N-Heterocyclic Carbene Stabilized Boryl Radicals

A boron-centered radical: a potassium-crown ether stabilized boryl radical anion

(2016) Ningning Yuan et al.   CHEMICAL COMMUNICATIONS

Reduction of a diamidocarbene-supported borenium cation: isolation of a neutral boryl-substituted radical and a carbene-stabilized aminoborylene

(2016) Anthony D. Ledet et al.   DALTON TRANSACTIONS

Highly selective catalytic trans-hydroboration of alkynes mediated by borenium cations and B(C6F5)3

(2016) John S. McGough et al.   Chemical Science

Stepwise Reduction of 9,10-Bis(dimesitylboryl)anthracene

(2015) Yang Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Phosphine-Coordinated Boron-Centered Gomberg-Type Radical

(2015) Amos J. Rosenthal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Planar N-Heterocyclic Carbene Diarylborenium Ions: Synthesis by Cationic Borylation and Reactivity with Lewis Bases

(2015) Jeffrey M. Farrell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogenations at Room Temperature and Atmospheric Pressure with Mesoionic Carbene-Stabilized Borenium Catalysts

(2015) Patrick Eisenberger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lowering the Reduction Potential of a Boron Compound by Means of the Substituent Effect of the Boryl Group: One-Electron Reduction of an Unsymmetrical Diborane(4)

(2015) Hiroki Asakawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Frustrated N-heterocyclic carbene–silylium ion Lewis pairs

(2015) Miguel F. Silva Valverde et al.   DALTON TRANSACTIONS

Preparation and reactivity of an isolable N-heterocyclic carbene–borane

(2015) Andrea Winkler et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis

(2015) Jeffrey M. Farrell et al.   Chemical Science

Metal-Free Dihydrogen Oxidation by a Borenium Cation: A Combined Electrochemical/Frustrated Lewis Pair Approach

(2014) Elliot J. Lawrence et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Confirmed by X-ray Crystallography: The B⋅B One-Electron σ Bond

(2014) Alexander Hübner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Evidence for Extensive Single-Electron-Transfer Chemistry in Boryl Anions: Isolation and Reactivity of a Neutral Borole Radical

(2014) Rüdiger Bertermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation of a Neutral Boron-Containing Radical Stabilized by a Cyclic (Alkyl)(Amino)Carbene

(2014) Philipp Bissinger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Reactivity of a CAAC-Aminoborylene Adduct: A Hetero-Allene or an Organoboron Isoelectronic with Singlet Carbenes

(2014) Fatme Dahcheh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Observation of a Chloride-Bridged P–P Bond in the Phosphorus Cation [L(Cl)P(μ-Cl)P(Cl)L]+ (L = NHC)

(2013) Florian D. Henne et al.   ORGANOMETALLICS

Carbene-stabilized main group radicals and radical ions

(2013) Caleb D. Martin et al.   Chemical Science

Cationic Tricoordinate Boron Intermediates: Borenium Chemistry from the Organic Perspective

(2012) Timothy S. De Vries et al.   CHEMICAL REVIEWS

Synthesis and Characterization of B-Heterocyclic π-Radical and Its Reactivity as a Boryl Radical

(2012) Yoshitaka Aramaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Hydrogen and Hydrogenation Catalysis by a Borenium Cation

(2012) Jeffrey M. Farrell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Borenium Ion Catalyzed Hydroboration of Alkenes with N-Heterocyclic Carbene-Boranes

(2012) Aleksandrs Prokofjevs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactions of N-Heterocyclic Carbene Boranes

(2011) Dennis P. Curran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electron Paramagnetic Resonance and Computational Studies of Radicals Derived from Boron-Substituted N-Heterocyclic Carbene Boranes

(2011) John C. Walton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactions of Boron-Substituted N-Heterocyclic Carbene Boranes with Triflic Acid. Isolation of a New Dihydroxyborenium Cation

(2011) Andrey Solovyev et al.   ORGANOMETALLICS

New Boryl Radicals Derived from N-Heteroaryl Boranes: Generation and Reactivity

(2010) Jacques Lalevée et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and Comparative Characterization of 9-Boraanthracene, 5-Boranaphthacene, and 6-Borapentacene Stabilized by the H2IMes Carbene

(2010) Thomas K. Wood et al.   CHEMISTRY-A EUROPEAN JOURNAL

4,5-Disubstituted N,N′-Di-tert-alkyl Imidazolium Salts: New Synthesis and Structural Features

(2010) Anastasia A. Grishina et al.   CHEMISTRY-A EUROPEAN JOURNAL

EPR Studies of the Generation, Structure, and Reactivity of N-Heterocyclic Carbene Borane Radicals

(2010) John C. Walton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbene-Stabilized Phosphorus(III)-Centered Cations [LPX2]+and [L2PX]2+(L = NHC; X = Cl, CN, N3)

(2010) Jan J. Weigand et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbenes−Borane Complexes: A New Class of Initiators for Radical Photopolymerization

(2010) Mohamad-Ali Tehfe et al.   MACROMOLECULES

9-Boraanthracene Derivatives Stabilized by N-Heterocyclic Carbenes

(2009) Thomas K. Wood et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Effect of Lewis base coordination on boryl radical reactivity: investigation using laser flash photolysis and kinetic ESR

(2009) Jacques Lalevée et al.   JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

N-Heterocyclic Carbene Boryl Radicals: A New Class of Boron-Centered Radical

(2009) Shau-Hua Ueng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Borenium Cation Stabilized by an N-Heterocyclic Carbene Ligand

(2009) Takeshi Matsumoto et al.   ORGANOMETALLICS

Complexes of Borane and N-Heterocyclic Carbenes: A New Class of Radical Hydrogen Atom Donor

(2008) Shau-Hua Ueng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boryl Radicals as a New Photoinitiating Species: A Way to Reduce the Oxygen Inhibition

(2008) J. Lalevée et al.   MACROMOLECULES