期刊
APPLIED CATALYSIS A-GENERAL
卷 578, 期 -, 页码 20-29出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2019.03.025
关键词
Soot combustion; Ceria catalyst; Nanoflakes; Cu doping; Redox property
资金
- National Science Foundation of China [21276214]
- Natural Science Foundation of Fujian Province [2015J05033]
- Energy Development Foundation of Energy College, Xiamen University [2017NYFZ02]
- Fundamental Research Funds for the Central Universities [20720170043]
In the present study, nanoflakes (NF) of CeO2-NF and CuxCe1-xO2-NF (x = 0.1, 0.2, 0.3 and 0.4) were prepared with the polyvinylpyrrolidone(PVP)-assisted co-precipitation method. The prepared samples were characterized with FE-SEM, HR-TEM, XRD, N-2 adsorption, O-2-TPD, H-2-TPR, Raman and XPS. It was found that doping of Cu in CeO2-NF significantly promoted the formation of oxygen species that replenished the vacancies. The CuxCe1-xO2-NF exhibited much better activity than CeO2-NF that has no Cu doping both in tight contact and NO-assistant loose contact modes. The highest activity was observed for the sample of Cu0.2Ce0.8O2-NF, which was most likely caused by its moderate doping that induced both a large amount of surface adsorbed oxygen species and a special flake morphology, thus providing effective contact area. Both the cyclic and accelerated aging tests demonstrated that Cu0.2Ce0.8O2-NF was able to keep a good thermal stability.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据