期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 35, 页码 10391-10395出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201603635
关键词
bromine; nitric acid; ozonation; photocatalysis; TiO2
资金
- University of Palermo
Significant production of elemental bromine (Br-2) was observed for the first time when treating bromide containing solutions at acidic pH, with TiO2 photocatalyst, ozone, or a combination thereof. Br-2 selectivities up to approximately 85% were obtained and the corresponding bromine mass balance values satisfied. The process is general and may be applied at a laboratory scale for green bromination reactions, or industrially as a cheap, safe, and environmentally sustainable alternative to the currently applied bromine production methods.
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