期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 20, 页码 6008-6012出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201600675
关键词
colloidal crystals; mesoporous silica; single crystals; superlattices; -quartz
资金
- Mizuho Foundation for the Promotion of Science
- Japan Chemical Industry Association
- [26248060]
- [26810118]
- Grants-in-Aid for Scientific Research [26810118, 26248060] Funding Source: KAKEN
There has been significant interest in the crystallization of nanostructured silica into -quartz because of its physicochemical properties. We demonstrate a single-crystalline mesoporous quartz superlattice, a silica polymorph with unprecedentedly ordered hierarchical structures on both the several tens of nanometers scale and the atomic one. The mesoporous quartz superlattice consists of periodically arranged -quartz nanospheres whose crystalline axes are mostly oriented in an assembly. The superlattice is prepared by thermal crystallization of amorphous silica nanospheres constituting a colloidal crystal. We found that the deposition of a strong flux of Li+ only on the surface of silica nanospheres is effective for crystallization.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据