期刊
CHEMICAL ENGINEERING JOURNAL
卷 361, 期 -, 页码 278-285出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2018.12.031
关键词
N-doped acicular hollow porous carbon; CNTs; Pyrrolic-N; CaCO3; CO2 capture
资金
- National Natural Science Foundation of China [21576055, 51372043]
- Major Science and Technology Foundation of Guangxi Province [AA17202030, AA16380050]
- Natural Science Foundation of Guangxi Province [2016GXNSFGA380003]
This work reports the synthesis of a N-doped acicular hollow porous carbon/carbon-nanotubes (N-AHPC@H-CNTs) using acicular CaCO3 as a green template and activating agent coupled with FeeCo catalyst, polydopamine and melamine as carbon and nitrogen precursors respectively. The prepared materials were applied for CO2 capture. N-AHPC@H-CNTs were characterized by SEM, TEM, PXRD, XPS, and BET techniques, which revealed their high SSA (S-BET, 561m(2).g(-1)), microporous surface area (351.9m(2).g(-1)), N content (11.60 wt%) having a ratio of Pyrrolic-N (56.63%) and a great mass of ultramicropores (d < 0.7 nm). Attributed to these intriguing characteristics, N-AHPC@H-CNTs exhibited outstanding CO2 capture capacity of 4.43 mmol.g(-1) at 273 K and 3.91 mmol.g(-1) at 298 K at 1.0 bar and good selectivity for CO2/N-2 and CO2/H-2 under the synergistic effect of N-AHPC and CNTs. This flexible and green synthesis approach opens the doors for preparing other similar multifunctional hollow porous carbon/carbon-nanotubes materials for a variety of other applications.
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