4.6 Article

Reduction of thermal conductivity in Al2O3 dispersed p-type bismuth antimony telluride composites

期刊

MATERIALS CHEMISTRY AND PHYSICS
卷 233, 期 -, 页码 9-15

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2019.05.023

关键词

Thermoelectric materials; p-type BiSbTe alloys; Seebeck coefficient; Thermal conductivity; Nanocomposites

资金

  1. Korea Institute of Energy Technology Evaluation and Planning from the Ministry of Trade, Industry & Energy, Republic of Korea [20152020001210]
  2. Industrial Strategic Technology Development Program - Ministry of Trade, Industry and Energy [10063286]
  3. Korea Evaluation Institute of Industrial Technology (KEIT) [20152020001210] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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In this work, BiSbTe/Al2O3 composites were prepared by incorporation of alumina (with 2, 4, and 6 wt%) particles into the p-type Bi-Sb-Te-gas atomized powders via mechanical milling and, subsequently consolidated by spark plasma sintering (SPS). The Seebeck coefficient was significantly improved (over 41%) at 325 K, while the electrical conductivity was abruptly decreased for 6 wt% Al2O3 added BiSbTe/Al2O3 composites, which was mainly due to the decreases in carrier concentration, and energy filtering of carriers at interfaces. The thermal conductivity was eminently decreased over 27.5% for 6 wt% Al2O3 added BiSbTe/Al2O3 composites, was mainly attributed to the scattering of carriers and phonons at enormous grain boundaries as well as newly formed interfaces. The Vickers hardness of the BiSbTe/Al2O3 composites was improved compared to that of base matrix, and this was attributed to refinement of grains, and to a dispersion strengthening mechanism.

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