期刊
CHEMSUSCHEM
卷 12, 期 12, 页码 2558-2563出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201900833
关键词
2,5-furandicarboxylic acid; continuous flow; green chemistry; heterogeneous catalysis; water chemistry
The oxidation reaction of 5-hydroxymethylfurfural to the bioplastic monomer 2,5-furandicarboxylic acid over heterogenous resin-supported Pt catalysts was investigated in detail, under continuous flow, base-free conditions, and in neat water. The product was continuously obtained in 99 % yield by running the reaction at 120 degrees C, 303 s residence time, 1.2 mL min(-1) O-2 flow rate, and 7.7 bar O-2 pressure. The product was isolated with a high space-time-yield of 46.0 g L-1 h(-1) without purifications or acid/base treatments.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据