Article
Chemistry, Physical
Steven A. Yamada, Samantha T. Hung, Jae Yoon Shin, Michael D. Fayer
Summary: The dynamics of benzene complex formation and dissociation with silanols on the amorphous silica surfaces of nanoporous SiO2 were investigated using 2D IR and PSPP measurements. Two types of isolated silanols, type I and II, were identified, with different dissociation time constants and vibrational relaxation rates. The results suggest that the type I silanols are more stable and energetically favorable, while the type II silanols exhibit faster vibrational relaxation rates.
JOURNAL OF PHYSICAL CHEMISTRY B
(2021)
Article
Engineering, Mechanical
Frank W. DelRio, Filippo Mangolini, Camille E. Edwards, Tomas F. Babuska, David P. Adams, Ping Lu, John F. Curry
Summary: Nanocrystalline metal alloys, especially platinum-gold (Pt-Au) alloys, have shown great promise as electrical contact materials due to their low coefficients of friction and specific wear rates. This study explores the structure-property relations and growth mechanisms of Pt-Au tribofilms as a function of composition. The addition of Au leads to a decrease in grain size and an increase in grain boundary segregation, resulting in a decrease in modulus and an increase in hardness. The presence of Au also leads to decreased friction and wear rates, with high Au-content films showing stable tribofilm growth.
Article
Physics, Multidisciplinary
Ebru Cihan, Dirk Dietzel, Benedykt R. Jany, Andre Schirmeisen
Summary: Structural superlubricity refers to greatly reduced friction between incommensurate atomically flat surfaces. By measuring the friction of antimony nanoparticles on graphite, this study found a characteristic change in friction during the amorphous-crystalline phase transition above 420 K, which was irreversible upon cooling. The results validate the concept that structural superlubricity is determined by the effectiveness of atomic force canceling processes.
PHYSICAL REVIEW LETTERS
(2023)
Article
Chemistry, Physical
Christoph Gerhard, Robert Koehler
Summary: Glass polishing is a complex process involving multiple mechanisms such as mechanical abrasion, flow-induced surface smoothing, and chemical reactions. This study analyzed the chemical composition and surface roughness of fused silica throughout the entire optics manufacturing process using X-ray photoelectron spectroscopy and atomic force microscopy. The results aligned well with the polishing theory proposed by Beilby, Bowden, and Hughes. Decomposing the oxygen peak in the XPS spectra allowed for a correlation between SiO2 and silanol concentration and surface roughness during specific manufacturing steps.
APPLIED SURFACE SCIENCE
(2024)
Article
Optics
Yayun Liu, Qi Zhu, Chuanyang Wang, Jiaqiang Li
Summary: This paper investigates the fabrication of biomimetic textures on CoCrMo artificial knee joints and their impact on friction performance. The results show that the textured joints exhibit better friction properties compared to non-textured joints, and samples with a scaly textured structure show the best friction performances. The mechanisms responsible for this enhancement are explained as micro-textures storing wear debris and lubricating fluid, as well as derivative-cutting behavior removing wear debris.
OPTICS AND LASER TECHNOLOGY
(2023)
Article
Materials Science, Multidisciplinary
Qiang Hao, Jian Yin, Yu Liu, Lu Jin, Shengfang Zhang, Zhihua Sha
Summary: Based on fractal theory and Hertz contact theory, this study constructs a 3-D fractal rough surface with random characteristics and derives the relationship between the wear deformation depth of the rough peak and its real contact area. Wear calculation models for worn and unworn surfaces are established, and the relationship between wear amount and surface topography change is characterized. By converting the 3-D rough surface into a 2-D discrete plane using image digitization technology, a time-varying wear calculation method for fractal rough surfaces is proposed. The simulation results are verified experimentally, showing the reduction of profile height and an average wear depth of 0.02 mm, and the analysis reveals the influence of friction parameters on surface topography.
Article
Engineering, Mechanical
Pan Wang, He Liang, Liang Jiang, Linmao Qian
Summary: Surface roughness has a significant impact on friction and wear, especially at the nanoscale. This study investigates the effect of nanoscale surface roughness on sliding friction and wear. The research reveals that reducing surface roughness decreases friction and wear in mixed lubrication, but excessively low roughness can lead to friction failure. The findings enhance our understanding of the role of surface roughness in tribology.
Article
Chemistry, Physical
Muhammad Adnan, Waqar Qureshi, Muhammad Umer, Daniele Botto
Summary: This study investigates the effects of EDM parameters on the tribological performance of recast layers, including wear depth, friction coefficient, friction force, and contact surface temperature. The results demonstrate that it is possible to control the tribological performance of recast layers by varying EDM parameters, thus reducing the time and costs required for surface treatments after machining.
Article
Engineering, Mechanical
Stephan Schirdewahn, Felix Spranger, Kai Hilgenberg, Marion Merklein
Summary: The study explores the use of laser implantation process to improve the tribological behavior of hot stamping tools, by embedding hard ceramic particles into the tool to create highly wear resistant and separated micro-features, modifying the stress in tool areas and influencing the thermal and tribological interactions. This technique shows significantly improved tribological performance and potential for adjusting thermal properties in hot stamping tools.
Article
Polymer Science
Iuliia Kapitonova, Nadezhda Lazareva, Praskovia Tarasova, Aitalina Okhlopkova, Samuel Laukkanen, Vasiliy Mukhin
Summary: The present study investigated the tribological behavior of PTFE composites filled with natural layered silicates. It was found that the content and chemical composition of layered silicates affect the morphology of the friction surface of the composites. The formation of a special layer on the friction surface, independent of the silicate content, was observed, indicating the formation of a protective layer during friction.
Article
Physics, Multidisciplinary
Zhuohan Li, Izabela Szlufarska
Summary: Utilizing density functional theory calculations, we found that the mechanochemical response of material interfaces can be attributed to the deformation of interfacial bonds and the contribution from the underlying solid. The relative contributions are influenced by the stiffness of these regions and the contact geometry. The activation volume and mechanochemical response of interfaces are finite due to effects on stiffness and stress distribution.
PHYSICAL REVIEW LETTERS
(2021)
Article
Engineering, Mechanical
Saood Ali, Rendi Kurniawan, Xu Moran, Farooq Ahmed, Mohd Danish, Kubilay Aslantas
Summary: Introducing external surface features on mating contact surfaces effectively reduces friction and wear between the surfaces. The tribological properties of the contact surfaces can be improved by controlling the geometrical parameters of the surface texture. Experimental tests on steel and aluminum materials with hierarchical micro-dimple textures show a lower friction coefficient and improved tribological characteristics under boundary lubrication conditions. The secondary hierarchical nano-structures generate an additional hydrodynamic lift effect.
Article
Chemistry, Physical
Slawomir Swirad, Pawel Pawlus
Summary: Experiments were conducted under a dry gross fretting regime with steel discs in contact with ceramic balls. Ball burnishing led to a decrease in surface amplitude, an increase in microhardness, and up to 45% reduction in friction force and volumetric wear compared to sliding pairs containing milled discs. Higher roughness of the disc resulted in higher friction force and volumetric wear.
Article
Chemistry, Multidisciplinary
Y. Chen, Q. Liu
Summary: By hydroxylation treatment and Ru doping, the formation of Ni-phyllosilicate on the surface of biogenic silica extracted from equisetum fluviatile was improved, resulting in enhanced catalytic activity. The Ru-modified Ni-phyllosilicate catalyst showed high CO2 conversion rate and CH4 selectivity, with good performance in terms of turnover frequency, activation energy, and stability under severe conditions.
MATERIALS TODAY CHEMISTRY
(2021)
Review
Engineering, Multidisciplinary
Sachin Kumar Sharma, Harpreet Singh Grewal
Summary: Energy losses due to tribological phenomena pose a challenge to sustainable development, but bioinspired surfaces offer a solution by minimizing friction and wear. The study focuses on recent advancements in the tribological behavior of bioinspired surfaces and materials.
Article
Engineering, Chemical
Weili Zhao, Fangli Duan
Article
Engineering, Mechanical
Weili Zhao, Fangli Duan
TRIBOLOGY INTERNATIONAL
(2020)
Article
Materials Science, Composites
Yuan Xin, Fangli Duan, Xiaojing Mu
POLYMER COMPOSITES
(2020)
Article
Chemistry, Physical
Wei Gui, Fangli Duan, Xiaojing Mu
APPLIED SURFACE SCIENCE
(2020)
Article
Chemistry, Multidisciplinary
Ming Wang, Fangli Duan
Summary: Reactive molecular dynamics simulations were used to investigate the atomistic mechanism of chemical mechanical polishing on a Si(110) surface polished with an a-SiO2 particle. The results show that oxidation of the Si surface, insertion of O atoms into the surface, and formation of interfacial Si-O-Si bonds all play important roles in surface wear during the CMP process, with multiple atomic-level wear mechanisms contributing to material removal. The oxide layer of the Si surface mainly provides O atoms for insertion into the surface, rather than additional reaction pathways for bond formation.
Article
Engineering, Chemical
Hao Fu, Fangli Duan
Summary: In this study, molecular dynamics simulations were conducted to investigate the impact of environmental moisture and functional groups on the sliding adhesive behavior of graphene steps. Different functionalization treatments were found to affect interfacial water layers and the wear resistance of graphene steps in varying ways.
Article
Biotechnology & Applied Microbiology
Yan Gou, Xiaojing Mu, Yan Li, Meiling Tang, Gang Chen, Shangyou Xiao
Summary: The study successfully achieved simultaneous extraction and fractionation of LAB and Tan IIA from Salvia miltiorrhiza Bunge using three-liquid-phase extraction and re-partition as an integrated process.
BIOCHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Xia Wang, Wei Gui, Fangli Duan, Xiaojing Mu
Summary: The study shows that adsorbed functional groups can enhance the interaction strength between graphene oxide and iron oxide substrate, with the magnitude of binding energy enhancement depending on the adsorption sites of functional groups. Models with adjacent C atom to the top oxygen atom on the oxide surface exhibit significantly enhanced binding energy, while other models show slightly increased binding energy.
Article
Engineering, Mechanical
Zhongren Li, Fang Zheng, Lingfei Wang, Fangli Duan, Xiaojing Mu
Summary: The study found that the adsorption of hydrogen atoms during the wear process of graphene can have different influences, leading to the breaking of carbon chains or changes in the propagation direction of wear cavities. Additionally, interfacial C-C bonds tend to form at high-stress positions, further affecting the wear behavior of graphene.
TRIBOLOGY INTERNATIONAL
(2021)
Article
Engineering, Chemical
Xia Wang, Fangli Duan
Summary: This study investigates the influence of benzene molecular coverage and relative orientation of substrate crystal surfaces on the adsorption structure of interfacial benzene molecules and substrate surface damage. The results show that during the approaching process, benzene molecules form different adsorption structures depending on the coverage and relative orientation. The bridging benzene molecules bonded with two substrates during the separation process cause more substrate damage in the monolayer coverage model than in the other models.
Article
Chemistry, Analytical
Keith Smith, Xiaojing Mu, Zhaoqiang Li, J. Stuart Woodhead, Gamal A. El-Hiti
Summary: Several novel N-substituted acridinium esters have been synthesized and their chemiluminescent properties have been tested. The characteristics of the substituent on the nitrogen atom were found to affect their chemiluminescent efficiency and hydrolytic stability. Additionally, dibromo-substituted leaving groups slightly accelerated the chemiluminescence process.
Article
Chemistry, Multidisciplinary
Haiming Huang, Xiaojing Mu, Jing Deng, Shangyou Xiao, Zhiwei Luo, Gang Chen
Summary: This study aimed to develop a theoretical method for selecting the aqueous two-phase system (ATPS) for paeonol extraction from cortex moutan. The solvation free energies (E-solv) of paeonol were calculated in different ATPS, and their ranking was compared with the extraction yield. The results showed that E-solv ranking was effective in selecting the optimal organic type, organic solvent fraction, and aqueous salt concentration. The use of theoretical E-solv can significantly reduce the tedious experimental work for optimization in ATPS extraction.
Article
Nanoscience & Nanotechnology
Pengjie Wang, Fangli Duan
Summary: This study used reactive molecular dynamics simulations to investigate the friction and wear behaviors of a monolayer graphene oxide or graphene (GO/Gr) flake confined between two amorphous iron oxide substrates. The results revealed that the sliding shear between the substrates was achieved through folding and unfolding of the confined GO/Gr flakes at lower loads, while at higher loads, the formation of interfacial C-Fe bonds led to the breakage of GO/Gr flakes and gradual damaging of the iron oxide surfaces.
ACS APPLIED NANO MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Suifeng Lu, Fangli Duan
Summary: We used reactive molecular dynamics (ReaxFF-MD) to simulate the friction and shear behavior of a-C:Si films with varying Si content (0-20 at%). The optimal doping content was found to be 7.2 at%, which showed similar friction to the undoped film but had smaller wear and running-in time. The proper amount of Si doping inhibited the formation of all-C bridging chains at the interface and prevented the formation of all-C and Si-involved bridging chains caused by surface dangling bonds at higher Si contents. Our study revealed the atomic scale mechanism of Si doping on the tribological properties of a-C films.