期刊
CERAMICS INTERNATIONAL
卷 45, 期 12, 页码 15711-15714出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2019.04.219
关键词
Composite; Anode; Li/Na-ion batteries
资金
- National Natural Science Foundation of China [21701030, 51801096, 51502043]
- Guangdong Province Natural Science Foundation [2017A030310241]
- Innovative talents cultivation project of outstanding youth in Guangdong Province [2016KQNCX038]
- Science and Technology Planning Project of Guangzhou City [201804010392]
- China Postdoctoral Science Foundation [1112000139]
Various P-Ge compounds including GeP5 and GeP3 can be easily synthesized by a direct ball milling method while GeP can not. Herein, we successfully synthesize binary-phase Ge2P3 composite which derived from layered GeP and black P. When applied as anodes for Li-ion batteries, the as-synthesized binary-phase composite delivers a large reversible capacity of 1605 mA h g(-1) with a high initial Coulombic efficiency of 89%, retains 1380 mA h g(-1) after 100 cycles and even achieves 920 mA h g(-1) at a current density of at 5 A g(-1). Also, for sodium-storage it shows a reversible capacity of 970 mA h g(-1) with an initial Coulombic efficiency of 88% and retains 890 mA h g(-1) after 100 cycles. The performance can be attributed to the following merits: the binary Li/Na-storage components host more Li/Na ions, the layered structure favors Li/Na-ion transportation and the abundant heterointerfaces increase the amount of active sites.
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