Stacking and Electrostatic Interactions Drive the Stereoselectivity of Silylium-Ion Asymmetric Counteranion-Directed Catalysis

Computational Approach to Diarylprolinol-Silyl Ethers in Aminocatalysis

(2016) Kim Søholm Halskov et al.   ACCOUNTS OF CHEMICAL RESEARCH

Theory and Modeling of Asymmetric Catalytic Reactions

(2016) Yu-hong Lam et al.   ACCOUNTS OF CHEMICAL RESEARCH

Computational Insights into the Central Role of Nonbonding Interactions in Modern Covalent Organocatalysis

(2016) Daniel M. Walden et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Control in Cyclizations: From Computational Mechanistic Understanding to Selectivity Prediction

(2016) Qian Peng et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Practical Guide for Predicting the Stereochemistry of Bifunctional Phosphoric Acid Catalyzed Reactions of Imines

(2016) Jolene P. Reid et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition State Models for Understanding the Origin of Chiral Induction in Asymmetric Catalysis

(2016) Raghavan B. Sunoj   ACCOUNTS OF CHEMICAL RESEARCH

Noncovalent Interactions in Organocatalysis and the Prospect of Computational Catalyst Design

(2016) Steven E. Wheeler et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Lewis acid organocatalysis of the Diels-Alder reaction by a silylated C-H acid

(2016) T. Gatzenmeier et al.   SCIENCE

Asymmetric counteranion-directed Lewis acid organocatalysis for the scalable cyanosilylation of aldehydes

(2016) Zhipeng Zhang et al.   Nature Communications

Electrostatic Basis for Enantioselective Brønsted-Acid-Catalyzed Asymmetric Ring Openings of meso-Epoxides

(2016) Trevor J. Seguin et al.   ACS Catalysis

Design of Organocatalysts for Asymmetric Propargylations through Computational Screening

(2016) Analise C. Doney et al.   ACS Catalysis

London Dispersion in Molecular Chemistry-Reconsidering Steric Effects

(2015) J. Philipp Wagner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselectivity in Catalytic Asymmetric Fischer Indolizations Hinges on the Competition of π-Stacking and CH/π Interactions

(2015) Trevor J. Seguin et al.   ORGANIC LETTERS

A data-intensive approach to mechanistic elucidation applied to chiral anion catalysis

(2015) A. Milo et al.   SCIENCE

Harnessing weak interactions for enantioselective catalysis

(2015) T. Lu et al.   SCIENCE

Enantioselective Synthesis of Fluoro–Dihydroquinazolones and −Benzooxazinones by Fluorination-Initiated Asymmetric Cyclization Reactions

(2015) Kenichi Hiramatsu et al.   ACS Catalysis

Chiral Counteranion Strategy for Asymmetric Oxidative C(sp3)H/C(sp3)H Coupling: Enantioselective α-Allylation of Aldehydes with Terminal Alkenes

(2014) Pu-Sheng Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Fluorination of α-Branched Cyclohexanones Enabled by a Combination of Chiral Anion Phase-Transfer Catalysis and Enamine Catalysis using Protected Amino Acids

(2014) Xiaoyu Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic kinetic resolution of a dynamic racemate: highly stereoselective β-lactone formation by N-heterocyclic carbene catalysis

(2014) Ryne C. Johnston et al.   Chemical Science

Asymmetric Cross-Dehydrogenative Coupling Enabled by the Design and Application of Chiral Triazole-Containing Phosphoric Acids

(2013) Andrew J. Neel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Disulfonimide-Catalyzed Asymmetric Synthesis of β3-Amino Esters Directly from N-Boc-Amino Sulfones

(2013) Qinggang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Control of Diastereoselectivity for Iridium-Catalyzed Allylation of a Prochiral Nucleophile with a Phosphate Counterion

(2013) Wenyong Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H⋯O non-classical hydrogen bonding in the stereomechanics of organic transformations: theory and recognition

(2013) Ryne C. Johnston et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric Ion-Pairing Catalysis

(2012) Katrien Brak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Counteranion-Directed Catalysis: Concept, Definition, and Applications

(2012) Manuel Mahlau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Supramolecular Binding Thermodynamics by Dispersion-Corrected Density Functional Theory

(2012) Stefan Grimme   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Counteranion-Directed Catalytic Hosomi-Sakurai Reaction

(2012) Manuel Mahlau et al.   CHEMISTRY-A EUROPEAN JOURNAL

The progression of chiral anions from concepts to applications in asymmetric catalysis

(2012) Robert J. Phipps et al.   Nature Chemistry

Direct Asymmetric α-Allylation of Aldehydes with Simple Allylic Alcohols Enabled by the Concerted Action of Three Different Catalysts

(2011) Gaoxi Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Quantum Mechanical Investigations of Organocatalysis: Mechanisms, Reactivities, and Selectivities

(2011) Paul Ha-Yeon Cheong et al.   CHEMICAL REVIEWS

Asymmetric Electrophilic Fluorination Using an Anionic Chiral Phase-Transfer Catalyst

(2011) V. Rauniyar et al.   SCIENCE

Integration Grid Errors for Meta-GGA-Predicted Reaction Energies: Origin of Grid Errors for the M06 Suite of Functionals

(2010) Steven E. Wheeler et al.   Journal of Chemical Theory and Computation

The activation strain model of chemical reactivity

(2010) Willem-Jan van Zeist et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Powerful Chiral Counteranion Motif for Asymmetric Catalysis

(2009) Pilar García-García et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Anion-Mediated Asymmetric Ring Opening ofmeso-Aziridinium and Episulfonium Ions

(2008) Gregory L. Hamilton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Computational prediction of small-molecule catalysts

(2008) K. N. Houk et al.   NATURE