4.6 Article

Yb3+/Er3+- codoped GeO2-PbO-PbF2 glass ceramics for ratiometric upconversion temperature sensing based on thermally and non-thermally coupled levels

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OPTICAL MATERIALS
卷 90, 期 -, 页码 200-207

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ELSEVIER SCIENCE BV
DOI: 10.1016/j.optmat.2019.02.035

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Er3+; Upconversion; Sensors; Optical thermometry; Sensitivity

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The contactless real-time temperature sensing technique with high temporal and spatial resolution is in high demand for the countless applications. Here, the Yb3+/Er3+- codoped GeO2-PbO-PbF2 glass ceramics synthesized via the melt-quenching technique has been presented as an optical thermometer. The thermal sensing was designed based on the temperature dependent fluorescence intensity ratios of thermally (H-2(11/2) and S-4(3/2)) and non-thermally (H-2(11/2) and F-4(9/2)) coupled Er3+ levels. The ratiometric techniques provide the thermal sensing within the temperature range of 300-466 K. The absolute and relative thermal sensitivities as well as the temperature resolution were calculated and compared with other Yb3+/Er3+-doped materials. The temperature of the microelectronic component on the printed circuit board was defined using the optical thermometry as a proof of concept revealing Yb3+/Er3+- codoped GeO2-PbO-PbF2 phosphor to be a promising candidate for precise non-contact thermal sensor.

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