期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 84, 期 10, 页码 6072-6083出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b00237
关键词
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资金
- National Natural Science Foundation of China [21702083]
- Yunnan Ten Thousand Talent Program for Young Top Notch Talents
- Program for Innovative Research Team (in Science and Technology) in Universities of Yunnan Province
An unprecedented benzylic C-H functionalization of methyl arenes across unactivated alkenes is presented. In the presence of MnCl2 center dot 4H(2)O and di-tert-butyl peroxide, N-allyl anilines underwent benzylation/cyclization cascade to give benzylated indolines, which are a previously unmet synthetic goal. This protocol features simple operation, broad substrate scope, and great exo selectivity.
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