期刊
APPLIED SURFACE SCIENCE
卷 475, 期 -, 页码 942-946出版社
ELSEVIER
DOI: 10.1016/j.apsusc.2019.01.045
关键词
Lithium-ion batteries; Anodes; TiNb2O7; Nanowires; Sol-gel method
类别
资金
- National Natural Science Foundation of China [51672235]
- Science and Technology Talents Training Project of Urumqi
- Student Innovation Training Program of Xinjiang University [201710755010]
- Program for Changjiang Scholars and Innovative Research Team in the University of Ministry of Education of China [IRT1081]
- National Ten Thousands Plan
TiNb2O7 nanowires (TNS) were synthesized by using a simple sol-gel method combined with subsequent calcination process. As anodes of lithium-ion batteries, TNS exhibit a specific capacity of 199.6 mAh g(-1) after 500 cycles at 0.4 A g(-1) and satisfactory coulombic efficiency of 98.7% after 2000 cycles at 5 A g(-1). Compared with TiNb2O7 nanoparticles (TN), TNS have excellent electrochemical performances due to the 1D materials assembled from uniform and dense TiNb2O7 nanoparticles ( similar to 35 nm). The 1D linear structural electrode gathered the merits of tiny nanoparticles, multiple active sites, short electronic transport path and excellent dynamics orientation, which are responsible for the favorable electrochemical properties.
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