期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 25, 期 40, 页码 9345-9349出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201900966
关键词
homogeneous catalysis; methanol dehydrogenation; pincer ligands; ruthenium; synergistic effect
资金
- state of Mecklenburg-Vorpommern
- German Ministry of Education and Research (BMBF)
- German Federal Ministry for Economic Affairs and Energy (BMWi) within the project Metha-Cycle [03ET6071C]
A novel state-of-the-art bicatalytic system for hydrogen generation from aqueous methanol at low temperature and base concentration is described. Applying two molecularly defined ruthenium complexes A and B3 for methanol dehydrogenation at the same time under the same conditions, a synergistic effect is observed. This behavior is explained by the increase of the dehydrogenation of formic acid, which is formed as an intermediate, by the second catalyst B3.
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