Article
Materials Science, Multidisciplinary
Xiaodong Wang, Xinmei Yang, Miaomiao Hu, Huajian Liu, Xingtai Zhou
Summary: The effect of 316 stainless steel on the corrosion of pressureless-sintered SiC in the vapor of molten NaCl-KCl-MgCl2 salt at 700 degrees C was studied. It was found that MgCl2•xH2O (x = 4, 6) hydrolyzed into HCl, which caused corrosion of the stainless steel. Some corrosion products dissolved and increased the concentration of elements Cr, Fe, and Ni in the salt, while others reacted with SiC to form Cr7C3, Fe3Si, and SiCl4. Reactions among SiC, stainless steel, and their corrosion products (FeCl2, CrCl2, and SiCl4) led to a corrosion depth of approximately 250 μm for 1000 hours.
Article
Energy & Fuels
Carolina Villada, Alejandra Toro, Francisco Bolivar
Summary: This study investigated the corrosion performance of stainless austenitic steel SS304 in contact with three different molten nitrate salts under long-term isothermal conditions. The analysis of microstructure and corrosion products, as well as further studies with current commercial salts, provided experimental data for metal/salt interaction and chemical interaction salt/atmosphere. The results may contribute to improving understanding of material compatibility and engineering design optimization with molten salts for thermal energy storage technologies.
JOURNAL OF ENERGY STORAGE
(2021)
Article
Materials Science, Multidisciplinary
Zhe Hu, Linlin Liu, Pengfei Lu, Weihua Liu, Fan Zhang, Zhongfeng Tang
Summary: The corrosion behavior and mechanism of 316SS alloy in NaCl-KCl-ZnCl2 molten salts were investigated. The annual corrosion rate initially increased and then decreased to a steady rate. No evident pitting and intergranular corrosion were observed. An oxide layer composed of various oxides formed on the surface of the 316SS samples. The corrosion mechanism involved the hygroscopicity of ZnCl2, the reactions with Fe and Cr, and the formation of nickel oxide. Removal of Zn(OH)2 or basic zinc chloride in NaCl-KCl-ZnCl2 is necessary for commercial application.
MATERIALS TODAY COMMUNICATIONS
(2022)
Article
Materials Science, Multidisciplinary
Jie Qiu, Digby D. Macdonald, Ryan Schoell, Junsoo Han, Sara Mastromarino, John R. Scully, Djamel Kaoumi, Peter Hosemann
Summary: The study found that the oxide film formed on Type 316L stainless steel in molten FLiNaK salt is unstable and can only provide temporary corrosion protection. After the dissolution of the oxide film, selective dealloying of Cr and Fe from the steel leads to intergranular corrosion of Type 316L SS in molten fluoride salt.
Article
Materials Science, Multidisciplinary
Minsung Hong, Ho Lun Chan, Yujun Xie, Elena Romanovskaia, John R. Scully, Peter Hosemann
Summary: The study investigated the effect of Te concentration in molten FLiNaK salt on the corrosion and mechanical properties of 304 stainless steel. The corrosion depth of samples decreased with increasing Te concentration after 48 h immersion at 600 degrees Celsius. Additionally, the 1.0 wt% Te sample showed less reduction in mechanical properties compared to the 0.1 wt% Te sample. It is hypothesized that a protective Cr-oxide layer is formed beneath the Ni-Fe rich layer formed by selective leaching of Cr.
Article
Materials Science, Multidisciplinary
Liyuan Peng, Ziyu Zhang, Jibo Tan, Xinqiang Wu, En-Hou Han, Wei Ke
Summary: The effects of boric acid and lithium hydroxide on the corrosion behaviors of 316LN stainless steel in simulated high-temperature pressurized water were investigated. The results showed that increasing the concentration of boric acid or lithium hydroxide decreased the corrosion resistance of 316LN stainless steel. Boric acid was recommended for the water chemistry, while lithium hydroxide alone was found to be inappropriate. The solubility of oxides in high-temperature pressurized water was calculated, and a promising water chemistry for high-temperature pressurized water was proposed.
Article
Biochemistry & Molecular Biology
Shiqiang Chen, Hao Deng, Yudi Zhao, Shihang Lu, Yao Zhao, Xin Cheng, Guangzhou Liu, Wenwen Dou, Jvna Chen
Summary: EH40 steel's corrosion behavior in seawater enriched with Methanococcus maripaludis was investigated, showing initial inhibition of corrosion followed by eventual propagation. The presence of M. maripaludis promotes both anodic and cathodic reactions of EH40 steel, while the protective corrosion products film inhibits corrosion during early immersion stages. Pitting corrosion is closely related to uneven distribution of M. maripaludis biofilm on EH40 steel surface.
BIOELECTROCHEMISTRY
(2021)
Article
Materials Science, Multidisciplinary
Xinmei Yang, Huajian Liu, Bingchuan Chen, Min Ge, Yuan Qian, Jianqiang Wang
Summary: This study investigates the corrosion behavior of GH3535 alloy in molten LiF-BeF2 salt. The results indicate that the corrosion is driven by NiF2 in the salt and O-2 leakage. The corrosion is severer in the hot section compared to the cold section. BeCr2O4 is detected on the alloy surface in the cold section but not in the hot section. Reactions between Be and metallic fluorides significantly reduce the impurity concentration in the molten salt, resulting in no obvious corrosion in the GH3535 alloy at different temperatures.
Article
Materials Science, Multidisciplinary
Yue Wang, Xin Mu, Junhua Dong, Aniefiok Joseph Umoh, Wei Ke
Summary: The corrosion behavior of mild steel in a simulated coastal atmosphere environment was studied through experiments, showing a trend of rapid increase followed by gradual stabilization during the corrosion process. Different chemical compositions and conductivity were observed in the inner and outer layers of the rust as it thickened. The thickening rust layer inhibited the diffusion of aggressive ions, gradually suppressing the electrochemical corrosion process.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Article
Electrochemistry
Charles R. Lhermitte, S. Scott Parker, J. Matt Jackson, Marisa J. Monreal
Summary: This report discusses the use of the Mg2+/0 couple as a reference in molten MgCl2-NaCl, demonstrating its reliability over a range of melt temperatures. It also showcases the construction of a simple molten magnesium reference electrode for operation at temperatures greater than magnesium's melting point.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2021)
Article
Materials Science, Multidisciplinary
James R. Keiser, Preet M. Singh, Michael J. Lance, Harry M. Meyer, Kristian G. Myhre, Tracie M. Lowe, Dino Sulejmanovic, Ercan Cakmak, Victoria A. Cox, C. Shane Hawkins, Adam W. Willoughby
Summary: The increased demand for renewable energy resources has sparked a renewed interest in nuclear reactors, including a new generation of molten salt reactors. The handling of molten chloride or fluoride salts poses a challenge due to the inability of metals to form and retain a protective oxide surface layer. A specific alloy, Hastelloy N, was developed to address this issue, but it had some deficiencies. For the next generation of molten salt reactors, an alloy with higher temperature capability and pressure vessel code approval is required, leading some reactor designers to opt for 316H stainless steel. To minimize corrosion of the stainless steel by the molten fluoride salt, beryllium metal can be added to react with impurities and lower the oxidation potential. However, there are concerns about the potential reaction between beryllium and the stainless steel components.
JOURNAL OF NUCLEAR MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Liyuan Peng, Ziyu Zhang, Jibo Tan, Xinqiang Wu
Summary: The effects of Zn injection into boric acid and lithium hydroxide solutions on the corrosion behaviors of 316LN stainless steel in simulated high-temperature pressurized water were examined. It was recommended to use low concentration of lithium hydroxide solutions with 20-100 ppb Zn injection for Zn-injected water chemistry in high-temperature pressurized water environment. The study confirmed the beneficial effects of Zn injection in terms of protecting the oxide films on 316LN stainless steel, both in the hot functional test and primary coolant water chemistry. The corrosion mechanism during the Zn injection in high-temperature pressurized water was also discussed.
Article
Materials Science, Multidisciplinary
Takaaki Koyanagi, Jo Jo Lee, James R. Keiser, Hanns Gietl, Yutai Katoh
Summary: In this study, chemical vapor deposited SiC single crystal and polycrystals were exposed to a static beryllium-bearing molten fluoride salt, 2LiF-BeF2, at 750°C for 500 and 1000 hours. The materials experienced slight weight loss and surface etching, which were attributed to trace metal impurities and oxygen. Minimal subsurface changes were observed in the microstructure. The corrosion processes were similar to those reported for molten LiF-KF-NaF salt with trace impurities, indicating the significant impact of impurities on SiC corrosion.
Article
Construction & Building Technology
Tangwei Mi, Yongqiang Lic, W. Liu, Z. Dong, Q. Gong, C. Mina, F. Xing, Yaocheng Wang, S. H. Chu
Summary: Desalinated sea sand concrete (DSSC) is increasingly used to replace natural river sand, but the corrosion risks of steel reinforcement in DSSC due to chloride and carbon dioxide attacks are a major concern. This study monitored the corrosion process of steel reinforcement embedded in cement paste containing chloride ions and found that corrosion was initiated before carbonation occurred. The study reveals that carbonation-induced chloride redistribution rather than pH decrease dominates the corrosion initiation.
CONSTRUCTION AND BUILDING MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Xiaoshuang Li, Weimin Zhao, Shengkai Shi, Ming Wang, Jianing Li, Xuexu Xu, Jianbo Sun
Summary: This study investigated the corrosion film formation mechanism of 110H-13Cr steel at 350 degrees C in the coexistence of H2, H2S, CO2, and H2O gases. The results showed that the corrosion rate of the steel was low, and the corrosion products consisted of an easily removable Fe(1-x)S film and a dense Fe-Cr oxide film inside the steel.
Article
Materials Science, Multidisciplinary
Qi Liu, Zirui Wang, Weihua Liu, Huiqing Yin, Zhongfeng Tang, Yuan Qian
Summary: The corrosion behavior of Ni-Mo-Cr alloy samples in salt and vapor revealed that oxidation in vapor accelerated corrosion, while corrosion in liquid molten salt was less severe. The corrosion by salt vapor should not be neglected in practical applications.
Article
Materials Science, Multidisciplinary
Qi Liu, Hongxia Xu, Huiqin Yin, Na Li, Wenrui Wang, Linfan Li, Zhongfeng Tang, Yuan Qian
Summary: The experiment investigated the corrosion behavior of 316 stainless steel in NaCl-KCl-MgCl2 salt vapor at 700 degrees C under static conditions. Easy-to-peel oxide layers were formed on the surface, with their composition and structure changing as exposure continued. The initially formed oxide monolayer gradually transformed into oxide multilayers, with the outermost layer changing from Cr-Fe oxide to Mg-Cr oxide, due to varying diffusion rates of elements and different reaction rates of MgCl2 in the salt vapor.
Article
Thermodynamics
Yu Zhang, Biao Hu, Gang Zeng, Shuhong Liu, Yong Du, Huiqin Yin
Summary: The phase equilibria of the Cu-Ti-Nb ternary system were studied through thermodynamic modeling and experiments. The thermodynamic parameters of the system were obtained and the solidification behavior and phase equilibria data of the alloys were determined. The results showed good agreement between the calculated and experimental results.
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
(2022)
Article
Thermodynamics
Huiqin Yin, Xiaomin Wu, Changjian Ling, Xing Lai, Biao Hu, Zhongfeng Tang
Summary: This study aims to build a thermodynamic database for the LiCl/RbCl/CaCl2-NaCl-UCl3-PuCl3 system and evaluate the suitability of LiCl, RbCl, and CaCl2 as additives for the matrix fuel of a Molten Salt Reactor. The CALPHAD method is used, and models including substitutional solution and compound energy formalism are adopted to describe the phases. The models are optimized based on experimental and theoretical data, and the thermodynamic parameters are obtained. Phase diagram information is predicted, and the impact of LiCl, RbCl, and CaCl2 on the matrix fuel is investigated. The results suggest that RbCl is a suitable additive, while LiCl and CaCl2 are not. This study enriches the thermodynamic databases and provides guidance for the design and preparation of nuclear fuel in a Molten Salt Reactor.
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
(2022)
Article
Energy & Fuels
Huiqin Yin, Zirui Wang, Xing Lai, Yang Wang, Zhongfeng Tang
Summary: Through thermodynamic calculation and experimental validation, NaCl-KCl-CaCl2 eutectic salt with excellent ultra-high-temperature thermal stability and lower cost was developed, which can be considered as ultra-high-temperature thermal energy storage materials.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2022)
Article
Energy & Fuels
Xing Lai, Huiqin Yin, Ping Li, Bingxin Liu, Li Gao, Zhongfeng Tang
Summary: NaNO3-NaCl-NaF salts were investigated and their thermodynamic parameters and properties were obtained. The salts showed excellent agreement between predicted and experimental melting points, high thermal stability, and low cost for thermal energy storage. These characteristics make them a potential candidate for thermal energy storage fluids.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Chemistry, Physical
Yu Zhang, Biao Hu, Huiqing Yin, Shuhong Liu, Yong Du
Summary: The Ag-Cu-M (M = Nb, Fe, Pb) ternary systems were thermodynamically evaluated using experimental data and thermodynamic models. The calculated isothermal sections showed good agreement with experimental data.
JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION
(2022)
Article
Thermodynamics
Huiqin Yin, Jinliang Song, Wenguan Liu, Biao Hu
Summary: Thermodynamic evaluation of the AClx-MgCl2 systems was conducted using the CALPHAD technique. The substitutional solution model and associate solution model were used to describe the liquid phase, while the intermediate phases were treated as stoichiometric compounds. The optimized thermodynamic parameters based on available data were in good agreement with experimental results. This study enriches the thermodynamic database of molten salts and provides an additional model choice for optimizing and designing molten salt systems.
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
(2022)
Article
Materials Science, Multidisciplinary
Yang Wang, Qi Liu, Xingzhi Su, Huiqin Yin, Zhongfeng Tang
Summary: Corrosion tests were conducted on 316 stainless steel (316SS) in NaCl-KCl-NaF reciprocal salts at different temperatures. The results showed perfect compatibility between the reciprocal salts and 316SS, even without special treatment, and a stable Cr-O enriched layer was observed. The mechanism of stabilization of chromium oxides in molten salts was investigated, revealing that low oxoacidity facilitated the formation of stable chromium oxides. These findings can potentially contribute to the design and corrosion control of molten salts.
Article
Thermodynamics
Yang Wang, Xiang Li, Huiqin Yin, Zhongfeng Tang
Summary: This study designed and optimized a novel NaF-KCl reciprocal salt through thermodynamic calculation and experimental measurement. The results showed that the eutectic point of NaF-KCl reciprocal salt was at 27.3 mol% NaF and 922.1 K, consistent with experimental values. The thermophysical properties of the salt, including fusion enthalpy, specific heat capacity, density, and electric conductance, were empirically predicted and experimentally determined. The NaF-KCl reciprocal salt exhibited a higher latent heat, lower energy cost, and good agreement between empirical predictions and experimental measurements.
THERMAL SCIENCE AND ENGINEERING PROGRESS
(2023)
Article
Chemistry, Physical
Na Li, Huaiyou Wang, Huiqin Yin, Qi Liu, Zhongfeng Tang
Summary: The corrosion resistance of 316 stainless steel (316SS) in molten KCl-MgCl2 salts at high temperatures was investigated. The corrosion rate of 316SS increased slowly with temperature below 600 degrees C, but increased dramatically at 700 degrees C. The corrosion of 316SS was mainly due to the selective dissolution of Cr and Fe at high temperatures. Impurities in the salts accelerated the dissolution process, while purification treatment reduced the corrosivity of the salts. The diffusion rate of Cr/Fe in 316SS changed more with temperature than the reaction rate of salt impurities with Cr/Fe under the experimental conditions.
Article
Energy & Fuels
Xing Lai, Huiqin Yin, Zhigang Yang, Zhongfeng Tang
Summary: The corrosion behaviors of 316 stainless steel in NaNO3-NaCl-NaF molten salt and vapor were investigated at 450°C. The results showed that weight gain occurred in argon gas condition while weight loss occurred in air condition. Fe-O enriched layer with different crystal forms was detected by XRD. The crystal forms were relatively homogeneously distributed after molten salt corrosion but not uniform after vapor corrosion. 316 stainless steel experienced a more serious corrosion attack in salts vapor than in molten salt.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Energy & Fuels
Zhigang Yang, Huiqin Yin, Fangyuan Guo, Liuping Chen, Xing Lai, Saijun Chen, Yajing Wang, Zhongfeng Tang
Summary: Two types of NaCl-KCl-FeCl3 eutectic salts with low melting temperature, good thermal stability, suitable working temperature, and low cost have been developed for low-temperature thermal energy storage. The thermodynamic calculation and experimental measurement were used to determine the reliable thermodynamic parameters of the NaCl-KCl-FeCl3 system, which showed excellent agreement with the experimental data. The predicted eutectic temperatures of the NaCl-KCl-FeCl3 system were also in excellent agreement with the experimental data.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Chemistry, Multidisciplinary
Xing Lai, Huiqin Yin, Ping Li, Bingxin Liu, Li Gao, Zhongfeng Tang
Summary: The corrosion behavior of 304 stainless steel in molten NaNO3-NaCl-NaF salt and vapor has been studied. The results showed the formation of surface oxides and shedding phenomenon, attributed to the existence of NO2 and NO in the vapor. The corrosion rate in the salt is similar to that in solar salt, indicating the insignificant influence of Cl- and F- on the steel. This study enriches the molten salt corrosion database and provides references for alloy and salt selection in CSP.
Article
Chemistry, Multidisciplinary
Rongshan Lan, Yiyang Liu, Ling Han, Jing Yang, Huiqin Yin, Min Ge, Xiaobin Fu, Hongtao Liu, Yuan Qian
Summary: By applying high-resolution NMR methods, this study elucidated the evolution of [ZrxFy](4x-y) local ionic structures in FLiNaK-ZrF4 salt mixtures, revealing the impact of ZrF4 content on the distribution of these species. The phase transition of K3ZrF7 from an orthorhombic lattice to a disordered cubic lattice was clarified, highlighting the influence of lattice changes on the dynamics of F- ions and crystal structure.
Article
Materials Science, Multidisciplinary
Zhichao Shang, Xiaoping Cai, Farshid Pahlevani, Yan Zheng, Akbar Hojjati-Najafabadi, Xinran Gao, Baojing Zhang, Peizhong Feng
Summary: High porosity Co-Al-Fe intermetallics with 3D-microstructures were successfully synthesized in one step via a thermal explosion reaction. The link between pore structure and permeability was investigated using 3D-XRM technology. The corrosion resistance of the samples with different Fe contents was studied at 900 degrees C under an oxygen/sulphur atmosphere for up to 120 h. The results showed that the samples maintained stable pore structure and intact internal matrices, attributed to the formation of a thin protective layer on the surface. In addition, inward diffusion of S resulted in the formation of FeS nodules.
Article
Materials Science, Multidisciplinary
Lian Ma, Hain Yang, Daquan Zhang, Wei Wu
Summary: In this study, an environmentally friendly volatile corrosion inhibitor, lysine salts (LA), was prepared between graphene oxide (GO) layers using an in situ intercalation technique. The corrosion inhibition effect of LA was evaluated, and it was found that LA-GO2 achieved a 99.3% corrosion inhibition efficiency after composition optimization. The inhibition of the electrochemical anodic process on the surface of mild steel was the main reason for the high corrosion inhibition efficiency of LA-GO2. The properties of the surface film on the corroded steel were also characterized in detail to understand the corrosion inhibition mechanism of LA-GO2.
Article
Materials Science, Multidisciplinary
Running Wang, Jiaping Zhang, Bing Liu, Jie Fei, Qiangang Fu
Summary: By introducing a tailored SiC-C interphase, the carbon fiber can be effectively protected, improving the mechanical and ablation properties of leading edge shaped C/C-ZrC-SiC composites.
Article
Materials Science, Multidisciplinary
Zihua Wang, Chijia Wang, Ruitao Wang, Jiapeng Deng, Kun Zhang, Yanji Zhu, Huaiyuan Wang
Summary: A robust anti-corrosive coating has been developed using functional fly ash, which demonstrates excellent corrosion resistance and improved mechanical properties. The coating achieves these enhancements through molecular cross-linking design and surface augmentation techniques, resulting in a significantly improved impedance modulus compared to pure polyurea coatings.
Article
Materials Science, Multidisciplinary
Haofei Sun, Meifeng Li, Hao Zhang, Jing Liu
Summary: The oxidation behavior of FeCrNi medium entropy alloy was investigated through experimental observations and density functional theory (DFT) calculations. The study found that at 900 degrees C, the alloy forms a desirable and continuous oxide layer, while at 1000 degrees C, the oxide layer becomes discontinuous with penetration of oxide. These observations highlight the significant role of phase structure in promoting the formation of protective oxide scales and influencing oxidation resistance.
Article
Materials Science, Multidisciplinary
Yang Li, Ke Ma, Jingjun Xu, Jingjing Li, Yueming Li, Yi Zhang, Jun Zuo, Meishuan Li
Summary: Cr2AlC diffusion barrier effectively blocks the diffusion of Ti, enhancing the stability and spalling resistance of the Al2O3 scales between NiCrAlY coating and TiAl alloy.
Article
Materials Science, Multidisciplinary
Weiyi Wang, Qinglin Pan, Xiangdong Wang, Bing Liu
Summary: By adding Ce, Sc, Y and Zr elements to Al-Mg-Si alloy, the microstructure of the alloy can be regulated, and the corrosion and heat resistance of the materials can be improved.
Article
Materials Science, Multidisciplinary
Andrea Cristoforetti, Javier Izquierdo, Ricardo M. Souto, Flavio Deflorian, Michele Fedel, Stefano Rossi
Summary: This study presents a new approach to studying the mechanism of filiform corrosion in organic coated steel using the scanning vibrating electrode technique (SVET) and micropotentiometry (potentiometric SECM). The electrochemical activity under the coating was evaluated by mapping the ionic current densities coming from artificial defects made in specific locations of the filament. Antimony tips were also used to investigate the pH changes associated with different corrosion reactions at the metal-paint interface. Local pH levels along the filament in the anodic and cathodic regions were determined.
Article
Materials Science, Multidisciplinary
Yang Gao, Dayun Sun, Zhu Liu, Shuo Cong, Rui Tang, Yanping Huang, Lefu Zhang, Xianglong Guo
Summary: The corrosion characteristics of a novel alumina-forming austenitic steel in high-pressure high-temperature water environment were studied. The addition of aluminum has a negative effect on the continuity of the alumina scale.
Article
Materials Science, Multidisciplinary
Negin Madelat, Benny Wouters, Peter Visser, Zahra Jiryaeisharahi, Kristof Marcoen, Shoshan T. Abrahami, Annick Hubin, Herman Terryn, Tom Hauffman
Summary: This work explores the correlation between electrolyte transport properties and the variation of pigment volume concentration (PVC) in organic coatings. An odd random phase electrochemical impedance spectroscopy (ORP-EIS) approach is used to analyze the diffusion of ions independent from water uptake. The results show that a higher PVC leads to a more homogeneous coating structure, resulting in faster diffusion of ions and enhanced water uptake.
Article
Materials Science, Multidisciplinary
Eloa Lopes Maia, Serguei Gavrilov, Valentyn Tsisar, Kitty Baert, Iris De Graeve
Summary: The effect of pre-oxidation in air at 300-500°C on the initiation and development of liquid metal corrosion attack on 316L austenitic steel in static lead-bismuth eutectic (LBE) has been investigated. It was found that pre-formed oxide films can protect the surface against dissolution, while high temperature pre-oxidation leads to localized corrosion.
Article
Materials Science, Multidisciplinary
Baozhuang Sun, Qiuyu Wang, Yue Pan, Zhiyong Liu, Cuiwei Du, Xiaogang Li
Summary: In this study, a non-steady electrochemical model was established to investigate stress corrosion cracking (SCC). The model was verified using 304 SS with various microstructures, confirming its effectiveness in assessing SCC susceptibility.
Article
Materials Science, Multidisciplinary
Xingyu Xiao, Xinhua Liu, Zhilei Wang, Xuexu Xu, Mingying Chen, Jianxin Xie
Summary: The corrosion behavior and mechanisms of Cu-10Ni-X (Al, Fe, Mn, Cr, Sn, Ti, Zn) alloys in a 3.5% NaCl solution were systematically investigated. Both computational and experimental results revealed that except Ti, other elements could enhance the corrosion resistance of Cu2O passivation film.
Article
Materials Science, Multidisciplinary
Gen Zhang, Yan-Ping Huang, E. Jiang, Wei -Wei Liu, Hong Yang, Jing Xiong, Yong-Fu Zhao
Summary: The addition of aluminum has a significant influence on the intermetallic compounds in AFA alloys, particularly increasing the content of B2-NiAl phase. In the SCO2 environment, the oxide scales formed on AFA alloys with aluminum were thinner than on ASS without aluminum, and the structure of the oxide scales changed to a double-layer structure.
Article
Materials Science, Multidisciplinary
Yuxuan He, Guozheng Xiao, Chao Wang, Xuefeng Lu, Liuyuan Li, Shiying Liu, Yusheng Wu, Zhanjie Wang
Summary: The relationship between configurational entropy and lattice distortion in novel rare earth monosilicates was investigated, and the effect of configurational entropy on their properties was studied. The results showed that lattice distortion increased with the increase of configurational entropy, but a highly symmetrical crystal structure was formed when the configurational entropy was large enough, inhibiting the lattice distortion.