期刊
CHEMICAL ENGINEERING JOURNAL
卷 377, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2019.04.102
关键词
Chemical Looping Combustion; CaCo-based oxygen carrier; Oxygen transfer capacity; Oxygen transfer rate
资金
- Energy Efficiency and Resources Core Technology Program of the Korean Institute of Energy Technology Evaluation and Planning (KETEP) from the Ministry of Trade, Industry Energy [20152010201840, 20184030202210]
- National Research Foundation of Korea (NRF) of Republic of Korea [2018R1D1A3B07050416]
- National Research Foundation of Korea [2018R1D1A3B07050416] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
We investigated whether a CaCo-based oxygen carrier could be an oxygen-transfer particle for Chemical Looping Combustion (CLC). The analysis was carried out using TGA to see the redox characteristics of the cycle. 15% H-2/N-2 was used as the reducing gas, and air was used as the oxidizing gas. The CaCo-based oxygen carrier maintained a high oxygen-transfer capacity of about 16 wt% for 10 cycles. Also, the oxygen-transfer rate was relatively stable over 10 cycles. The maximum oxygen-transfer rate was about 0.022 mmol O-2/g/s in the reduction section. The maximum oxygen-transfer rate in the oxidation section was about 0.022 mmol O-2/g/s. From the XRD results, the CaCo-based oxygen carrier exhibited a similar XRD pattern after the 10th-cycle oxidation, which confirmed that the phase was stably recovered even though the CaCo-based oxygen carrier was completely reduced to CaO and Co metal during reduction. Although some agglomeration was observed, it did not affect overall oxygen transfer capacity and rates. Conclusively, CaCo-based oxygen carriers show high performance and phase stability, and thus can be potential candidates for oxygen carriers in CLC process.
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