期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 32, 页码 9216-9219出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201603760
关键词
boron; carbon monoxide; frustrated Lewis pairs; nitric oxide; phosphorus
资金
- European Research Council
- DFG
Coupling of carbon monoxide with nitrogen monoxide was achieved at a frustrated Lewis pair template. This unique reaction uses hydride as an auxiliary, which reductively activates carbon monoxide at the frustrated Lewis pair. The CO/NO coupling reaction then takes place through a pathway involving a radical reaction in which the hydrogen atom auxiliary is eventually removed again.
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