期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 84, 期 12, 页码 7871-7882出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b00745
关键词
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资金
- National Science Foundation [CHE-1659775]
- National Institute of General Medical Sciences [R15-GM116054]
Trichloroacetimidates are useful reagents for the synthesis of esters under mild conditions that do not require an exogenous promoter. These conditions avoid the undesired decomposition of substrates with sensitive functional groups that are often observed with the use of strong Lewis or Bronsted acids. With heating, these reactions have been extended to benzyl esters without electron-donating groups. These inexpensive and convenient methods should find application in the formation of esters in complex substrates.
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