4.7 Article

Production of fire-retardant phosphorylated cellulose fibrils by twin-screw extrusion with low energy consumption

期刊

CELLULOSE
卷 26, 期 9, 页码 5635-5651

出版社

SPRINGER
DOI: 10.1007/s10570-019-02447-4

关键词

CNF; Twin-screw extrusion; Ultra-fine grinder; Energy consumption; Fire retardant; Phosphorylation; Nanopapers

资金

  1. Institut Carnot Polynat [ANR-16-CARN-0025-01]
  2. Centre Technique du Papier (Grenoble, France)
  3. LabEx Tec 21 [ANR-11-LABX-0030]

向作者/读者索取更多资源

Phosphorylated cellulose nanofibrils (CNFs) were produced using a twin-screw extruder (TSE). The energy efficiency was compared with that of an ultra-fine grinder (UFG). CNFs at different solid contents were produced (10wt% for the TSE and 2wt% for the UFG), and their quality was compared using several characterization tests, such as optical microscopy, atomic force microscopy or MorFi fiber analyser. CNF nanopapers with high a Young's modulus (14GPa) and high transparency were successfully manufactured using CNFs produced by the TSE. The efficiency of the TSE was improved by using phosphorylated pulp instead of mechano-enzymatically treated pulp. The results show that phosphorylated CNFs can be easily produced at the industrial scale via twin-screw extrusion and present new functionalities such as fire-retardant properties, which are useful in many applications.

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