期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 27, 页码 9244-9247出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201903839
关键词
frustrated Lewis pairs; magnesiation; pyridazine; TMP bases; zincation
资金
- DFG [SFB749]
Mono- or bidentate boron Lewis acids trigger a regioselective magnesiation or zincation of pyridazine in position C3 (ortho product) or C4 meta product). The regioselectivity of the metalation was rationalized with the help of calculated pK(a) values of both pyridazine and pyridazine/Lewis acid complexes.
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