期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 84, 期 9, 页码 5067-5077出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b00004
关键词
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资金
- SERB, New-Delhi [EMR/2016/006358]
- CSIR, New-Delhi [02(0226)15/EMR-II]
- Indian Institute of Science
- R. L. Fine Chem
Acylation of electron-deficient heteroaromatic compounds has been developed using visible light. alpha-Ketoacids have been used as an efficient source of acyl radicals under photoredox conditions. The in situ generated acyl radicals from alpha-ketoacids have been coupled to a wide variety of electron-deficient heteroaromatic compounds in a Minisci type reaction. This method would be attractive to access biologically attractive molecules.
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