期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 847, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2019.05.066
关键词
Voltammetry; Screen-printed electrodes; Gold nanoparticles; Carbon nanotubes; Carbon nanofibers; Aminothiols; Liquid chromatography; Amperometric detection
资金
- European Commission (EACEA) [SGA 2015-1992, FPA 2013-0225]
- ESF funds
- Sistema de Garantia Juvenil depending on Ministerio de Empleo y Seguridad Social of Spain
- Junta de Andalucia [E-11-2017-0397859]
- Institute of Research on Electron Microscopy and Materials (IMEYMAT)
- Generalitat de Catalunya [2017SGR311]
- Junta de Andalucia (PAIDI 2017)
Commercially available gold screen-printed electrodes cured at high temperature were modified or functionalized at the surface with gold nanoparticles, mainly produced by a green synthesis method, and other carbon-based nanomaterials in order to enhance the electron transfer between the sulfhydryl groups of the aminothiols cysteine (Cys), methionine (Met), glutathione (GSH) and homocysteine (hCys) and the electrode. The electrochemical characterization by cyclic and differential pulse voltammetry of some of the modified electrodes showed an improved performance in terms of sensitivity, reproducibility, repeatability, linearity range and limits of detection (12, 1, 0.2 and 1 mu mol L-1 for Cys, Met, GSH, hCys, respectively) and quantification (40, 2, 0.5 and 2 mu mol L-1 for Cys, Met, GSH, hCys, respectively) as compared to unmodified units. Then, some of these modified devices were successfully applied to the determination of cysteine and methionine in dietary supplements by means of liquid chromatography with amperometric detection.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据