Article
Materials Science, Multidisciplinary
Mohammad Ghorbani, Mohammad Hassan Vakili, Elham Ameri
Summary: In this study, polymeric membranes were synthesized for separating oil/water emulsion in Iran's Mobarakeh steel company's effluent, and membranes containing silica nanoparticles showed better separation performance compared to those without.
MATERIALS TODAY COMMUNICATIONS
(2021)
Article
Engineering, Chemical
Lia Vasquez, Katarzyna Dziza, Siew-Leng Loo, Vassilios Binas, Sofia Stefa, George Kiriakidis, Athanassia Athanassiou, Despina Fragouli
Summary: This paper reports the fabrication of multifunctional composite cryogels that can remove oil and dye from polluted water through gravity-driven filtration. The cryogels exhibit excellent adsorption capacity and photocatalytic self-cleaning property, maintaining good performance after multiple filtration cycles.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Engineering, Chemical
Umair Baig, Abdul Waheed
Summary: A polymeric-inorganic nanocomposite membrane with self-cleaning properties was fabricated for treating water-containing emulsified oily feed. The membrane showed high separation efficiency and photocatalytic cleaning ability.
Article
Engineering, Chemical
Mengjiao Yan, Kangying Guo, Yue Gao, Qinyan Yue, Baoyu Gao
Summary: This study investigates the coagulation-ultrafiltration integrated process for oily wastewater treatment. It is found that polyaluminum chloride (PAC) is more effective than AlCl3 and Fe based coagulants. The PAC-PDMDAAC coagulation system forms large and loose flocs, indicating efficient removal of oil droplets.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Review
Engineering, Environmental
Sarita Kalla
Summary: This paper discusses the importance of treating oil or surfactant-containing wastewater and introduces the application of Membrane Distillation (MD) technology in treating highly saline wastewater and oil-containing feed streams. It also discusses MD processes, the development of amphiphobic membranes, and the influence of MD operating variables on flux.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Engineering, Chemical
Xiaocheng Zhang, Xiangjun Liao, Minghao Shi, Yuan Liao, Abdul Ghani Razaqpur, Xiaofei You
Summary: Membrane wetting and fouling are major challenges in membrane distillation, especially with low surface tension components in the feed. This study developed membranes with different wettability to guide membrane selection for treating these wastewaters. Superhydrophobic and superomniphobic modifications improved anti-fouling/wetting properties when the feeds had anionic and cationic surfactants. However, these modifications worsened membrane performance when the feeds contained nonionic surfactant Tween-20. The hydrophilic layer on Janus membranes showed improvement in anti-fouling/wetting abilities for emulsified oily wastewaters, while the choice of substrate was still important.
Review
Engineering, Multidisciplinary
Nafiu Umar Barambu, Muhammad Roil Bilad, Mohamad Azmi Bustam, Kiki Adi Kurnia, Mohd Hafiz Dzarfan Othman, Nik Abdul Hadi Md Nordin
Summary: The paper reviews recent advances in membrane material development for oil-water separation, focusing on improving surface chemistry, structure, and hydrodynamics to enhance filtration performance over long periods of operation.
AIN SHAMS ENGINEERING JOURNAL
(2021)
Article
Engineering, Environmental
Xueling Wang, Kuo Sun, Guoquan Zhang, Fenglin Yang, Shihong Lin, Yingchao Dong
Summary: The study reports a novel method of efficiently separating oil nano-emulsions using zirconia membranes with sub-100 nm pores and superoleophobic properties. The membrane fouling behavior is dominated by a combined model of intermediate pore blocking and cake filtration, with effective mitigation under high pH conditions. Overall, the zirconia membrane demonstrates high rejection efficiency for nano-sized oil droplets and consistent separation performance for real oily wastewaters.
Article
Engineering, Environmental
Hongmei Wang, Hao Chen, Yibin Hong, Wenxiang Li, Li Guishui
Summary: The effects of operating pressure, feed temperature, oil content of feed solution, and membrane surface flow rate on membrane flux, concentration multiple, and average particle size of oil droplets in the concentrated solution during the single-stage membrane concentration process were investigated. The experimental results show that optimal conditions for single-stage concentration can be determined by increasing the operating pressure, feed temperature, and membrane surface flow rate, and decreasing the oil content of the feed liquid, the concentration ratio, and the average particle size of oil droplets in the concentrated solution. Furthermore, the recovery of oil resources in emulsified oil-containing wastewater can be realized through the combination of different pore size separation membranes in multi-stage membrane concentration.
WATER SCIENCE AND TECHNOLOGY
(2023)
Article
Polymer Science
Alireza Yousefi, Habib Etemadi, Milad Hermani, Farid Aftabi, Ghader Hosseinzadeh
Summary: This study focuses on improving the performance of PVC membranes by adding different concentrations (0.5-1.5 wt.%) of polydopamine-modified alumina nanoparticles. The fabricated nanocomposite membranes were tested for the removal of oily wastewater in a cross-flow filtration system. Various characterization techniques were used to analyze the membranes, and it was found that the addition of 0.5 wt.% Al2O3-PDA nanoparticles resulted in increased hydrophilicity, porosity, and pure water flux. However, the mechanical strength of the membranes decreased by 33% when 1.5 wt.% Al2O3-PDA nanoparticles were added. The permeation flux of the PVC/Al2O3-PDA-0.5 sample reached 38.2 Lm(-2) h(-1) with a TOC content of 56.3 mg L-1.
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
(2023)
Review
Engineering, Environmental
Amir Hossein Behroozi, Maryam Rostami Ataabadi
Summary: The review presents comprehensive developments in MF process over the past two decades, covering research on different membrane materials, hybrid technologies, and enhancement methods. Future outlook includes the incorporation of nanoparticles with excellent photocatalytic and hydrophilic characteristics in MF membranes for better treatment of oily wastewater on an industrial scale.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Crystallography
Junliang Chen, Qingxin Lv, Qingmei Meng, Xinpeng Liu, Xiaolong Xiao, Xiao Li, Yiyi Liu, Xue Zhang, Peiling Gao
Summary: In this study, alumina ceramic plate microfiltration membranes were used to treat oily wastewater, and the results showed that the system had good oil rejection and permeation flux recovery performance. The concentration of raw oil had a certain impact on the oil rejection rate, but had little effect on the flux change of ceramic membranes.
Article
Engineering, Environmental
Linxin Zhong, Chunyi Sun, Fenglin Yang, Yingchao Dong
Summary: The study presents a waste-to-resource strategy for recycling copper-bearing waste and treating oily wastewater by rational design of spinel ceramic membranes. A spinel phase conversion mechanism was proposed, and spinning and sintering parameters were systematically studied to tailor membrane structure and properties. This approach demonstrates the feasibility of recycling hazardous metal-bearing sludges into functional ceramic membranes for water treatment applications.
JOURNAL OF WATER PROCESS ENGINEERING
(2021)
Article
Chemistry, Multidisciplinary
Wei Yao, Jian Tan, Xiaodong Zhu, Guanglei Liu, Zhenglong Xu, Mingxin Ye, Jianfeng Shen
Summary: Inspired by leaf structure, a carbon felt/PVA solar-driven device was developed for the separation of versatile oily wastewater. This device exhibits superior solar energy absorption and vapor release capacity, enabling efficient purification of different types of wastewater, including high concentration oil-water emulsions and acidic/alkaline wastewater.
CELL REPORTS PHYSICAL SCIENCE
(2022)
Review
Engineering, Environmental
Abdul Halim, Lusi Ernawati, Maya Ismayati, Fahimah Martak, Toshiharu Enomae
Summary: This paper reviews the current research trend of using cellulose as a membrane material for purifying oily wastewater. It introduces three typical biostructures: superhydrophobic, underwater superoleophobic, and Janus surfaces, and applies their characteristics to improve membrane performance. The study also focuses on the biodegradability and sustainability of cellulose. The principles, mechanisms, fabrication processes, and membrane performances are summarized and compared, and future outlook is discussed.
FRONTIERS OF ENVIRONMENTAL SCIENCE & ENGINEERING
(2022)
Article
Materials Science, Paper & Wood
Parisa Daraei, Negin Ghaemi, Hedayatollah Sadeghi Ghari
Article
Chemistry, Physical
Negin Ghaemi
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2017)
Article
Engineering, Environmental
Negin Ghaemi, Sina Zereshki, Saeid Heidari
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION
(2017)
Article
Chemistry, Applied
Negin Ghaemi, Parisa Daraei, Farima Sadat Akhlaghi
CARBOHYDRATE POLYMERS
(2018)
Article
Engineering, Environmental
Negin Ghaemi, Parisa Safari
JOURNAL OF HAZARDOUS MATERIALS
(2018)
Article
Biochemistry & Molecular Biology
Maryam Maghsudi, Nahid Shahabadi, Mohammad Reza Ashrafi Kooshk, Negin Ghaemi, Leila Nemati, Shahram Parvaneh, Khosrow Adeli, Kambiz Varmira
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2018)
Article
Chemistry, Applied
Negin Ghaemi, Zahra Khodakarami
CARBOHYDRATE POLYMERS
(2019)
Article
Chemistry, Multidisciplinary
Parisa Daraei, Sina Zereshki, Amin Shokri
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2019)
Article
Environmental Sciences
S. S. Madaeni, M. Falsafi, N. Ghaemi, P. Daraei
Summary: Through biomimetic technique, the surface structure of nasturtium leaf was replicated on RO membrane, improving surface characteristics, enhancing hydrophilicity, and reducing fouling tendency. The replicated membranes exhibited higher pure water flux and flux recovery values, indicating lower fouling propensity.
ENVIRONMENTAL TECHNOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Mohammad Nasiri, Fariborz Atabaki, Negin Ghaemi, Zahra Seyedzadeh
IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION
(2020)
Article
Engineering, Chemical
Meghdad Pirsaheb, Farnaz Azizi, Masoud Moradi, Yasser Vasseghian, Elena-Niculina Dragoi, Negin Ghaemi
DESALINATION AND WATER TREATMENT
(2020)
Article
Engineering, Chemical
Negin Ghaemi, Farzaneh Darabi, Monireh Falsafi
MEMBRANE AND WATER TREATMENT
(2019)
Article
Engineering, Chemical
Negin Ghaemi, Abbas Rezaei, Majid Mohadesi
DESALINATION AND WATER TREATMENT
(2017)
Article
Chemistry, Physical
Nadine J. Kanik, Artur Kuligiewicz, Jeffrey T. Cullen
Summary: This study examined the effects of different pre-treatments on the structural H-isotope composition of clay minerals. The results showed that different pre-treatments had varied impacts on different clay minerals, and the choice of pre-treatment should be based on the specific properties and mineralogy of the samples.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
Lorenzo Lisuzzo, Giuseppe Cavallaro, Stefana Milioto, Giuseppe Lazzara
Summary: This study proposes Pickering emulsions based on wax and halloysite clay nanotubes for coating silk sutures to increase their loading capacity towards eosin. The presence of halloysite/wax microspheres on the surface of silk sutures has also been explored for controlled release of hydrophobic drugs. The influence of the coating on the thermal and mechanical properties of the sutures has been studied using various techniques. In conclusion, the wax/halloysite Pickering emulsions can successfully generate hydrophobic microdomains on the surface of silk sutures, leading to enhanced flexibility and improved loading capacity towards eosin.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
Bruna F. Alves, Rita C. P. Nunes, Luiz C. Bertolino, Elizabete F. Lucas
Summary: Operational problems in the oil industry caused by the precipitation of paraffins can be prevented by using polymeric additives. This article evaluates the use of polymeric nanocomposites as pour point reducers in different types of crude oil and finds that they are more efficient than pure poly(ethylene-covinyl acetate) (EVA) in reducing the pour point. The nanocomposites also modify the wax crystals and reduce the viscosity of the oil samples.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
K. A. Daniels, C. C. Graham, A. C. Wiseall, J. F. Harrington, P. Sellin
Summary: Geological storage with clay buffer is widely preferred for removing hazardous radioactive waste. The impact of fluid salinity and void space on the swelling behavior of barrier bentonites was examined through experiments. The findings suggest that clay swelling is suppressed at higher salinities, which affects the void-filling process.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
N. Werling, A. Kuligiewicz, A. Steudel, R. Schuhmann, F. Dehn, K. Emmerich
Summary: Thermal treatment of clay minerals can be used to produce building materials and environmentally friendly binders. This process involves dehydration, dehydroxylation, breakdown of structure, and recrystallization of high temperature phases. Rehydration and rehydroxylation are important factors to consider for geopolymers and SCM.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
Xuan Wang, Hao Ding, Zhuoqun Xu, Jianmeng Zhang, Yanbin Yao
Summary: Rutile nano-TiO2 was loaded onto the surface of sericite to prepare sericite-rutile composite particles, which were then modified with HDTMS and sprayed onto the substrates to form sericite-rutile/HDTMS composite coatings with UV shielding and superhydrophobic self-cleaning properties. The coating exhibited good UV shielding rate and remained superhydrophobic after UV irradiation. The hierarchical structure of the sericite-rutile composite and the low surface energy of HDTMS contributed to the superhydrophobicity and UV shielding effect of the coating.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
Kailang Sun, Taojun Zhang, Jie Zhou, Yonghong Liu, Minfeng Zeng, Zhen Yang, Ruokun Feng, Xiaorong Ren, Peng Zhang, Baoyi Wang, Xingzhong Cao
Summary: Chitosan-Pd0 nano particles encapsulated in Al, Co-pillared montmorillonite nanocomposites were successfully synthesized using a facile one-pot heat treatment method. The Al, Co pillaring effectively expanded the surface area and generated numerous mesopores in the interlayer space of the MMt. The resultant nanocomposite exhibited similar high comprehensive catalytic performances as the one prepared by the regular divided-multistep method. The encapsulation of CS chains and doping of Co in the Al pillaring also contributed to the improved catalytic performance.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
Nathalie Fagel, Isabel Israde-Alcantara, Reza Safaierad, Marttiina Rantala, Sabine Schmidt, Gilles Lepoint, Pierre Pellenard, Nadine Mattielli, Sarah Metcalfe
Summary: Environmental conditions significantly influence clay minerals, and studying clay sediments in tropical lakes can provide valuable insights into past environmental conditions. In this study, multiproxy records from sediment cores of three crater lakes in central Mexico were analyzed. The results showed that disordered kaolinite, formed through hydrolysis and hydrothermal alteration, was the predominant mineral in the sediments. The abundance of kaolinite varied in relation to organic carbon and organic matter-related elements, and showed opposite trends with lithogenic elements. Geochemical data suggested that the increase in kaolinite abundance is linked to the formation of organo-mineral aggregates and lake level changes in closed basins.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
M. J. Martin-Alfonso, A. Mejia, F. J. Martinez-Boza, P. Partal
Summary: The drilling industry is facing new challenges to develop eco-friendlier drilling fluids. Organic modified sepiolite dispersed in oil can be an excellent additive with suitable rheological properties. This study investigated the effect of alkyl ammonium modifiers on the microstructure and rheological properties of sepiolite-vegetable oil dispersions under high-temperature and high-pressure conditions.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
Weiquan Zhan, Siyuan Yang, Shenxu Bao, Liuyi Ren, Cheng Liu
Summary: The interaction between talc and the depressor CMC was investigated through molecular dynamics simulation and density functional theory calculation. It was found that CMC showed stronger adsorption on the edge plane of talc due to enhanced interactions with polar groups and water molecules. The study also revealed specific interactions between H atoms in CMC and O atoms in the edge plane, as well as between O atoms in CMC and Si, Mg atoms in the edge plane. Hydration shells on the basal and edge planes of talc were examined to explain the phenomenon.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
Pierre Dramou, Yiyang Sun, Xu Ni, Fangqi Wang, Hua He
Summary: In this study, a magnetic nanocomposite was prepared and used for the separation of rutin from real samples through magnetic solid phase extraction (MSPE). The nanocomposite exhibited high specific surface area, chemical and thermal stability, water solubility, and easy separation in aqueous solution. Characterization and experiments confirmed the successful synthesis and efficient enrichment ability of the nanocomposite.
APPLIED CLAY SCIENCE
(2024)