期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 3, 页码 832-836出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201607948
关键词
disulfide catalysts; donor-acceptor complexes; olefin oxidation; organocatalysis; visible-light photocatalysis
资金
- Shanghai Advanced Research Institute
- European Union [641861]
- Marie Curie Actions (MSCA) [641861] Funding Source: Marie Curie Actions (MSCA)
A photocatalytic method for the aerobic oxidative cleavage of C=C bonds has been developed. Electron-rich aromatic disulfides were employed as photocatalyst. Upon visible-light irradiation, typical mono- and multi-substituted aromatic olefins could be converted into ketones and aldehydes at ambient temperature. Experimental and computational studies suggest that a disulfide-olefin charge-transfer complex is possibly responsible for the unconventional dissociation of S-S bond under visible light.
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