期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 14, 页码 4557-4561出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201512015
关键词
bromonium ylides; carbenes; isoquinolines; rhodium; triazoles
资金
- National Natural Science Foundation of China [21372204]
- Program for Innovative Research Team of Zhejiang Sci-Tech University [13060052-Y]
- Young Researchers Foundation of Zhejiang Provincial Top Key Academic Discipline of Chemical Engineering and Technology, Zhejiang Sci-Tech University [ZYG2015004]
Highly functionalized 4-bromo-1,2-dihydroisoquinolines were synthesized from readily available 4-(2-(bromomethyl)phenyl)-1-sulfonyl-1,2,3-triazoles. A bromonium ylide is proposed as the key intermediate, which can be formed by the intramolecular nucleophilic attack of the benzyl bromide on the -imino rhodium carbene formed in the presence of the rhodium catalyst.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据