期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 23, 页码 9415-9421出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b04381
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资金
- National Institutes of Health [GM110382]
We herein report a direct intermolecular anti-Markovnikov hydroazidation method for unactivated olefins, which is promoted by a catalytic amount of bench-stable benziodoxole at ambient temperature. This method facilitates previously difficult, direct addition of hydrazoic acid across a wide variety of unactivated olefins in both complex molecules and unfunctionalized commodity chemicals. It conveniently fills a synthetic chemistry gap of existing olefin hydroazidation procedures, and thereby provides a valuable tool for azido-group labeling in organic synthesis and chemical biology studies.
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