期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 3, 页码 712-716出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201610810
关键词
arenes; carboranes; cross-coupling; photochemistry; radicals
资金
- Research Grants Council of the Hong Kong Special Administration Region [14304115]
- CUHK
- National Natural Sciences Foundation of China [21372245]
- NSFC/RGC Joint Research Scheme [N_CUHK442/14]
- CAS-Croucher Funding Scheme
Photoarylation of iodocarboranes with unactivated arenes/heteroarenes at room temperature has been achieved, for the first time, thus leading to the facile synthesis of a large variety of cage carbon mono(hetero) arylated and di-(hetero) arylated o-carboranes. This work represents a clean, efficient, transition-metal-free, and cheap synthesis of functionalized carboranes, which has significant advantages over the known methods.
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