high-performance perovskite nanocrystal emitting layers.
ORGANIC ELECTRONICS
(2024)
Article
Materials Science, Multidisciplinary
Jia-Hua Yeh, Suhendro Purbo Prakoso, Leon Lukhas Santoso, Shi-Ju Chen, Bryan Chiang, Ju-Chieh Cheng, Ru-Ning Zhang, Yu-Cheng Chiu
Summary: This study demonstrates the application of a renewable material called dextrin-SMS in the production of electret filters and transistor memory. Dextrin-SMS material can maintain prolonged electrostatic charges and has a relatively wide memory window, making it suitable for the production of biodegradable face masks and green electronics.
ORGANIC ELECTRONICS
(2024)
Article
Materials Science, Multidisciplinary
Ahmad Telfah, Qais M. Al-Bataineh, Ahmad A. Ahmad, Rund Abu-Zurayk, Carlos J. Tavares, Johannes Etzkorn, Farzad Foadian
Summary: Polyacrylic acid complexed with polyaniline (PAA/PANI) composite materials have the potential to form organic mixed ion-electron conductive (OMIEC) films, which can be used in optoelectronic and energy storage applications. The composite films are formed through an acid-base reaction, resulting in strong electrostatic interactions and intermolecular hydrogen bonds between PANI and PAA. The separation of PANI-rich domains from PAA-rich matrix in the composite films is observed. The electrical conductivity of the composite films is higher when the content of PANI is 33 wt%, due to the high ionic-electronic coupling at the interface between phase-separated regions.
ORGANIC ELECTRONICS
(2024)
Article
Materials Science, Multidisciplinary
Min-Chih Hou, Dian Luo, Yu-Ting Huang, Shun-Wei Liu, Chin-Wei Lu, Chih-Hao Chang, Hai-Ching Su
Summary: Light-emitting electrochemical cells (LECs) have great potential for novel emission applications, but their relatively low device efficiency hinders their competitiveness with other emission technologies. A study finds that increasing the concentration of small TiO2 nano-particles in the diffuser film can enhance light extraction and improve the device efficiency of LECs.
ORGANIC ELECTRONICS
(2024)
Article
Materials Science, Multidisciplinary
Qiaoli Niu, Yao Xu, Jun Yang, Wei Hua, Baoxiang Chai, Zequan Zhang, Yuhui Ma, Wenjin Zeng, Ana Flavia Nogueira, Ruidong Xia
Summary: By introducing CPB as a defect passivation agent in the perovskite precursor solution, the optoelectronic properties of perovskite films can be significantly improved and non-radiative carrier recombination can be effectively suppressed. CPB-modified perovskite solar cells exhibit lower trap-state density and stronger carrier migration capability, leading to enhanced power conversion efficiency and stability.
ORGANIC ELECTRONICS
(2024)
Article
Materials Science, Multidisciplinary
Hulya Ozturk Dogan, Fatma Yildirim, Zeynep Orhan, Ali Ben Ahmed, Mostefa Benhaliliba, Sakir Aydogan
Summary: In this study, efficient self-powered visible and UV photodetectors based on hybrid organic-inorganic materials were demonstrated. The photodetectors showed excellent UV detecting capability and good photoresponsivity.
ORGANIC ELECTRONICS
(2024)