Article
Nanoscience & Nanotechnology
Micaela Vazquez, Modan Liu, Zejun Zhang, Abhinav Chandresh, Anemar Bruno Kanj, Wolfgang Wenzel, Lars Heinke
Summary: Metal-organic framework (MOF)-based separators in Li-ion batteries have the potential to improve battery performance, with the mobility and conduction of lithium and organic ionic liquids (ILs) in these materials being crucial for the power output. Molecular dynamics simulations reveal the conductivity mechanism of a Li-based IL in MOF nanopores, showing complex conductivity depending on the Li-IL loading and composition. The presence of Li prevents conductivity collapse at high IL loadings, and the competing mechanisms of Li conduction are elucidated, with implications for the development of advanced batteries based on IL and nanoporous separators.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Xuhuan Xiao, Xinglan Deng, Ye Tian, Shusheng Tao, Zirui Song, Wentao Deng, Hongshuai Hou, Guoqiang Zou, Xiaobo Ji
Summary: Two-dimensional metal-organic frameworks (MOFs) show promise as high-energy anode materials for next-generation lithium-ion capacitors (LICs) due to their tunability and short ion transport paths. This study investigates the production of ultrathin 2D Co/Fe-BDC nanosheets and their storage mechanism. The results demonstrate that LICs with optimal Co4Fe-BDC anodes exhibit high energy density, power density, and superior cycle lifespan.
Article
Chemistry, Multidisciplinary
Wei Zhang, Michael. J. J. Bojdys, Nicola Pinna
Summary: We demonstrate a versatile synthesis strategy to combine metal-organic frameworks with nanoparticles, allowing for the formation of mono-, bi-, tri-, and quaternary composites. This method does not require specific surface structures or functionalities on the pre-formed cores. The controlled diffusion rate of alkaline vapors regulates the growth of MOFs and encapsulation of NPs.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Review
Nanoscience & Nanotechnology
Ziwei Cao, Roya Momen, Shusheng Tao, Dengyi Xiong, Zirui Song, Xuhuan Xiao, Wentao Deng, Hongshuai Hou, Sedat Yasar, Sedar Altin, Faith Bulut, Guoqiang Zou, Xiaobo Ji
Summary: This comprehensive review outlines the synthetic methods and electrochemical performances of metal-organic frameworks (MOFs), as well as their applications in the field of supercapacitors. The review highlights the advantages of MOFs-related materials and discusses the major challenges and opportunities for future research.
NANO-MICRO LETTERS
(2022)
Article
Chemistry, Multidisciplinary
Marco Tortora, Pawel Zajdel, Alexander Rowland Lowe, Miroslaw Chorazewski, Juscelino B. Leao, Grethe Jensen, Markus Bleuel, Alberto Giacomello, Carlo Massimo Casciola, Simone Meloni, Yaroslav Grosu
Summary: This study demonstrates exceptional negative linear compressibility (NLC) and negative volumetric compressibility (NVC) values can be achieved through nonwetting liquid intrusion in flexible porous media, particularly in the ZIF-8 metal-organic framework. The presence of liquid in the windows connecting cavities of ZIF-8 leads to volumetric expansion, paving the way for designing novel materials with exceptional NLC and NVC at reasonable pressures for a wide range of applications.
Review
Chemistry, Physical
Xinru Tang, Nan Li, Huan Pang
Summary: Metal-organic frameworks (MOFs) derived metal-phosphides exhibit controllable structures, high specific surface area, high stability, and excellent electrical conductivity, showing great potential in electrochemistry.
GREEN ENERGY & ENVIRONMENT
(2022)
Article
Environmental Sciences
Fatima Izhar, Muhammad Imran, Hamyal Izhar, Shoomaila Latif, Nazim Hussain, Hafiz M. N. Iqbal, Muhammad Bilal
Summary: Nanoporous metal and carbon composites as sensor materials exhibit high reliability, selectivity, and sensitivity, playing a significant role in monitoring various analytes.
Article
Chemistry, Physical
Seyed Mohamad Moosavi, Balazs Almos Novotny, Daniele Ongari, Elias Moubarak, Mehrdad Asgari, Oezge Kadioglu, Charithea Charalambous, Andres Ortega-Guerrero, Amir H. Farmahini, Lev Sarkisov, Susana Garcia, Frank Noe, Berend Smit
Summary: A machine learning approach has been developed to accurately predict the heat capacity of materials such as zeolites, metal-organic frameworks, and covalent-organic frameworks, providing an important theoretical basis for carbon capture applications.
Review
Materials Science, Multidisciplinary
Meng Du, Qing Li, Guangxun Zhang, Feifei Wang, Huan Pang
Summary: Lithium-sulfur batteries are considered promising new energy storage systems with high theoretical energy densities, but face limitations such as low electrical conductivity. Metal-organic frameworks show significant potential in overcoming these limitations due to their high porosity and tunable porous structure. Future research directions must address potential obstacles in the development of these materials.
ENERGY & ENVIRONMENTAL MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Rui Jiao, Yanming Wang, Yuxia Pang, Dongjie Yang, Hongming Lou, Xueqing Qiu
Summary: In this article, a new-type mesoporous 3D ZIF-8-Cu composed of 2D nanostructures is constructed by adjusting a metal guide agent copper chloride (CuCl). The in situ encapsulation of beta-G within the developed mesoporous 3D ZIF-8-Cu enhances the synergistic catalysis ability of the enzyme complex (beta-G@ZIF8-Cu). The improvement in enzyme activity can be attributed to the expansion of pores, promoting substrate diffusion, and the thinner 2D structure that shortens the mass transfer distance.
ACS APPLIED NANO MATERIALS
(2023)
Review
Chemistry, Multidisciplinary
Xue Feng Lu, Yongjin Fang, Deyan Luan, Xiong Wen David Lou
Summary: Metal-organic frameworks (MOFs) have been recognized as versatile precursors or templates for preparing high-performance electrodes or catalysts in electrochemical energy storage and conversion (EESC), due to their high surface area, tunable pore sizes, and diverse chemical compositions and physical structures. Research focuses on the composition/structure/performance relationship and practical applications in various EESC systems, providing insights into the future development of MOF-derived functional materials.
Article
Chemistry, Physical
Gwang Hyeon Eom, Sang A. Han, Joo Hyeong Suh, Jung Ho Kim, Min-Sik Park
Summary: Enriched cavities are strategically introduced to zeolitic imidazolate frameworks using a hard silica template approach, allowing easy access for Li ions to inner pores and cavities during Li plating and stripping. This approach optimizes internal pore utilization and facilitates Li-ion transport, ultimately enhancing electrochemistry performances such as long-term cyclability and reversible capacity.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Yingying Yang, Jian Chen, Jikun Tang, Fei Xing, Man Yao
Summary: This study found through calculations that TiC MXenes terminated with oxygen atoms exhibit higher catalytic activity, providing important theoretical guidance for the design of cathode catalysts in LiO2 batteries.
JOURNAL OF PHYSICAL CHEMISTRY C
(2021)
Review
Chemistry, Multidisciplinary
Watcharop Chaikittisilp, Yusuke Yamauchi, Katsuhiko Ariga
Summary: Materials science and chemistry play a central role in advancing society, and the development of functional materials is crucial for sustaining life on our planet. Implementing nanotechnology, nanoarchitectonics, and materials informatics can open advanced routes for designing and exploring functional materials.
ADVANCED MATERIALS
(2022)
Review
Chemistry, Multidisciplinary
Hui Ling Chia, Carmen C. Mayorga-Martinez, Martin Pumera
Summary: The rapid advancements in materials science, particularly nanoscience, have significantly contributed to the development of sensors, with 2D materials showing great potential for high-sensitivity sensor applications. Modification and doping of 2D materials can enhance sensor performance, allowing for fine-tuning of their properties and electronic structure.
ADVANCED FUNCTIONAL MATERIALS
(2021)